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Raubasine

Product Name
Raubasine
CAS No.
483-04-5
Chemical Name
Raubasine
Synonyms
Tensyl;Sarpan;Vincain;Vincein;Lamuran;Ranitol;RAUBASIN;Vinceine;Vincaine;Raubasil
CBNumber
CB7129678
Molecular Formula
C21H24N2O3
Formula Weight
352.43
MOL File
483-04-5.mol
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Raubasine Property

Melting point:
258°C (rough estimate)
Boiling point:
486.04°C (rough estimate)
alpha 
D20 -60° (c = 0.5 in chloroform); D20 -45° (c = 0.5 in pyridine); D20 -39° (c = 0.25 in methanol)
Density 
1.1823 (rough estimate)
refractive index 
1.6500 (estimate)
storage temp. 
2-8°C
solubility 
Chloroform (Slightly), Methanol (Slightly, Heated)
form 
Solid
pka
pK1:10.55(+1) (25°C)
color 
Pale Yellow
optical activity
[α]/D -65±3°, c = 1 in chloroform
Water Solubility 
insoluble in water
BRN 
97268
LogP
2.880 (est)
NIST Chemistry Reference
Ajmalicine(483-04-5)
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Safety

Hazard Codes 
Xn
Risk Statements 
25-22
Safety Statements 
22-45
RIDADR 
1544
WGK Germany 
3
RTECS 
AX7875000
HazardClass 
6.1(b)
PackingGroup 
III
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H300Fatal if swallowed

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
41111
Product name
Ajmalicine
Purity
≥98.0% (HPLC)
Packaging
50mg
Price
$112.4
Updated
2024/03/01
Sigma-Aldrich
Product number
41111
Product name
Ajmalicine
Purity
≥98.0% (HPLC)
Packaging
10mg
Price
$77.7
Updated
2023/06/20
Sigma-Aldrich
Product number
R751618
Product name
AJMALICINE
Purity
AldrichCPR
Packaging
50MG
Price
$97.9
Updated
2022/05/15
TRC
Product number
R127000
Product name
Raubasine
Packaging
50mg
Price
$185
Updated
2021/12/16
Usbiological
Product number
288595
Product name
Raubasine
Packaging
5g
Price
$345
Updated
2021/12/16
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Raubasine Chemical Properties,Usage,Production

Description

Vinca rosea L. yields this alkaloid which crystallizes as colourless needles from MeOH. The base is laevorotatory having a specific rotation of [α]D_620 (MeOH) and forms a crystalline hydrochloride, m.p. 281-3°e. The structure given above has been elucidated from chemical and spectroscopic data.

Uses

Antihypertensive, anti-ischemic.

Uses

Antihypertensive, anti-ischemic (cerebral and peripheral)

Definition

ChEBI: Ajmalicine is a monoterpenoid indole alkaloid with formula C21H24N2O3, isolated from several Rauvolfia and Catharanthus species. It is a selective alpha1-adrenoceptor antagonist used for the treatment of high blood pressure. It has a role as an antihypertensive agent, an alpha-adrenergic antagonist and a vasodilator agent. It is a monoterpenoid indole alkaloid, a methyl ester and an organic heteropentacyclic compound. It is a conjugate base of an ajmalicine(1+).

target

P450 (e.g. CYP17)

Purification Methods

It crystallises from MeOH, EtOH or EtOAc. [Beilstein 27 III/IV 7927.]

References

Janot, Le Men, Cornpt. Rend., 243, 1786 (1956) Shamma, Moss, J. Arner. Chern. Soc., 83, 5038 (1961) Abdurakhsimova, Yuldashev, Yunusov, Khirn. Prir. Soedin., 1,224 (1965)

Raubasine Preparation Products And Raw materials

Raw materials

Preparation Products

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Raubasine Suppliers

Wako Pure Chemical Industries, Ltd.
Tel
--
Fax
--
Email
labchem-tec@wako-chem.co.jp
Country
Japan
ProdList
6819
Advantage
80
Nacalai Tesque, Inc.
Tel
--
Fax
--
Email
info-tech@nacalai.co.jp
Country
Japan
ProdList
6046
Advantage
75
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View Lastest Price from Raubasine manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
Raubasine 483-04-5
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-07
Hebei Fengqiang Trading Co., LTD
Product
Raubasine 483-04-5
Price
US $100.00/bag
Min. Order
1bag
Purity
99
Supply Ability
5000
Release date
2023-09-14
Henan Bao Enluo International TradeCo.,LTD
Product
Raubasine 483-04-5
Price
US $50.00/kg
Min. Order
1kg
Purity
99.9%
Supply Ability
10000MT
Release date
2023-08-17

483-04-5, RaubasineRelated Search:


  • RAUBASIN
  • RAUBASINE
  • YOHIMBINE, C-
  • , 7-[3-hydroxy-2-(3-hydroxy-1-octenyl)-5-oxocyclopentyl]-
  • 16,17-Didehydro-19alpha-methyloxayohimban-16-carboxylic acid methyl ester
  • 16,17-Didehydro-19-methyloxayohimban-16-carboxylic acid methyl ester
  • 16,17-didehydro-19-methyloxayohimban-16-carboxylicacidmethylester
  • 19-Epiajmalicine
  • 4H-Indolo[2,3-a]pyrano[3,4-g]quinolizine, oxayohimban-16-carboxylic acid deriv.
  • Ajmalicin
  • Alkaloid C
  • Alkaloid F
  • Alkaloid II
  • substanceii
  • Tensyl
  • Tetrahydroserpentine
  • Vincain
  • Vincein
  • Vinceine
  • Vinceinen
  • D-YOHIMBINE
  • ALPHA-YOHIMBIN
  • AJMALICINE
  • AJMALICINE(-YOHIMBINE)
  • AJMALICINE HCl(RG)
  • Ajmalicine (base and/or unspecified salts)
  • (19alpha)-16,17-Didehydro-19-methyloxayohimban-16-carboxylic acid methyl ester
  • Vincaine
  • (19α)-16,17-Didehydro-19-Methyl-oxayohiMban-16-carboxylic Acid Methyl Ester
  • NSC 72133
  • NSC 95087
  • TETRAHYDROALSTONINE; AJMALICINE
  • alkaloidc
  • alkaloidf
  • alkaloidii
  • Circolene
  • delta-Yohimbine
  • gamma-Yohimbine
  • Hydrosarpan
  • Isoarteril
  • Lamuran
  • Methyl 19-methyl-16,17-didehydrooxayohimban-16-carboxylate
  • Oxayohimban-16-carboxylic acid, 16,17-didehydro-19-methyl-, methyl ester, (19alpha)-
  • oxayohimban-16-carboxylicacid,16,17-didehydro-19-methyl-,methylester,(19
  • Py-tetrahydroserpentine
  • Ranitol
  • Raubaserp
  • Raubasil
  • Raumalina
  • Rauvasan
  • Sarpan
  • Substance II
  • Oxayohimban-16-carboxylic acid, 16,17-didehydro-19-methyl-, methylester, (19a)-
  • Raubasine USP/EP/BP
  • (4S,4aR,13bS,14aS)-Methyl 4-methyl-4a,5,7,8,13,13b,14,14a-octahydro-4H-indolo[2,3-a]pyrano[3,4-g]quinolizine-1-carboxylate
  • Vinceine (Raubasine)
  • Ajmalicine pure, 98%
  • Oxayohimban-16-carboxylic acid, 16,17-didehydro-19-methyl-, methyl ester, (19α)-