3-(METHOXYMETHYL)BENZOIC ACID
- Product Name
- 3-(METHOXYMETHYL)BENZOIC ACID
- CAS No.
- 32194-76-6
- Chemical Name
- 3-(METHOXYMETHYL)BENZOIC ACID
- Synonyms
- Benzoic acid, 3-(MethoxyMethyl)-;3-(methoxymethyl)benzoic acid(SALTDATA: FREE)
- CBNumber
- CB71490557
- Molecular Formula
- C9H10O3
- Formula Weight
- 166.17
- MOL File
- 32194-76-6.mol
3-(METHOXYMETHYL)BENZOIC ACID Property
- Melting point:
- 64-66 °C
- Boiling point:
- 120-126 °C(Press: 0.1 Torr)
- Density
- 1.177±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- pka
- 4.12±0.10(Predicted)
- Appearance
- White to off-white Solid
Safety
- HazardClass
- IRRITANT
- HS Code
- 2918999090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 3575AB
- Product name
- 3-(Methoxymethyl)benzoicacid
- Packaging
- 1g
- Price
- $334
- Updated
- 2021/12/16
- Product number
- 053776
- Product name
- 3-(Methoxymethyl)benzoic acid
- Packaging
- 1g
- Price
- $350
- Updated
- 2021/12/16
- Product number
- CHM0085476
- Product name
- 3-(METHOXYMETHYL)BENZOIC ACID
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $852.55
- Updated
- 2021/12/16
- Product number
- 053776
- Product name
- 3-(Methoxymethyl)benzoic acid
- Packaging
- 5g
- Price
- $975
- Updated
- 2021/12/16
- Product number
- CHM0085476
- Product name
- 3-(METHOXYMETHYL)BENZOIC ACID
- Purity
- 95.00%
- Packaging
- 2.5G
- Price
- $1227.82
- Updated
- 2021/12/16
3-(METHOXYMETHYL)BENZOIC ACID Chemical Properties,Usage,Production
Synthesis
124-41-4
1129-28-8
32194-76-6
a) Synthesis of 3-(methoxymethyl)benzoic acid: Sodium methanol (0.74 g, 13.8 mmol) was added to a solution of methyl 3-bromomethylbenzoate (1129-28-8, 1.05 g, 4.6 mmol) in anhydrous methanol (30 mL) under argon protection and room temperature. The resulting suspension was stirred and reacted at 50 °C for 2 h. Subsequently, 5 M aqueous potassium hydroxide solution was added and stirring was continued for 1.5 h at 50 °C. The reaction mixture was cooled to room temperature and the pH was adjusted to 2-3 with aqueous hydrochloric acid.The aqueous phase was extracted with ethyl acetate, the organic phases were combined and dried over anhydrous sodium sulfate. The solvent was removed by concentration under reduced pressure to give the target product 3-(methoxymethyl)benzoic acid as a colorless oil (749 mg, 96% yield).LCMS analysis: retention time RtB = 2.47 min; [M + H]+ = 167.0.
References
[1] Patent: US2012/101110, 2012, A1. Location in patent: Page/Page column 70
[2] Patent: US2012/165331, 2012, A1. Location in patent: Page/Page column 27-28
[3] Patent: WO2012/101487, 2012, A1. Location in patent: Page/Page column 65; 66
3-(METHOXYMETHYL)BENZOIC ACID Preparation Products And Raw materials
Raw materials
Preparation Products
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