Piperonylic acid

Product Name: Piperonylic acid
CAS No.: 94-53-1
Chemical Name: Piperonylic acid
Synonyms: Benzo[d][1,3]dioxole-5-carboxylic acid;Heliotropic acid;1,3-BENZODIOXOLE-5-CARBOXYLIC ACID;PIPEROYLICACID;3,4-(METHYLENEDIOXY)BENZOIC ACID;AKOS 213-90;Pepper acid;heliotropicacid;PIPERONYLIC ACID;PiperonylicAcid>
CBNumber: CB7162666
Molecular Formula: C8H6O4
Formula Weight: 166.13
MOL File: 94-53-1.mol

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Piperonylic acid Property

Melting point:: 229-231 °C (lit.)
Boiling point:: 254.32°C (rough estimate)
Density: 1.3579 (rough estimate)
refractive index: 1.5090 (estimate)
storage temp.: Sealed in dry,Room Temperature
solubility: DMSO (Slightly), Methanol (Slightly)
pka: 4.35±0.20(Predicted)
form: Powder
color: Off-white to beige
Water Solubility: slightly soluble
Merck: 14,7477
BRN: 150206
LogP: 0.810 (est)
CAS DataBase Reference: 94-53-1(CAS DataBase Reference)
NIST Chemistry Reference: 1,3-Benzodioxole-5-carboxylic acid(94-53-1)
EPA Substance Registry System: 1,3-Benzodioxole-5-carboxylic acid (94-53-1)

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Safety

Hazard Codes: Xn,Xi
Risk Statements: 22-37/38-41-36/37/38
Safety Statements: 26-36/37/39-37/39
WGK Germany: 3
RTECS: DF4912765
Hazard Note: Irritant
TSCA: Yes
HS Code: 29329970

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H318Causes serious eye damage

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: P49805
Product name: Piperonylic acid
Purity: 99%
Packaging: 5g
Price: $59
Updated: 2024/03/01

Sigma-Aldrich

Product number: P49805
Product name: Piperonylic acid
Purity: 99%
Packaging: 25g
Price: $98
Updated: 2024/03/01

TCI Chemical

Product number: P0459
Product name: Piperonylic Acid
Purity: >98.0%(GC)(T)
Packaging: 25g
Price: $50
Updated: 2024/03/01

Alfa Aesar

Product number: A14105
Product name: Piperonylic acid, 98+%
Packaging: 25g
Price: $59.65
Updated: 2024/03/01

Alfa Aesar

Product number: A14105
Product name: Piperonylic acid, 98+%
Packaging: 100g
Price: $192
Updated: 2024/03/01

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Piperonylic acid Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powde

Uses

Piperonylic Acid is a compound closely mimicking the structure of transcinnamic acid involved in the phenylpropanoid pathway in plant physiology.

Definition

ChEBI: Piperonylic acid is a member of the class of benzodioxoles that is 1,3-benzodioxole substituted by a carboxy group at position 5. It is a natural product isolated from several plant species. It is a selective mechanism-based inactivator of the trans-cinnamate 4-hydroxylase enzyme and exhibits antifungal and skin wound healing properties. It has a role as a plant metabolite, an EC 1.14.14.91 ( trans-cinnamate 4-monooxygenase) inhibitor, a vulnerary and an antifungal agent. It is a member of benzodioxoles, a monocarboxylic acid and an aromatic carboxylic acid. It is a conjugate acid of a piperonylate.

Synthesis Reference(s)

The Journal of Organic Chemistry, 40, p. 3803, 1975 DOI: 10.1021/jo00913a051

Purification Methods

Crystallise the acid from EtOH or water. [Beilstein 19/7 V 300.]

Piperonylic acid Preparation Products And Raw materials

Raw materials

Potassium hydroxide Piperonyl aldehyde Potassium permanganate

Preparation Products

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Piperonylic acid Suppliers

Americas 1 Belgium 2 China 263 Europe 3 France 1 Germany 6 India 8 Italy 2 Japan 4 Slovakia 1 South Korea 1 Switzerland 2 The Netherlands 1 United Kingdom 12 United States 40 Global 347

Aaron Chemistry GmbH

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Email: sales@aaron-chemistry.de
Country: Germany
ProdList: 579
Advantage: 60

Service Chemical Inc.

