ChemicalBook > CAS DataBase List > 4''-PROPYL-3-FLUOROBIPHENYL-4-BORONIC ACID

4''-PROPYL-3-FLUOROBIPHENYL-4-BORONIC ACID

Product Name
4''-PROPYL-3-FLUOROBIPHENYL-4-BORONIC ACID
CAS No.
909709-42-8
Chemical Name
4''-PROPYL-3-FLUOROBIPHENYL-4-BORONIC ACID
Synonyms
3-Fluoro-4'-n-propylbiphenyl-4-boronic;3-Fluoro-4'-propyl-biphenylboronic acid;3-Fluoro-4'-propyl-4-biphenylboronic Acid;3-Fluoro-4'-propylbiphenyl-4-boronic acid;4''-PROPYL-3-FLUOROBIPHENYL-4-BORONIC ACID;4'-Propyl-3-fluoro-biphenyl-4-boronic acid;3-Fluoro-4'-n-propylbiphenyl-4-boronic acid;(3-fluoro-4'-propyl-4-biphenylyl)boronic acid;[3-Fluoro-4'-propylbiphenyl-4-yl]boronic acid;4-Propyl-3'-Fluorobiphenyl-4'-Boronic Acid N
CBNumber
CB71519232
Molecular Formula
C15H16BFO2
Formula Weight
258.1
MOL File
909709-42-8.mol
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4''-PROPYL-3-FLUOROBIPHENYL-4-BORONIC ACID Property

Boiling point:
412.5±55.0 °C(Predicted)
Density 
1.17±0.1 g/cm3(Predicted)
vapor pressure 
0-0.004Pa at 20-50℃
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
pka
8.41±0.58(Predicted)
form 
Solid
color 
White to Light yellow
Water Solubility 
Slightly soluble in water.
InChI
InChI=1S/C15H16BFO2/c1-2-3-11-4-6-12(7-5-11)13-8-9-14(16(18)19)15(17)10-13/h4-10,18-19H,2-3H2,1H3
InChIKey
XZGCBSYWWZAXRC-UHFFFAOYSA-N
SMILES
B(C1=CC=C(C2=CC=C(CCC)C=C2)C=C1F)(O)O
LogP
4.9 at 25℃ and pH6.4
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Safety

HS Code 
2931900090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical
Product number
F0942
Product name
3-Fluoro-4'-propyl-4-biphenylboronic Acid (contains varying amounts of Anhydride)
Packaging
1g
Price
$66
Updated
2025/07/31
TCI Chemical
Product number
F0942
Product name
3-Fluoro-4'-propyl-4-biphenylboronic Acid (contains varying amounts of Anhydride)
Packaging
5g
Price
$224
Updated
2025/07/31
TRC
Product number
P835268
Product name
4''-Propyl-3-fluoro-biphenyl-4-boronicacid
Packaging
500mg
Price
$185
Updated
2021/12/16
TRC
Product number
P835268
Product name
4''-Propyl-3-fluoro-biphenyl-4-boronicacid
Packaging
1g
Price
$265
Updated
2021/12/16
TRC
Product number
P835268
Product name
4''-Propyl-3-fluoro-biphenyl-4-boronicacid
Packaging
100mg
Price
$60
Updated
2021/12/16
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4''-PROPYL-3-FLUOROBIPHENYL-4-BORONIC ACID Chemical Properties,Usage,Production

Chemical Properties

White powder

Uses

4''-Propyl-3-fluoro-biphenyl-4-boronic acid

Synthesis

5419-55-6

948044-01-7

909709-42-8

The general procedure for the synthesis of (3-fluoro-4'-propyl-[1,1'-biphenyl]-4-yl)boronic acid from triisopropyl borate and 3-fluoro-4-propylbiphenyl was as follows: 3-fluoro-4-propylbiphenyl (22.2 g, 0.104 mol) and 150 mL of tetrahydrofuran were added to a reaction vessel equipped with a dropping funnel. The mixture was heated to 70 °C, followed by the slow dropwise addition of 124 mL of sec-butyllithium solution (1.0 mol/L). The reaction mixture was stirred at 70 °C for 2 h. Triisopropyl borate (25.3 g, 0.135 mol) was added dropwise. After continued stirring for 2 hours, the reaction mixture was cooled to 0 °C and 300 mL of 10% hydrochloric acid solution was added slowly and dropwise. After stirring for 1 h at room temperature, aqueous washing was performed to remove the salts. Eventually, by concentration and drying treatment, (3-fluoro-4'-propyl-[1,1'-biphenyl]-4-yl)boronic acid (25.7 g, 0.0995 mol) was obtained.

