Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

Uses

Product Name: Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
CAS No.: 35138-22-8
Chemical Name: Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
Synonyms: Bis(cycloocta-1,5-dien)rho;dipalladium(II);ooctadiene)rhodium(Ⅰ)tetrafL;(1Z,5Z)-cycloocta-1,5-diene,rhodium;BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRA&;BIS(1,5-CYCLOOCTADIENE)RHODIUM TETRAFLUOROBORATE;BIS(1,5-CYCLOOCTADIEN)RHODIUM(I) TETRAFLUOROBORATE;BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE;BIS(CYCLOOCTA-1,5-DIEN)RHODIUM(I)-TETRAFLUOROBORATE;Bis(1,5-cyclooctadiene)rhodium(Ⅰ) tetrafluoroborate
CBNumber: CB6666011
Molecular Formula: C16H24BF4Rh
Formula Weight: 406.07
MOL File: 35138-22-8.mol

More

Less

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Property

Melting point:: 210 °C
Density: 0.42 g/cm3 (20℃)
storage temp.: Inert atmosphere,Store in freezer, under -20°C
solubility: Chloroform (Slightly), Methanol (Slightly)
form: Powder
color: Red
PH: 7 (5g/l, H2O, 20℃)
Water Solubility: insoluble
Sensitive: Slightly air & moisture sensitive
Exposure limits: ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
InChIKey: IEMMJJILGGBYNZ-GSLAGHMSSA-M
CAS DataBase Reference: 35138-22-8(CAS DataBase Reference)

More

Less

Safety

Hazard Codes: F,Xi
Risk Statements: 11-34
Safety Statements: 16-45-36/37/39-26
RIDADR: UN 2921
WGK Germany: 2
Hazard Note: Irritant
TSCA: No
HazardClass: 8
PackingGroup: III
HS Code: 28439000

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H228Flammable solid

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 14694
Product name: Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
Packaging: 100mg
Price: $124
Updated: 2024/03/01

TCI Chemical

Product number: B3961
Product name: Bis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate
Packaging: 1g
Price: $653
Updated: 2024/03/01

TCI Chemical

Product number: B3961
Product name: Bis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate
Packaging: 100mg
Price: $114
Updated: 2024/03/01

Alfa Aesar

Product number: 044031
Product name: Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
Packaging: 1g
Price: $600
Updated: 2023/06/20

Alfa Aesar

Product number: 044031
Product name: Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
Packaging: 5g
Price: $2600
Updated: 2023/06/20

More

Less

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Chemical Properties,Usage,Production

Uses

Convenient catalyst precursor, for example, with (R,R)QuinoxP* for asymmetric alkylations and hydrogenations.
Catalyst precursor with chiral biaryl bisphosphine ligands for [2+2+2] enantioenriched cycloadditions.

Chemical Properties

dark red

Uses

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate is useful for hydrogenation, isomerization reactions and is also employed as a precursor for asymmetric hydrogenations. Furthermore, it is used in the synthesis of cationic COD-Rhodium complexes with phosphine ligands. In addition, it shows an important application for enantioselective hydrogenation and hydrosilylation.

reaction suitability

core: rhodium
reagent type: catalyst

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Preparation Products And Raw materials

Raw materials

Ethanol Rhodium(III) chloride hydrate Silver tetrafluoroborate Ethyl acetate 1,5-Cyclooctadiene

Preparation Products

More

Less

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Suppliers

Americas 1 Belgium 4 Canada 1 China 171 Europe 1 France 1 Germany 7 India 11 Japan 2 South Korea 1 Spain 1 Switzerland 1 United Kingdom 8 United States 40 Global 250

Ark Pharm, Inc.

Tel: 847-367-3680
Fax: 847-367-3681
Email: sales@arkpharminc.com
Country: United States
ProdList: 1670
Advantage: 56

HBCChem, Inc.

