2-Iodoanisole Property

Melting point:

588.5 °C

Boiling point:

125-126 °C19 mm Hg(lit.)

Density 

1.799 g/mL at 25 °C(lit.)

refractive index 

n20/D 1.622(lit.)

Flash point:

>110°C

storage temp. 

Keep in dark place,Sealed in dry,Room Temperature

solubility 

alcohol: miscible(lit.)

form 

Liquid

color 

Clear yellow

Specific Gravity

1.799

Water Solubility 

insoluble

Sensitive 

Light Sensitive

Merck 

14,5028

BRN 

1860243

CAS DataBase Reference

529-28-2(CAS DataBase Reference)

NIST Chemistry Reference

2-Iodoanisole(529-28-2)

EPA Substance Registry System

Benzene, 1-iodo-2-methoxy- (529-28-2)

Safety

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26-36

WGK Germany 

3

F 

8

TSCA 

Yes

HS Code 

29093090

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

2-Iodoanisole Chemical Properties,Usage,Production

Chemical Properties

Clear yellow liquid

Uses

suzuki reaction

Uses

2-Iodoanisole has been used in palladium/copper-catalyzed synthesis of o-(1-alkynyl)anisoles.

Definition

ChEBI: An organoiodine compound that is iodobenzene substituted by methoxy group at psotion 2.

General Description

2-Iodoanisole participates in palladium catalyzed enantioselective Heck arylation of 2,3-dihydrofuran in the presence of chiral ionic liquids containing L-prolinate and L-lactate anions and non-chiral quaternary ammonium cations.