ChemicalBook > CAS DataBase List > 4'-CHLORO-2,2':6',2''-TERPYRIDINE

4'-CHLORO-2,2':6',2''-TERPYRIDINE

Product Name
4'-CHLORO-2,2':6',2''-TERPYRIDINE
CAS No.
128143-89-5
Chemical Name
4'-CHLORO-2,2':6',2''-TERPYRIDINE
Synonyms
DK7365;4'-Chloro-α,α',α''-tripyridyl;4'-CHLORO-2,2'6'2''-TERPYRIDINE;4'-CHLORO-2,2':6',2''-TERPYRIDINE;4'-CHLORO-2,2':6',2''-TERPYRIDINE;2,2':6',2''-Terpyridine,4'-chloro-;4'-Chloro-2,2,2':6',2''-terpyridine;4'-Chloro-2,2':6',2"-terpyridine-98%;4'-Chloro-2,2':6',2"-terpyridine-98%;4-Chloro-2,6-di(pyridin-2-yl)pyridine
CBNumber
CB6491835
Molecular Formula
C15H10ClN3
Formula Weight
267.71
MOL File
128143-89-5.mol
More
Less

4'-CHLORO-2,2':6',2''-TERPYRIDINE Property

Melting point:
148-150 °C(lit.)
Boiling point:
416.73°C (rough estimate)
Density 
1.2245 (rough estimate)
refractive index 
1.6010 (estimate)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
form 
Crystalline Powder
pka
4.22±0.22(Predicted)
color 
Brown
Water Solubility 
Slightly soluble in water.
λmax
278nm(CH3CN)(lit.)
BRN 
3613386
InChIKey
AHEMFMCEBIJRMU-UHFFFAOYSA-N
More
Less

Safety

Hazard Codes 
Xn
Risk Statements 
22-37/38-41
Safety Statements 
26-39
RIDADR 
UN 2811 6.1 / PGIII
WGK Germany 
3
HS Code 
29333990
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H301Toxic if swalloed

H315Causes skin irritation

H318Causes serious eye damage

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
405868
Product name
4′-Chloro-2,2′:6′,2′′-terpyridine
Purity
99%
Packaging
1g
Price
$215
Updated
2024/03/01
TCI Chemical
Product number
C3187
Product name
4'-Chloro-2,2':6',2''-terpyridine
Purity
>98.0%(GC)(T)
Packaging
200mg
Price
$69
Updated
2024/03/01
TCI Chemical
Product number
C3187
Product name
4'-Chloro-2,2':6',2''-terpyridine
Purity
>98.0%(GC)(T)
Packaging
1g
Price
$206
Updated
2024/03/01
Alfa Aesar
Product number
L14728
Product name
4'-Chloro-2,2':6',2''-terpyridine, 98%
Packaging
250mg
Price
$51.65
Updated
2024/03/01
Alfa Aesar
Product number
L14728
Product name
4'-Chloro-2,2':6',2''-terpyridine, 98%
Packaging
1g
Price
$145
Updated
2024/03/01
More
Less

4'-CHLORO-2,2':6',2''-TERPYRIDINE Chemical Properties,Usage,Production

Chemical Properties

brown crystalline powder

Uses

4'-Chloro-2,2':6',2''-terpyridine is widely utilized in the field of supramolecular chemistry, which is used to manufacture double helicates, dendrimers, micelles and metallo-supramolecular polymers. It is used to synthesize the mono- and bis-terpyridines. It is actively involved in Williamson type ether reactions alpha,μ-bishydroxy-functionalized poly(propylene oxide).

General Description

4′-Chloro-2,2′:6′,2′′-terpyridine (4′-Cltpy, Cltpy, Cl-terpy) is a tridentate ligand that contains a terpyridine (tpy) site with a Cl site at the 4 -position. It coordinates with various metal ions through these two sites to form different coordination polymers. Crystal structure study shows terpyridine unit of Cltpy adopts a trans, trans conformation. Mol-ecules assemble themselves into stacked columns along the b axis, with an inter-planar distance of 3.51?. It undergoes Williamson type ether reactions with α,ω-bishydroxy-functionalized poly(propylene oxide). It undergoes Williamson type reaction with α-hydroxy-ω-carboxy-functionalized poly(ethylen-oxide) to afford monoterpyridine terminated telechelics.