Tel: +1-510-219-6317
Fax: +1-650-486-1361
Email: sales@hbcchem.com
Country: United States
ProdList: 10648
Advantage: 60

Alfa Chemistry

Tel: 1-516-6625404
Fax: 1-516-927-0118
Email: support@alfa-chemistry.com
Country: United States
ProdList: 9171
Advantage: 60

AbaChemScene

Tel: 732-484-9848
Fax: 888-484-5008
Email: sales@chemscene.com
Country: United States
ProdList: 3982
Advantage: 60

Aladdin Scientific

Tel: +1-+1(833)-552-7181
Email: sales@aladdinsci.com
Country: United States
ProdList: 52924
Advantage: 58

Aladdin Scientific

Tel: +1-+1(833)-552-7181
Email: sales@aladdinsci.com
Country: United States
ProdList: 57505
Advantage: 58

Alfa Chemistry

Tel
Email: info@alfa-chemistry.com
Country: United States
ProdList: 2344
Advantage: 58

United States Biological

Tel: --
Fax: --
Email: sales@advtechind.com
Country: United States
ProdList: 6075
Advantage: 58

Glentham Life Sciences Ltd

Tel: --
Fax: --
Email: info@glentham.com
Country: United States
ProdList: 2026
Advantage: 58

SynQuest Laboratories, Inc.,

Tel: --
Fax: --
Country: United States
ProdList: 2301
Advantage: 58

Combi-Blocks, Inc.

Tel: --
Fax: --
Email: les@combi-blocks.com
Country: United States
ProdList: 2555
Advantage: 58

SynQuest Laboratories, Inc. (Part of Central Glass Co., Ltd.)

Tel: --
Fax: --
Email: nfo@synquestlabs.com
Country: United States
ProdList: 1897
Advantage: 58

Beantown Chemical Corporation

Tel: --
Fax: --
Country: United States
ProdList: 396
Advantage: 58

MuseChem (A division of Adv Biolabs, Inc.)

Tel: --
Fax: --
Email: @musechem.com
Country: United States
ProdList: 246
Advantage: 58

Ambeed, Inc.

Tel: --
Fax: --
Email: info@ambeed.com
Country: United States
ProdList: 502
Advantage: 58

Alichem Inc.

Tel: --
Fax: --
Email: sales@alichem.com
Country: United States
ProdList: 6167
Advantage: 58

MilliporeSigma (Sigma-Aldrich Corp.)

Tel: --
Fax: --
Email: @sial.com
Country: United States
ProdList: 5414
Advantage: 58

Colonial Metals, Inc. (part of Ames Goldsmith Co)

Tel: --
Fax: --
Email: istry@colonialmetals.com
Country: United States
ProdList: 8
Advantage: 58

Aurum Pharmatech, LLC

Tel: --
Fax: --
Email: sales@aurumpharmatech.com
Country: United States
ProdList: 498
Advantage: 0

Spectrum Chemical Mfg. Corp.

Tel: --
Fax: --
Email: marketing@spectrumchemical.com
Country: United States
ProdList: 3113
Advantage: 60

American Elements, USA

Tel: --
Fax: --
Email: customerservice@americanelements.com
Country: United States
ProdList: 251
Advantage: 70

Heraeus Incorporated

Tel: --
Fax: --
Email: douglas.joy@heraeus.com
Country: United States
ProdList: 40
Advantage: 58

HBCChem Inc.

Tel: --
Fax: --
Email: sales@hbcchem-inc.com
Country: United States
ProdList: 4569
Advantage: 30

Chem-Impex International, Inc. (CII)

Tel: --
Fax: --
Email: Customer@chemimpex.com
Country: United States
ProdList: 893
Advantage: 58

OChem Incorporation

Tel: --
Fax: --
Email: sales@ocheminc.com
Country: United States
ProdList: 6501
Advantage: 60

VWR International, LLC.

Tel: --
Fax: --
Email: @sargentwelch.com
Country: United States
ProdList: 6262
Advantage: 58

Strem Chemicals, Inc.

Tel: --
Fax: --
Email: info@strem.com
Country: United States
ProdList: 4910
Advantage: 86

United States Biological

Tel: --
Fax: --
Email: chemicals@usbio.net
Country: United States
ProdList: 6214
Advantage: 80

SynQuest Laboratories, Inc.

Tel: --
Fax: --
Email: info@synquestlabs.com
Country: United States
ProdList: 6871
Advantage: 62

Riedel-de Haen AG

Tel: --
Fax: --
Country: United States
ProdList: 6773
Advantage: 87

TCI America

Tel: --
Fax: --
Email: sales@tciamerica.com
Country: United States
ProdList: 6909
Advantage: 75

Matrix Scientific

Tel: --
Fax: --
Email: sales@matrixscientific.com
Country: United States
ProdList: 6632
Advantage: 80

Paradigm Scientific, Inc.

Tel: --
Fax: --
Email: support@paradigmscientific.com
Country: United States
ProdList: 165
Advantage: 50

AK Scientific, Inc.

