ChemicalBook > CAS DataBase List > 3-BROMO-2-CHLORO-5-NITRO-6-PICOLINE

3-BROMO-2-CHLORO-5-NITRO-6-PICOLINE

Product Name
3-BROMO-2-CHLORO-5-NITRO-6-PICOLINE
CAS No.
856834-95-2
Chemical Name
3-BROMO-2-CHLORO-5-NITRO-6-PICOLINE
Synonyms
3-bromo-2-chloro-5-nitro-6-picolin;5-Bromo-6-chloro-3-nitro-2-picoline;3-BROMO-2-CHLORO-5-NITRO-6-PICOLINE;2-Picoline, 5-bromo-6-chloro-3-nitro-;Chloro-3-bromo-5-nitro-6-methylpyridine;3-Bromo-2-chloro-6-methyl-5-nitropyridine;3-Bromo-2-chloro-5-nitro-6-methylpyridine;2-Chloro-3-bromo-5-nitro-6-methylpyridine;Pyridine, 3-bromo-2-chloro-6-methyl-5-nitro-;3-BROMO-2-CHLORO-5-NITRO-6-PICOLINE ISO 9001:2015 REACH
CBNumber
CB71093017
Molecular Formula
C6H4BrClN2O2
Formula Weight
251.47
MOL File
Mol file
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3-BROMO-2-CHLORO-5-NITRO-6-PICOLINE Property

Melting point:
93℃
Boiling point:
296℃
Density 
1.810
Flash point:
133℃
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
solid
pka
-4.03±0.10(Predicted)
Appearance
Off-white to light yellow Solid
InChI
InChI=1S/C6H4BrClN2O2/c1-3-5(10(11)12)2-4(7)6(8)9-3/h2H,1H3
InChIKey
WKGHUAZJNBXABN-UHFFFAOYSA-N
SMILES
C1(Cl)=NC(C)=C([N+]([O-])=O)C=C1Br
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Safety

HS Code 
2933399990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
CDS021075
Product name
3-Bromo-2-chloro-6-methyl-5-nitropyridine
Packaging
25 mg
Price
$107
Updated
2025/07/31
TRC
Product number
B684563
Product name
3-Bromo-2-chloro-5-nitro-6-picoline
Packaging
50mg
Price
$55
Updated
2021/12/16
ChemScene
Product number
CS-0019331
Product name
2-Picoline,5-bromo-6-chloro-3-nitro-
Purity
99.23%
Packaging
5g
Price
$80
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB141897
Product name
3-Bromo-2-chloro-6-methyl-5-nitropyridine
Packaging
50mg
Price
$80
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB141897
Product name
3-Bromo-2-chloro-6-methyl-5-nitropyridine
Packaging
250mg
Price
$250
Updated
2021/12/16
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3-BROMO-2-CHLORO-5-NITRO-6-PICOLINE Chemical Properties,Usage,Production

Chemical Properties

light yellow crystal powder

Synthesis

874493-25-1

856834-95-2

3-Bromo-6-methyl-5-nitropyridin-2-ol (9.2 g, 36.7 mmol) was used as starting material, which was dissolved in phosphorus oxychloride (POCl3, 56.2 g, 366.7 mmol). The reaction mixture was stirred and reacted at 80 °C overnight. Upon completion of the reaction, the mixture was slowly poured into water (800 mL) and the solid product was precipitated. The solid was collected by filtration and dried to afford the target compound 3-bromo-2-chloro-5-nitro-6-methylpyridine (7.5 g, 81.4% yield).

References

[1] Patent: US2018/170909, 2018, A1. Location in patent: Paragraph 1925; 1926
[2] Patent: WO2015/89192, 2015, A1. Location in patent: Paragraph 00275; 00276
[3] Patent: WO2016/37005, 2016, A1. Location in patent: Paragraph 00259-00260
[4] Patent: WO2008/101682, 2008, A2. Location in patent: Page/Page column 42-43

3-BROMO-2-CHLORO-5-NITRO-6-PICOLINE Preparation Products And Raw materials

Raw materials

Preparation Products

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3-BROMO-2-CHLORO-5-NITRO-6-PICOLINE Suppliers

Accela ChemBio Inc.
Tel
+1-858-6993322
Fax
(+1)-858-876-1948
Email
info@accelachem.com
Country
United States
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21193
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58
Aladdin Scientific
Tel
Email
tp@aladdinsci.com
Country
United States
ProdList
52923
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58
Synthonix Inc
Tel
--
Fax
--
Email
info@synthonix.com
Country
United States
ProdList
6872
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58
Combi-Blocks Inc.
Tel
--
Fax
--
Email
sales@combi-blocks.com
Country
United States
ProdList
6618
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69
SynQuest Laboratories, Inc.
Tel
--
Fax
--
Email
info@synquestlabs.com
Country
United States
ProdList
6871
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Matrix Scientific
Tel
--
Fax
--
Email
sales@matrixscientific.com
Country
United States
ProdList
6632
Advantage
80
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View Lastest Price from 3-BROMO-2-CHLORO-5-NITRO-6-PICOLINE manufacturers

Shaanxi Dideu New Materials Co. Ltd
Product
3-BROMO-2-CHLORO-5-NITRO-6-PICOLINE 856834-95-2
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98.0%
Supply Ability
10000KGS
Release date
2025-06-03
Shaanxi Dideu Medichem Co. Ltd
Product
3-bromo-2-chloro-5-nitro- 6-picoline 856834-95-2
Price
US $1.00-1.00/Kg/Drum
Min. Order
1g
Purity
99%
Supply Ability
50tons
Release date
2020-05-13
Henan Fengda Chemical Co., Ltd
Product
3-BROMO-2-CHLORO-5-NITRO-6-PICOLINE 856834-95-2
Price
US $5.00-0.10/KG
Min. Order
1KG
Purity
98%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-04-08

856834-95-2, 3-BROMO-2-CHLORO-5-NITRO-6-PICOLINERelated Search:


  • 3-BROMO-2-CHLORO-5-NITRO-6-PICOLINE
  • 3-Bromo-2-chloro-6-methyl-5-nitropyridine
  • 5-Bromo-6-chloro-3-nitro-2-picoline
  • 3-bromo-2-chloro-5-nitro-6-picolin
  • 2-Picoline, 5-bromo-6-chloro-3-nitro-
  • 2-Chloro-3-bromo-5-nitro-6-methylpyridine
  • Pyridine, 3-bromo-2-chloro-6-methyl-5-nitro-
  • 3-BROMO-2-CHLORO-5-NITRO-6-PICOLINE ISO 9001:2015 REACH
  • 3-Bromo-2-chloro-5-nitro-6-methylpyridine
  • Chloro-3-bromo-5-nitro-6-methylpyridine
  • 856834-95-2