Uses in Perfume
ChemicalBook > CAS DataBase List > Ethyl phenylacetate

Ethyl phenylacetate

Uses in Perfume
Product Name
Ethyl phenylacetate
CAS No.
101-97-3
Chemical Name
Ethyl phenylacetate
Synonyms
ethyl 2-phenylacetate;BENZENEACETIC ACID ETHYL ESTER;Ethyl benzeneacetate;PHENYLACETIC ACID ETHYL ESTER;Ethyl phenacetate;ethylbenzeneacetate;Natural Ethyl phenylacetate;FEMA 2452;ETHYL A-TOLUATE;Ethyl α-toluate
CBNumber
CB6701512
Molecular Formula
C10H12O2
Formula Weight
164.2
MOL File
101-97-3.mol
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Ethyl phenylacetate Property

Melting point:
-29 °C
Boiling point:
229 °C(lit.)
Density 
1.03 g/mL at 25 °C(lit.)
vapor pressure 
22.7Pa at 20℃
FEMA 
2452 | ETHYL PHENYLACETATE
refractive index 
n20/D 1.497(lit.)
Flash point:
172 °F
storage temp. 
Store below +30°C.
solubility 
Chloroform (Slightly), Ethyl Acetate (Slightly)
color 
Colourless
Odor
at 10.00 % in dipropylene glycol. sweet floral honey rose balsam cocoa
Odor Type
floral
biological source
synthetic
Water Solubility 
insoluble
Merck 
14,3840
JECFA Number
1009
BRN 
509140
Dielectric constant
5.4（21℃）
InChIKey
DULCUDSUACXJJC-UHFFFAOYSA-N
LogP
2.36 at 22℃
CAS DataBase Reference
101-97-3(CAS DataBase Reference)
NIST Chemistry Reference
Benzeneacetic acid, ethyl ester(101-97-3)
EPA Substance Registry System
Benzeneacetic acid, ethyl ester (101-97-3)
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Safety

Safety Statements 
23-24/25
WGK Germany 
2
RTECS 
AJ2824000
TSCA 
Yes
HS Code 
29163500
Hazardous Substances Data
101-97-3(Hazardous Substances Data)
Toxicity
The acute oral LD50 value in rats was reported as 3.30g/kg(2.52-4.08 g/kg) (Moreno,1973).The acute dermal LD50 in rabbits was reported as > 5g/kg(Moreno, 1973).
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H227Combustible liquid

H303May be harmfulif swallowed

Precautionary statements

P403+P235Store in a well-ventilated place. Keep cool.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
W245230
Product name
Ethyl Phenylacetate
Purity
natural, 98%, FG
Packaging
100g
Price
$286
Updated
2024/03/01
Sigma-Aldrich
Product number
W245230
Product name
Ethyl Phenylacetate
Purity
natural, 98%, FG
Packaging
500g
Price
$1110
Updated
2024/03/01
Sigma-Aldrich
Product number
W245208
Product name
Ethyl Phenylacetate
Purity
≥98%, FCC, FG
Packaging
1kg
Price
$102
Updated
2024/03/01
Sigma-Aldrich
Product number
W245208
Product name
Ethyl Phenylacetate
Purity
≥98%, FCC, FG
Packaging
5kg
Price
$357
Updated
2024/03/01
Sigma-Aldrich
Product number
108049
Product name
Ethyl phenylacetate
Purity
ReagentPlus , 99%
Packaging
250g
Price
$54.1
Updated
2024/03/01
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Ethyl phenylacetate Chemical Properties,Usage,Production

Uses in Perfume

Used in perfume compositions for its mildly animal notes, honey-character and power. In trace amounts, it may impart pleasant nuances in MugueI, Rose, Lily, Sweet Pea, Orangeblossom. Clover, Oriental bases and numerous types of "waxy" odor. In combination with lower alkyl cinnamates and in higher concentration, it creates the typical "low-cost Oriental" note.

