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Methyl bromoacetate

Product Name
Methyl bromoacetate
CAS No.
96-32-2
Chemical Name
Methyl bromoacetate
Synonyms
METHYL 2-BROMOACETATE;BAM;BROMO METHYLACETATE;BROMOACETIC ACID METHYL ESTER;Methyl bomoacetate;METHYL BROMOACETATE;2-BROMOMETHYL ACETATE;BroMine Methyl acetate;methylmonobromoacetate;Methyl broMoacetate 97%
CBNumber
CB7171783
Molecular Formula
C3H5BrO2
Formula Weight
152.97
MOL File
96-32-2.mol
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Methyl bromoacetate Property

Melting point:
-50°C
Boiling point:
51-52 °C/15 mmHg (lit.)
Density 
1.616 g/mL at 25 °C (lit.)
vapor pressure 
18 hPa (50 °C)
refractive index 
n20/D 1.458(lit.)
Flash point:
145 °F
storage temp. 
Store below +30°C.
form 
Liquid
color 
Clear colorless to slightly yellow
Specific Gravity
1.416
Water Solubility 
Miscible with methanol, ether and acetone. Slightly miscible with water
FreezingPoint 
<-50℃
BRN 
506256
LogP
0.71 at 25℃
CAS DataBase Reference
96-32-2(CAS DataBase Reference)
NIST Chemistry Reference
Acetic acid, bromo-, methyl ester(96-32-2)
EPA Substance Registry System
Acetic acid, bromo-, methyl ester (96-32-2)
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Safety

Hazard Codes 
T,Xi,F
Risk Statements 
25-34-37-23/24/25-40-36/37/38-38
Safety Statements 
26-36/37/39-45-28A-36-16
RIDADR 
UN 2643 6.1/PG 2
WGK Germany 
3
RTECS 
AF6300000
F 
19
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
II
HS Code 
29159080
Hazardous Substances Data
96-32-2(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H301Toxic if swalloed

H314Causes severe skin burns and eye damage

H317May cause an allergic skin reaction

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
157910
Product name
Methyl bromoacetate
Purity
97%
Packaging
25g
Price
$32.3
Updated
2024/03/01
Sigma-Aldrich
Product number
157910
Product name
Methyl bromoacetate
Purity
97%
Packaging
100g
Price
$95.6
Updated
2024/03/01
TCI Chemical
Product number
B0533
Product name
Methyl Bromoacetate
Purity
>98.0%(GC)
Packaging
25g
Price
$28
Updated
2024/03/01
TCI Chemical
Product number
B0533
Product name
Methyl Bromoacetate
Purity
>98.0%(GC)
Packaging
100g
Price
$73
Updated
2024/03/01
Alfa Aesar
Product number
A10605
Product name
Methyl bromoacetate, 98+%
Packaging
50g
Price
$41.65
Updated
2024/03/01
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Methyl bromoacetate Chemical Properties,Usage,Production

Chemical Properties

Colorless liquid

Uses

Methyl bromoacetate was used in the synthesis of novel coumarins. It was also employed in the synthesis of cis-cyclopropanes

Uses

Methyl bromoacetate is used in the synthesis of coumarins and cis-cyclopropanes. It reacts with the conjugate base of (methylmethoxycarbene)pentacarbonylchromium(0) to prepare alkylated carbene complexes. Further, it is used to make vitamins and pharmaceuticals.

Application

Methyl Bromoacetate is an organic building block that has been used as a reactant in the preparation of isoquinolinone indole acetic acid derivatives as antagonists of chemoattractant receptor homologous molecule expressed on Th2 cells (CRTH2) for the treatment of allergic inflammatory diseases.

General Description

A colorless to straw-colored liquid with a sharp penetrating odor. Denser than water and soluble in water. Severly irritates skin and eyes. Toxic by ingestion and inhalation. Used to make vitamins and pharmaceuticals.

Air & Water Reactions

Highly flammable. Soluble in water.

Reactivity Profile

Methyl bromoacetate is a halogenated ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.

Hazard

Vapor is strong irritant to eyes.

Health Hazard

TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Bromoacetates and chloroacetates are extremely irritating/lachrymators. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Fire Hazard

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapors may travel to source of ignition and flash back. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.

Safety Profile

Poison by intravenous route. When heated to decomposition it emits toxic fumes of Br-. See also ESTERS.

Methyl bromoacetate Preparation Products And Raw materials

Raw materials

Carbon tetrachloride Bromoacetic acid

Preparation Products

morpholin-3-one DIMETHYLAMINOACETYL CHLORIDE HYDROCHLORIDE Methyl indole-2-carboxylate METHYL 6-(TRIFLUOROMETHYL)-1H-INDOLE-2-CARBOXYLATE 4-CHLOROPHENOXYACETYL CHLORIDE
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Methyl bromoacetate Suppliers

Americas 1 Belgium 2 Canada 1 China 278 Europe 3 France 3 Germany 9 India 34 Israel 2 Japan 7 Russia 1 Slovakia 1 Switzerland 3 United Kingdom 10 United States 42 Global 397
HBCChem, Inc.
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BromOrganics Corporation
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Lab Express International
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United States Biological
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View Lastest Price from Methyl bromoacetate manufacturers

Hebei Miaoyin Technology Co.,Ltd
Product
Methyl bromoacetate 96-32-2
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10000
Release date
2023-04-18
Hebei Yanxi Chemical Co., Ltd.
Product
Methyl bromoacetate 96-32-2
Price
US $20.00-1.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
10 tons
Release date
2023-10-16
Hebei Chuanghai Biotechnology Co,.LTD
Product
Methyl bromoacetate 96-32-2
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100000kg
Release date
2024-08-20

96-32-2, Methyl bromoacetateRelated Search:

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  • 96-32-2
  • BrCH2CO2CH3
  • CH2BrCOOCH3
  • BrCH2COOCH3
  • ACETATE
  • Organic Building Blocks
  • Esters
  • Carbonyl Compounds
  • C2 to C5
  • Building Blocks
  • Organics
  • C2 to C5
  • Carbonyl Compounds
  • Esters
  • 500 Series Drinking Water Methods
  • BromoEPA
  • Chemical Class
  • Halogenated
  • Method 552
  • Building Blocks
  • C2 to C5
  • Carbonyl Compounds
  • Chemical Synthesis
  • Organic Building Blocks