trans-1,4-Diaminocyclohexane
- Product Name
- trans-1,4-Diaminocyclohexane
- CAS No.
- 2615-25-0
- Chemical Name
- trans-1,4-Diaminocyclohexane
- Synonyms
- (1r,4r)-cyclohexane-1,4-diaMine;1,4-Cyclohexanediamine;TRANS-1,4-CYCLOHEXANEDIAMINE;cas:2615-25-0;TIMTEC-BB SBB008553;Trans 1,4-Diaminocyc;TRANS-1,4-CYCLOHEXYLDIAMINE;1,4-CyclohexyldiaMine(CHDA);rans-1,4-Diaminocyclohexane;TRANS-1,4-DIAMINOCYCLOHEXANE
- CBNumber
- CB6702524
- Molecular Formula
- C6H14N2
- Formula Weight
- 114.19
- MOL File
- 2615-25-0.mol
trans-1,4-Diaminocyclohexane Property
- Melting point:
- 67-72 °C
- Boiling point:
- 197 °C(lit.)
- Density
- 0.939±0.06 g/cm3(Predicted)
- vapor pressure
- 18 mm Hg ( 87.2 °C)
- Flash point:
- 71 °C
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- solubility
- soluble in Methanol
- pka
- 10.78±0.70(Predicted)
- form
- Crystals or Chunks
- color
- Off-white to brown
- explosive limit
- 6%
- BRN
- 2801657
- InChI
- InChI=1S/C6H14N2/c7-5-1-2-6(8)4-3-5/h5-6H,1-4,7-8H2/t5-,6-
- InChIKey
- VKIRRGRTJUUZHS-IZLXSQMJSA-N
- SMILES
- [C@@H]1(N)CC[C@@H](N)CC1
- CAS DataBase Reference
- 2615-25-0(CAS DataBase Reference)
- EPA Substance Registry System
- 1,4-Cyclohexanediamine, trans- (2615-25-0)
Safety
- Hazard Codes
- C
- Risk Statements
- 22-34-20/21/22
- Safety Statements
- 26-36/37/39-45
- RIDADR
- UN 3259 8/PG 2
- WGK Germany
- 2
- F
- 10-34
- Autoignition Temperature
- 680 °F
- HazardClass
- 8
- PackingGroup
- II
- HS Code
- 29213000
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H302Harmful if swallowed
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P270Do not eat, drink or smoke when using this product.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 32851
- Product name
- trans-1,4-Diaminocyclohexane
- Purity
- ≥98.0% (GC)
- Packaging
- 25g
- Price
- $154
- Updated
- 2024/03/01
- Product number
- 32851
- Product name
- trans-1,4-Diaminocyclohexane
- Purity
- ≥98.0% (GC)
- Packaging
- 100g
- Price
- $214
- Updated
- 2024/03/01
- Product number
- C1426
- Product name
- trans-1,4-Cyclohexanediamine
- Purity
- >98.0%(GC)(T)
- Packaging
- 5g
- Price
- $16
- Updated
- 2024/03/01
- Product number
- C1426
- Product name
- trans-1,4-Cyclohexanediamine
- Purity
- >98.0%(GC)(T)
- Packaging
- 25g
- Price
- $38
- Updated
- 2024/03/01
- Product number
- C1426
- Product name
- trans-1,4-Cyclohexanediamine
- Purity
- >98.0%(GC)(T)
- Packaging
- 100g
- Price
- $112
- Updated
- 2024/03/01
trans-1,4-Diaminocyclohexane Chemical Properties,Usage,Production
Chemical Properties
off-white to brown crystals or chunks
Uses
trans-1,4-diaminocyclohexane be used as organic intermediates and epoxy curing agents.
Uses
trans-1,4-Diaminocyclohexane was used in preparation of fully aliphatic polyimides. It was employed as the structure-directing agent in the synthesis of novel two-dimensional layered zinc phosphate.
Synthesis
Cyclohexane-1,4-diamine is one of several produced when p-phenylene diamine is hydrogenated on nickel or cobalt catalysts in methylcyclohexane or dioxane or decaline at 180° C./100 or 150 atmospheres. Trans-1,4-Diaminocyclohexane can be obtained from this isomeric mixture by fractional crystallization as described in U.S. Pat. No. 3,657,345, but several crystallizations are required to achieve this.
A process is disclosed for selectively making trans-1,4-Diaminocyclohexane by reacting ammonia with a mixture of cis and trans-cyclohexane-1,4-dicarboxylic acid, a lower alkyl ester, a glycol ester, an oligomeric ester or a polyester to make a solid trans-dicarboxylic acid diamide in a first step. The diamide is chlorinated to form trans-cyclohexane-1,4-dicarboxylic acid-bis-N-chloramide. The latter compound is then converted into a trans-1,4-Diaminocyclohexane with an alkali or alkaline earth metal hydroxide.
Purification Methods
Recrystallise the diamine from pet ether under N2 or Ar as it should be an even stronger base than the above 1,2-diamine isomers. It distils under N2. Store in the dark under N2. [Beistein 13 I 3, 13 III 11.]
trans-1,4-Diaminocyclohexane Preparation Products And Raw materials
Raw materials
Preparation Products
trans-1,4-Diaminocyclohexane Suppliers
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- Country
- United Kingdom
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- Country
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View Lastest Price from trans-1,4-Diaminocyclohexane manufacturers
- Product
- trans-1,4-Diaminocyclohexane 2615-25-0
- Price
- US $0.00-0.00/KG
- Min. Order
- 0.5KG
- Purity
- 99%
- Supply Ability
- 100kg
- Release date
- 2024-01-05
- Product
- trans-1,4-Diaminocyclohexane 2615-25-0
- Price
- US $0.00-0.00/KG
- Min. Order
- 1g
- Purity
- 98%min
- Supply Ability
- 100kgs/month
- Release date
- 2021-11-21
- Product
- trans-1,4-Diaminocyclohexane 2615-25-0
- Price
- US $1.00/kg
- Min. Order
- 1kg
- Purity
- 98%min
- Supply Ability
- 1000kg
- Release date
- 2018-12-18