Chemical Properties

Ethyl Phenylacetate is a volatile aroma component of fruit and honey. It is a clear colourless to pale yellowish liquid with a pleasant, strong, sweet odor reminiscent of honey and a bittersweet flavor. Small amounts are used in flower perfumes and in fruit flavors.

Occurrence

Reported found in grapefruit juice, apple juice, figs, guava, pineapple, papaya, cognac, cider, grape wines and port wine.

Uses

Ethyl phenylacetate was used to study the solvent-based self-healing of epoxy materials. It is also used as a flavoring agent, flavor animal feeds, In perfumery.

Definition

ChEBI: Ethyl phenylacetate is a member of benzenes. It is a less toxic, greener solvent. It is non-mutagenic.

Preparation

Ethyl phenylacetate is prepared by heating at the boil phenylacetonitrile and sulfuric acid in alcohol solution; by esterification of the acid catalyzed by HCl or H2SO4.

Aroma threshold values

Detection: 650 ppb

Taste threshold values

Taste characteristics at 10 ppm: sweet, fruity, honey, cocoa, apple and woody

General Description

Ethyl phenylacetate is a less toxic, greener solvent. It is non-mutagenic.

Flammability and Explosibility

Non flammable

Biochem/physiol Actions

Taste at 5 to 10 ppm

Safety Profile

Moderately toxic by ingestion. Combustible liquid. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS.

Purification Methods

Shake the ester with saturated aqueous Na2CO3 (three times), aqueous 50% CaCl2 (twice) and saturated aqueous NaCl (twice). Dry with CaCl2 and distil it under reduced pressure. [Beilstein 9 H 434, 9 IV 1618.]

Ethyl phenylacetate Preparation Products And Raw materials

Raw materials

2-Phenylacetamide Benzeneacetonitrile Phenylacetic acid

Preparation Products

1-Phenyl-1-cyclopropanecarboxylic acid ETHYL ALPHA-CHLOROPHENYLACETATE Ethyl alpha-Formyl Benzeneacetic Acid Ester ETHYL A-ETHOXYOXALYLPHENYL ACETATE Diethyl 2-ethyl-2-phenylmalonate Diethyl phenylmalonate Acetamide Phenethyl alcohol Leucoson BUCILLAMINE Phenobarbital 2-PHENYLMALONAMIDE Phenthoate
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View Lastest Price from Ethyl phenylacetate manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Ethyl phenylacetate 101-97-3
Price
US $30.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-04-30
Hebei Mujin Biotechnology Co.,Ltd
Product
Ethyl phenylacetate 101-97-3
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 tons
Release date
2023-06-02
Hebei Mujin Biotechnology Co.,Ltd
Product
Ethyl phenylacetate 101-97-3
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 tons
Release date
2023-06-02

101-97-3, Ethyl phenylacetateRelated Search:

ETHYL P-TOLYLACETATE 2,2-DIMETHYL-5-PHENYL-1,3-DIOXANE-4,6-DIONE Diethyl phenylmalonate ETHYL HOMOVANILLATE Homatropine Hydrobromide BENACTYZINE HYDROCHLORIDE 2,3-DIPHENYLMALEIC ANHYDRIDE ETHYL PHENYLCYANOACETATE 2-PHENYLGLUTARIC ANHYDRIDE Scopolamine hydrobromide Ethyl phenylacetate ETHYL O-TOLYLACETATE ALPHA,ALPHA-DIPHENYL-GAMMA-BUTYROLACTONE 2-Oxo-2-phenylacetic acid ethyl ester O,O-Dimethyl-S-(phenylacetic acid ethyl ester) phosphorodithioate Ethyl 4-bromophenylacetate (R)-2-Hydroxy-2-phenylacetic acid ethyl ester,(2R)-2-Hydroxy-2-phenylacetic acid ethyl ester Ethyl 4-hydroxyphenylacetate

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