4'-CHLORO-2,2':6',2''-TERPYRIDINE Preparation Products And Raw materials

Raw materials

Sodium hydride Acetone Phosphorus oxychloride Ethyl picolinate Phosphorus pentachloride Tetrahydrofuran Ammonium acetate

Preparation Products

More
Less

4'-CHLORO-2,2':6',2''-TERPYRIDINE Suppliers

Americas 1 Belgium 1 Canada 1 China 115 Europe 1 Germany 2 India 8 Japan 2 Switzerland 2 United Kingdom 4 United States 15 Global 152
TCI Chemicals (India) Pvt. Ltd.
Tel
--
Fax
--
Email
sales-in@tcichemicals.com
Country
India
ProdList
6768
Advantage
58
CHEMSWORTH
Tel
--
Fax
--
Email
info@chemsworth.com
Country
India
ProdList
6700
Advantage
30
Alfa Aesar
Tel
--
Fax
--
Email
tech@alfa.com
Country
India
ProdList
6905
Advantage
58
A.J Chemicals
Tel
--
Fax
--
Email
sales@ajchem.in
Country
India
ProdList
6100
Advantage
58
Gagri Global IT Services Pvt. Ltd.
Tel
--
Fax
--
Email
info@sapalaorganics.com
Country
India
ProdList
1321
Advantage
58
More
Less

View Lastest Price from 4'-CHLORO-2,2':6',2''-TERPYRIDINE manufacturers

Shanghai UCHEM Inc.
Product
4'-CHLORO-2,2':6',2''-TERPYRIDINE 128143-89-5
Price
US $80.00-376.00/g
Min. Order
1g
Purity
0.98
Supply Ability
10kg
Release date
2024-04-12
Career Henan Chemical Co
Product
4'-CHLORO-2,2':6',2''-TERPYRIDINE 128143-89-5
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
1ton
Release date
2019-07-11

128143-89-5, 4'-CHLORO-2,2':6',2''-TERPYRIDINERelated Search:

2,2'-BIPYRIDINE-5-CARBOXYLIC ACID 2,2'-DIPYRIDYL N,N'-DIOXIDE 2,2':6',2''-TERPYRIDINE-4,4',4''-TRICARBOXYLIC ACID 4,4'-Dimethyl-2,2'-bipyridyl 4‘-(4-hydroxyphenyl)-2, 2':6‘, 2“-terpyridine 1,3,5-Tris(m-iodophenyl)benzene 4'-BROMO-2,2':6',2''-TERPYRIDINE 4-Methyl-4'-(3-carboxypropyl)-2,2'-bipyridine 6-BROMO-2,2'-BIPYRIDINE 6''-CHLORO-[3,2':5',3'']-TERPYRIDINE 2,2':6',2''-TERPYRIDINE 4-Chloro-2,6-dimethylpyridine 4'-CHLORO-2,2':6',2''-TERPYRIDINE 2,2'-BIPYRIDINE HYDROCHLORIDE 4-Chloro-2,2'-bipyridine 6-METHYL-2,2'-BIPYRIDINE 2,6-Lutidinehydrochloride CHLORO(2,2':6',2''-TERPYRIDINE)PLATINUM(II) CHLORIDE DIHYDRATE

  • 4'-CHLORO-2,2':6',2''-TERPYRIDINE
  • 4'-CHLORO-2,2'6'2''-TERPYRIDINE
  • 4-Chloro-2,6-di(pyridin-2-yl)pyridine ,99%
  • 4''-CHLORO-2,2'':6'',2''-TERPYRIDINE 99%
  • 4'-Chloro-2,2':6',2''-terpyridine,99%
  • 4-Chloro-2,6-di(pyridin-2-yl)pyridine
  • 2,2':6',2''-Terpyridine,4'-chloro-
  • 4'-Chloro-2,2,2':6',2''-terpyridine
  • 4'-Chloro-alpha,alpha',alpha''-tripyridyl
  • 4'-Chloro-2,2':6',2"-terpyridine-98%
  • 4-chloro-6-(pyridin-2-yl)-2,2''-bipyridine
  • DK7365
  • 4'-CHLORO-2,2':6',2''-TERPYRIDINE
  • 4'-Chloro-α,α',α''-tripyridyl
  • 4'-Chloro-2,2':6',2"-terpyridine-98%
  • 128143-89-5
  • C15H10ClN3
  • Building Blocks
  • Pyridines
  • Heterocyclic Building Blocks
  • Halogenated Heterocycles
  • C9 to C46Heterocyclic Building Blocks
  • Halogenated Heterocycles
  • Heterocyclic Building Blocks
  • Pyridines
  • Building Blocks
  • C13 to C40
  • C7 to C18
  • Chemical Synthesis
  • Halogenated Heterocycles
  • Heterocyclic Building Blocks