References

[1] Patent: JP2015/110531, 2015, A. Location in patent: Paragraph 0108; 0110

4''-PROPYL-3-FLUOROBIPHENYL-4-BORONIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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4''-PROPYL-3-FLUOROBIPHENYL-4-BORONIC ACID Suppliers

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View Lastest Price from 4''-PROPYL-3-FLUOROBIPHENYL-4-BORONIC ACID manufacturers

Henan Aochuang Chemical Co.,Ltd.
Product
4''-PROPYL-3-FLUOROBIPHENYL-4-BORONIC ACID 909709-42-8
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1ton
Release date
2022-10-18
Shanghai Daken Advanced Materials Co.,Ltd
Product
(3-fluoro-4'-propyl-[1,1'-biphenyl]-4-yl)boronic acid 909709-42-8
Price
US $0.00/KG
Min. Order
1KG
Purity
98.00%
Supply Ability
1000KG/month
Release date
2021-11-04
Henan Fengda Chemical Co., Ltd
Product
4''-PROPYL-3-FLUOROBIPHENYL-4-BORONIC ACID 909709-42-8
Price
US $34.00-1.20/kg
Min. Order
1kg
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-04-08

909709-42-8, 4''-PROPYL-3-FLUOROBIPHENYL-4-BORONIC ACIDRelated Search:

2,3-Difluorobenzyl bromide 2,3-Difluorobenzoic acid 2,3-Difluoroanisole 4-PHENOXYPHENYLBORONIC ACID 9,9-Dimethyl-9H-fluoren-2-yl-boronic acid 2,3-Difluoro-4-ethoxybenzeneboronic acid 3,4,5-Trifluorophenylboronic acid 4-Chloro-2-fluoro-3-methoxyphenylboronic acid 4-(Hydroxymethyl)phenylboronic acid 3-Carboxyphenylboronic acid 3-Tolylboronic acid 1-Methyl-4-pyrazole boronic acid pinacol ester 4'-Butyl-3-fluorobiphenyl-4-boronic acid 2,3-DIFLUORO-4'-PENTYLBIPHENYL-4-BORONIC ACID 4''-PROPYL-3-FLUOROBIPHENYL-4-BORONIC ACID 4''-PENTYL-3-FLUOROBIPHENYL-4-BORONIC ACID 2,3-DIFLUORO-4'-HEPTYLBIPHENYL-4-BORONIC ACID 3-FLUORO-4'-HEPTYLBIPHENYL-4-BORONIC ACID

  • 4''-PROPYL-3-FLUOROBIPHENYL-4-BORONIC ACID
  • 3-Fluoro-4'-propyl-biphenylboronic acid
  • (3-Fluoro-4'-propyl[1,1'-biphenyl]-4-yl)boronic acid
  • BORONIC ACID,B-(3-FLUORO-4'-PROPYL[1,1'-BIPHENYL]-4-YL)-
  • 3-Fluoro-4'-n-propylbiphenyl-4-boronic acid, 98%
  • 3-Fluoro-4'-propyl-4-biphenylboronic Acid
  • (3-fluoro-4'-propyl-4-biphenylyl)boronic acid
  • 3-Fluoro-4＇-alkyl[1,1＇-biphenyl]-4-yl）-boronic acid
  • [2-Fluoro-4-(4-propylphenyl)phenyl]boronic acid
  • [3-Fluoro-4'-propylbiphenyl-4-yl]boronic acid
  • 3-Fluoro-4'-propyl-4-biphenylboronic Acid (contains varying amounts of Anhydride)
  • 3-Fluoro-4'-n-propylbiphenyl-4-boronic
  • 3-fluorine-4-(4-propylphenyl)benzeneboronic acid
  • 3-Fluoro-4'-propylbiphenyl-4-boronic acid
  • 4-Propyl-3'-Fluorobiphenyl-4'-Boronic Acid N
  • 4'-Propyl-3-fluoro-biphenyl-4-boronic acid
  • (3-Fluoro-4'-propyl-[1,1'-biphenyl]-4-yl)boronic acid
  • 3-Fluoro-4'-n-propylbiphenyl-4-boronic acid
  • Boronicacid,B-(3-fluoro-4'-propyl[1,1'-biphenyl]-4-yl)-
  • (3-fluoro-4'-propyl[biphenyl]-4-yl)boronic acid
  • Boronic acid, B-(3-fluoro-4'-propyl[1,1'-biphenyl]-4-yl)-
  • 4′-Propyl-3-fluorobiphenyl-4-boronic acid, CAS 909709-42-8
  • 909709-42-8
  • C15H16BFO2