Tel: --
Fax: --
Email: sales@aksci.com
Country: United States
ProdList: 6347
Advantage: 65

Alfa Aesar

Tel: --
Fax: --
Email: tech@alfa.com
Country: United States
ProdList: 6814
Advantage: 81

Colonial Metals

Tel: --
Fax: --
Email: info@colonialmetals.com
Country: United States
ProdList: 317
Advantage: 61

HONEST JOY HOLDINGS LIMITED

Tel: --
Fax: --
Email: sales@honestjoy.cn
Country: United States
ProdList: 6675
Advantage: 54

APAC Pharmaceutical, LLC

Tel: --
Fax: --
Email: sales@apacpharma.com
Country: United States
ProdList: 6322
Advantage: 38

ChemPacific Corporation

Tel: --
Fax: --
Email: sales@chempacific.com
Country: United States
ProdList: 6891
Advantage: 51

BOSCHE SCIENTIFIC, LLC

Tel: --
Fax: --
Email: Sales@BoscheSci.com
Country: United States
ProdList: 6477
Advantage: 55

More

Less

View Lastest Price from Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate manufacturers

Longyan Tianhua Biological Technology Co., Ltd

Product: Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 35138-22-8
Price: US $20.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000KG
Release date: 2020-11-11

Career Henan Chemical Co

Product: Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 35138-22-8
Price: US $9.80/KG
Min. Order: 1g
Purity: ≥99%
Supply Ability: 100kg
Release date: 2020-01-08

35138-22-8, Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborateRelated Search:

Sodium tetrafluoroborate Octamethylcyclotetrasiloxane Rhodium 1,3-CYCLOOCTADIENE 1,5-Cyclooctadiene Potassium tetrafluoroborate Fluoroboric acid Ammonium fluoborate Dichloro(1,5-cyclooctadiene)palladium(II) methoxy(cyclooctadiene)rhodium(i) dimer Chloro(1,5-cyclooctadiene)iridium(I) dimer Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate BIS(1 5-CYCLOOCTADIENE)RHODIUM(I) Bis(1,5-cyclooctadiene)bis(μ-diphenylphosphido)dirhodium Tris(dibenzylideneacetone)dipalladium Dichloro(1,5-cyclooctadien)ruthenium(II) polymer BIS(1,5-CYCLOOCTADIENE)IRIDIUM (I) TETRAFLUOROBORATE

Bis(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate,98% [Rh(COD)2]BF4

Bis(1,5-cyclooctadiene)rhodium(Ⅰ) tetrafluoroborate

Bis(cycloocta-1,5-diene)rhodium(I) tetrafluoroborate

ooctadiene)rhodium(Ⅰ)tetrafL

(1Z,5Z)-cycloocta-1,5-diene,rhodium,tetrafluoroborate

RHODIUM(I) TETRAFLUOROBORATE 1,5-CYCLOOCTADIENE COMPLEX

Bis(cycloocta-1,5-dien)rhodium(I)-tetrafluoroborat for synthesis

BIS(CYCLOOCTA-1,5-DIEN)RHODIUM(I)-TETRAFLUOROBORATE

BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE

BIS(1,5-CYCLOOCTADIENE)RHODIUM TETRAFLUOROBORATE

BIS(1,5-CYCLOOCTADIEN)RHODIUM(I) TETRAFLUOROBORATE

BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRA&

Bis(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,98+%

Bis(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate Also available as trifluoromethanesulfonate and hexafluorophosphate

Bis(cycloocta-1,5-dien)rho

Bis(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate, [Rh(COD)2]BF4

(1Z,5Z)-cycloocta-1,5-diene,rhodium

Bis(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate 1GR

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate ISO 9001：2015 REACH

Rhodium(1+), bis[(1,2,5,6-η)-1,5-cyclooctadiene]-, tetrafluoroborate(1-) (1:1)

bis[(1,2,5,6-η)-1,5-cyclooctadiene]-Rhodium(1+) tetrafluoroborate(1-) (1:1)

Bis[(1,2,5,6-n)-1,5-cyclooctadiene]-rhodium tetrafluoroborate

dipalladium(II)

35138-22-8

2C8H12BF4Rh

C16H24BF4Rh

C16H24RhBF4

RhC8H122BF

RhCOD2BF4

RhC8H122BF4

C8H6O4XH2O

Catalysis and Inorganic Chemistry

Rh

organometallic complex