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Email: sales@chemos-group.com
Country: Germany
ProdList: 6350
Advantage: 71

ABCR GmbH & CO. KG

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Email: info@abcr.de
Country: Germany
ProdList: 6831
Advantage: 75

AKos Consulting & Solutions GmbH

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Email: akos@akosgmbh.de
Country: Germany
ProdList: 6717
Advantage: 72

Rare Chemicals GmbH

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Email: sales@rarechem.de
Country: Germany
ProdList: 6297
Advantage: 38

Merck Schuchardt OHG

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Email: schuchardt-vertrieb@merck.de
Country: Germany
ProdList: 5827
Advantage: 74

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View Lastest Price from Piperonylic acid manufacturers

Jinan Finer Chemical Co., Ltd

Product: Piperonylic acid 94-53-1
Price: US $0.00/Kg/Drum
Min. Order: 1KG
Purity: 99%
Supply Ability: 200mt/year
Release date: 2021-07-12

Hebei Zhuanglai Chemical Trading Co Ltd

Product: Piperonylic acid 94-53-1
Price: US $10.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20 ton
Release date: 2024-11-25

Hebei Weibang Biotechnology Co., Ltd

Product: Piperonylic acid 94-53-1
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100 mt
Release date: 2024-11-06

94-53-1, Piperonylic acidRelated Search:

(Trifluoromethoxy)benzene Citric acid 1,3-Benzodioxole 4-Methoxybenzoic acid Glycine Ethyl 2-(Chlorosulfonyl)acetate Folic acid Anisole Methoxydiethylborane Black Pepper Oil 2-Benzoylbenzoic acid Alginic acid Dextrin 3,4-(METHYLENEDIOXY)PHENYLACETIC ACID Arachidic acid Ascoric Acid Aristolochic acid Piperonylic acid hydrazide

1,3-BENZODIOXOLE-5-CARBOXYLIC ACID

3,4-METHYLENDIOXYBENZOIC ACID

3,4-(METHYLENEDIOXY)BENZOIC ACID

RARECHEM AL BO 0210

3,4-(methylenedioxy)benzoic acid, piperonylic acid

Piperonylic acid, 98+%

PIPEROYLICACID

3,4-Methylendioxybenzoic acid 98%

AKOS 213-90

β(3,4-methylenedioxy-styryl)acrylic acid

5-carboxy-2H-1,3-benzodioxol-5-iuM

1,3-Benzodioxole-5-carboxylic acid 98%

3,4-(Methylendioxy)benzoic acid, Piperonylic acid

1,3-Benzodioxole-5-carboxylic acid, 3,4-(Methylenedioxy)benzoic acid

Piperonylic acid ,99%

3,4-Methylenebisoxybenzoic acid

2-phenyl-2H-1,3-dioxole-4-carboxylic acid

Piperonylic acid,1,3-Benzodioxole-5-carboxylic acid, 3,4-(Methylenedioxy)benzoic acid

Benzo[d][1,3]dioxole-5-carboxylic acid

TIMTEC-BB SBB003897

5-benzodioxolecarboxylicacid

Benzoic acid, 3,4-(methylenedioxy)-

Heliotropic acid

heliotropicacid

Protocatechuic acid methylene ether

3,4-dioxymethylenebenzoicacid

PIPERONYLIC ACID

PROTOCATECHUIC ACID METHYLENETHER

5-Carboxy-1,3-benzodioxole, 3,4-(Methylendioxy)benzoic acid, Piperonylic acid

Piperonylic acid 99%

PiperonylicAcid&gt

Tadalafil Impurity 90

Pepper acid

94-53-1

94-53-11

OCH2OC6H3COOH

CH2O2C6H3COOH

C8H6O4

CH2O2C6H3CHCHCHCHCOOH

Carboxylic Acids

Carbonyl Compounds

C8

Building Blocks

Organic Building Blocks

Building Blocks

C8

Carbonyl Compounds

Chemical Synthesis

Organic Building Blocks

Benzodiozoles, Benzodioxines & Benzodioxepines

Carboxylic Acids

Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts

Benzodiozoles, Benzodioxines & Benzodioxepines

Carboxylic Acids

Quinoxalines ,Quinazolines ,Quinaldines