Dimethyl 5-nitroisophthalate
Uses- Product Name
- Dimethyl 5-nitroisophthalate
- CAS No.
- 13290-96-5
- Chemical Name
- Dimethyl 5-nitroisophthalate
- Synonyms
- 5-NITROISOPHTHALIC ACID DIMETHYL ESTER;Dimethyl- 5–Nitroisophathalate;5-NIPA-DME;Iohexol Impurity R;Dimethyl-5-nitrophthalate;DIMETHYLNITROISOPHTHALATE-5;Dimethyl-5itroisophathalate;DIMETHYL 5-NITROISOPHTHALATE;Dimethyl5-Nitromisophthalate;5-NITRO DIMETHYL ISOPHTHALATE
- CBNumber
- CB9205602
- Molecular Formula
- C10H9NO6
- Formula Weight
- 239.18
- MOL File
- 13290-96-5.mol
Dimethyl 5-nitroisophthalate Property
- Melting point:
- 123-125 °C (lit.)
- Boiling point:
- 381.83°C (rough estimate)
- Density
- 1.4504 (rough estimate)
- refractive index
- 1.5310 (estimate)
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- soluble in Toluene
- form
- powder to crystal
- color
- White to Light yellow
- BRN
- 2140916
- InChI
- InChI=1S/C10H9NO6/c1-16-9(12)6-3-7(10(13)17-2)5-8(4-6)11(14)15/h3-5H,1-2H3
- InChIKey
- GGTSJKFPGKFLCZ-UHFFFAOYSA-N
- SMILES
- C1(C(OC)=O)=CC([N+]([O-])=O)=CC(C(OC)=O)=C1
- CAS DataBase Reference
- 13290-96-5(CAS DataBase Reference)
- NIST Chemistry Reference
- 1,3-Benzenedicarboxylic acid, 5-nitro-, dimethyl ester(13290-96-5)
- EPA Substance Registry System
- Dimethyl 5-nitroisophthalate (13290-96-5)
Safety
- Hazard Codes
- Xn
- Risk Statements
- 20/21/22
- Safety Statements
- 22-24/25-36
- RIDADR
- UN 2811
- WGK Germany
- 2
- RTECS
- CZ4340000
- TSCA
- Yes
- HS Code
- 29173990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H332Harmful if inhaled
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 237361
- Product name
- Dimethyl 5-nitroisophthalate
- Purity
- 98%
- Packaging
- 25g
- Price
- $34.6
- Updated
- 2023/06/20
- Product number
- N0567
- Product name
- Dimethyl 5-Nitroisophthalate
- Packaging
- 25g
- Price
- $27
- Updated
- 2025/07/31
- Product number
- N0567
- Product name
- Dimethyl 5-Nitroisophthalate
- Packaging
- 500g
- Price
- $181
- Updated
- 2025/07/31
- Product number
- D480553
- Product name
- Dimethyl 5-nitroisophthalate
- Packaging
- 50g
- Price
- $75
- Updated
- 2021/12/16
- Product number
- FD34167
- Product name
- Dimethyl 5-nitroisophthalate
- Packaging
- 2Kg
- Price
- $250
- Updated
- 2021/12/16
Dimethyl 5-nitroisophthalate Chemical Properties,Usage,Production
Uses
Dimethyl 5-Nitroisophthalate is a useful chemical in organic synthesis.
Chemical Properties
slightly yellow fine crystalline powder
Uses
Dimethyl 5-nitroisophthalate has been used as starting reagent in the synthesis of 5-nitro-1,3-bis(ethylenediamine) and 5-nitroisophthaldihydrazide.
Synthesis
67-56-1
618-88-2
13290-96-5
In a 100 mL three-necked round-bottomed flask equipped with a condenser tube, an electric stirrer and a thermometer, 5.0 g of 5-nitroisophthalic acid and 33.3 mL of methanol were added sequentially. The mixture was stirred under nitrogen protection at room temperature for about 3 minutes until the solid was completely dissolved to give a colorless transparent solution. Subsequently, 1.0 mL of concentrated sulfuric acid was slowly added dropwise and heated to reflux, and after the reaction for about 3 hours, white solid precipitation was observed. The progress of the reaction was monitored by thin layer chromatography (TLC, unfolding agent ratio of dichloromethane:methanol=10:1). Upon completion of the reaction, it was cooled to room temperature, crystals were precipitated and the solid product was collected by filtration. The filter cake was washed with deionized water and finally mixed with a small amount of water and dried to obtain dimethyl 5-nitroisophthalate. The product yield was 98%.
References
[1] Patent: CN105254521, 2016, A. Location in patent: Paragraph 0025
[2] Journal of the Chemical Society, 1905, vol. 87, p. 1265
[3] Journal fuer Praktische Chemie (Leipzig), 1882, vol. <2> 25, p. 491
[4] Patent: US2005/281746, 2005, A1. Location in patent: Page/Page column 15-16
Dimethyl 5-nitroisophthalate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Dimethyl 5-nitroisophthalate manufacturers
- Product
- Dimethyl 5-nitroisophthalate 13290-96-5
- Price
- US $13.95/Kg/Drum
- Min. Order
- 25Kg/Drum
- Purity
- 99.00%HPLC
- Supply Ability
- 10tons/month
- Release date
- 2021-09-23
- Product
- Dimethyl 5-Nitroisophthalate 13290-96-5
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10mt
- Release date
- 2025-03-10
- Product
- Dimethyl 5-Nitroisophthalate 13290-96-5
- Price
- US $5.00-2.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10000kg
- Release date
- 2024-08-21