Polymethylene polyphenyl polyisocyanate
- Product Name
- Polymethylene polyphenyl polyisocyanate
- CAS No.
- 9016-87-9
- Chemical Name
- Polymethylene polyphenyl polyisocyanate
- Synonyms
- papi;PMDI;pmppi;isocyanuric;papi27;isocyanatedepolymethyleneetdepolyphenyle;Polymeric Methylene Diphenyl Diisocyanate;e534;cr200;mr200
- CBNumber
- CB6416391
- Molecular Formula
- C8H7NO2
- Formula Weight
- 149.14668
- MOL File
- 9016-87-9.mol
Polymethylene polyphenyl polyisocyanate Property
- Boiling point:
- 392 °C5 mm Hg
- Density
- 1.2 g/mL at 25 °C(lit.)
- vapor density
- 8.6 (vs air)
- refractive index
- n20/D 1.634
- Flash point:
- >230 °F
- storage temp.
- Refrigerator, Under inert atmosphere
- solubility
- DMSO (Sparingly), Ethyl Acetate (Slightly), Methanol (Soluble)
- form
- Oil
- color
- Yellow to Orange
- Stability:
- Stable. Incompatible with strong oxidizing agents, alcohols. May decompose in moist air, or on contact with water.
- InChI
- InChI=1S/C7H5NO.CH2O/c9-6-8-7-4-2-1-3-5-7;1-2/h1-5H;1H2
- InChIKey
- JTEOXXUIKUHXLD-UHFFFAOYSA-N
- SMILES
- O=C=NC1C([H])=C([H])C([H])=C([H])C=1[H].O=C([H])[H]
- IARC
- 3 (Vol. 19, Sup 7) 1987
- EPA Substance Registry System
- Polymeric diphenylmethane diisocyanate (9016-87-9)
Safety
- Hazard Codes
- Xn,T+,T,F
- Risk Statements
- 20-36/37/38-42-42/43-26-22-39/23/24/25-23/24/25-11-20/21/22
- Safety Statements
- 26-28-38-45-36/37-23-16-7-36
- WGK Germany
- 3
- RTECS
- TR0350000
- Hazardous Substances Data
- 9016-87-9(Hazardous Substances Data)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H315Causes skin irritation
H317May cause an allergic skin reaction
H319Causes serious eye irritation
H330Fatal if inhaled
H334May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335May cause respiratory irritation
H351Suspected of causing cancer
H373May cause damage to organs through prolonged or repeated exposure
- Precautionary statements
-
P202Do not handle until all safety precautions have been read and understood.
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 406597
- Product name
- Poly[(phenyl isocyanate)-co-formaldehyde]
- Purity
- average M
- Packaging
- 100ml
- Price
- $128
- Updated
- 2023/06/20
- Product number
- 372986
- Product name
- Poly[(phenyl isocyanate)-co-formaldehyde]
- Purity
- average M
- Packaging
- 100ml
- Price
- $87.7
- Updated
- 2023/06/20
- Product number
- P688095
- Product name
- Poly[methylene(polyphenylIsocyanate)](Mn~340-400)
- Packaging
- 10ml
- Price
- $55
- Updated
- 2021/12/16
- Product number
- AR00GTKS
- Product name
- Polymethylenepolyphenylpolyisocyanate
- Purity
- 98%
- Packaging
- 5g
- Price
- $7
- Updated
- 2021/12/16
- Product number
- AR00GTKS
- Product name
- Polymethylenepolyphenylpolyisocyanate
- Purity
- 98%
- Packaging
- 25g
- Price
- $13
- Updated
- 2021/12/16
Polymethylene polyphenyl polyisocyanate Chemical Properties,Usage,Production
Description
Polymethylene polyphenyl polyisocyanate is a chain extender and a cross-linker that is used in the formation of a polyurethane system by forming amide linkages (?NCO).
Chemical Properties
liquid
Uses
Poly[methylene(polyp?henyl Isocyanate)?] is an engineering polymer used in the synthesis of highly resiliant polyurethane foams with flame retardancy.Environmental toxin on US EPA Toxic Release Inventory list (TRI) list.
Definition
A polymer of diphenylmethane-4,4′-diisocyanate.
Application
Polymethylene polyphenyl polyisocyanate can be used as a cross-linker to DNA and CTMA based films for the fabrication of biomaterials for organic electronic devices. It can be used in the formation of polyurethane based materials for non-linear optical applications.
General Description
Dark-brown liquid with a weak odor. Sinks in water.
Air & Water Reactions
Reacts with water slowly forming heavy scum and liberating carbon dioxide gas. Dangerous pressure can build up if container is sealed.
Reactivity Profile
Polymethylene polyphenyl polyisocyanate reacts with water slowly forming heavy scum and liberating carbon dioxide gas. Dangerous pressure can build up if container is sealed. Base-catalysed reactions of isocyanates with alcohols should be carried out in inert solvents. Such reactions in the absence of solvents often occur with explosive violence [Wischmeyer 1969].
Hazard
Questionable carcinogen.
Health Hazard
Inhalation causes breathlessness, chest discomfort, and reduced pulmonary function; wheezing, cough, and sputum may also occur. Contact with liquid irritates eyes and skin. Ingestion causes irritation of mouth and stomach.
Fire Hazard
Behavior in Fire: Containers may explode.
Safety Profile
Moderately toxic by ingestion. Mildly toxic by inhalation. Questionable carcinogen with experimental neoplastigenic data by implant route. When heated to decomposition it emits toxic fumes of NOx.
Polymethylene polyphenyl polyisocyanate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Polymethylene polyphenyl polyisocyanate manufacturers
- Product
- Polymethylene Polyphenylene Isocyanate Mdi 9016-87-9
- Price
- US $85.00-25.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20ton
- Release date
- 2024-05-23
- Product
- Polymethylene polyphenyl polyisocyanate 9016-87-9
- Price
- US $6.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 2000KG/Month
- Release date
- 2024-08-06
- Product
- Polymethylene polyphenyl polyisocyanate 9016-87-9
- Price
- US $6.00/kg
- Min. Order
- 1kg
- Purity
- More than 99%
- Supply Ability
- 2000KG/Month
- Release date
- 2024-05-15