Trifluoromethyl iodide

Uses Reactions

Product Name: Trifluoromethyl iodide
CAS No.: 2314-97-8
Chemical Name: Trifluoromethyl iodide
Synonyms: CF3I;Trifluoroiodomethane;CIF3;IODOTRIFLUOROMETHANE;R13I1;FIC-1311;FIC-13I1;freon13t1;Freon13I1;uoroiodomethane
CBNumber: CB7356124
Molecular Formula: CF3I
Formula Weight: 195.91
MOL File: 2314-97-8.mol

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Trifluoromethyl iodide Property

Melting point:: <−78 °C(lit.)
Boiling point:: −22.5 °C(lit.)
Density: 2.361
vapor pressure: 540.5kPa at 25℃
refractive index: 1.379
Flash point:: -22.5°C
form: Gas
Water Solubility: Slightly soluble in water.
Sensitive: Light Sensitive
BRN: 1732740
Stability:: Stable. Substances to be avoided include strong oxidizing agents. Avoid direct sunlight. Risk of explosion if heated under confinement. Flammable.
LogP: 2.41 at 22.85℃
CAS DataBase Reference: 2314-97-8(CAS DataBase Reference)
NIST Chemistry Reference: Methane, trifluoroiodo-(2314-97-8)
EPA Substance Registry System: Trifluoroiodomethane (2314-97-8)

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Safety

Hazard Codes: Xn,Xi
Risk Statements: 68
Safety Statements: 36/37
RIDADR: UN 1956 2.2
WGK Germany: 1
RTECS: PB6975000
F: 27
Hazard Note: Irritant
TSCA: T
HazardClass: 2.2
HS Code: 2903780020

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H280Contains gas under pressure; may explode if heated

H341Suspected of causing genetic defects

H420Harms public health and the environment by destroying ozone in the upper atmosphere

Precautionary statements

P201Obtain special instructions before use.

P202Do not handle until all safety precautions have been read and understood.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P308+P313IF exposed or concerned: Get medical advice/attention.

P410+P403Protect from sunlight. Store in a well-ventilated place.

P502Refer to manufacturer/supplier for information on recovery/recycling

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 171441
Product name: Trifluoroiodomethane
Purity: 99%
Packaging: 25g
Price: $264
Updated: 2024/03/01

Sigma-Aldrich

Product number: 171441
Product name: Trifluoroiodomethane
Purity: 99%
Packaging: 100g
Price: $455
Updated: 2024/03/01

Alfa Aesar

Product number: 041479
Product name: Trifluoroiodomethane
Purity: 97+%
Packaging: 25g
Price: $369
Updated: 2023/06/20

Alfa Aesar

Product number: 041479
Product name: Trifluoroiodomethane
Purity: 97+%
Packaging: 100g
Price: $651
Updated: 2023/06/20

Strem Chemicals

Product number: 09-7680
Product name: Trifluoromethyliodide, min. 97%
Packaging: 100g
Price: $654
Updated: 2024/03/01

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Trifluoromethyl iodide Chemical Properties,Usage,Production

Uses

Trifluoroiodomethane is used as a gaseous fire suppression flooding agent for in-flight aircraft and electronic equipment fires. It is also an important raw material and intermediate used in organic synthesis, pharmaceuticals and agrochemicals. It is involved in the rhodium-catalyzed alfa-trifluoromethylation of alfa,beta-unsaturatedketones. It plays an important role as catalyst in the enantioselective alfa -trifluoromethylation of aldehydes through photoredox organocatalysis using a readily available iridium photocatalyst.

Reactions

Trifluoromethyl iodide reacts with [AuMeL] to give [AuMe2(CF3)L] and [AuIL](L = PMe3 or PMe2Ph), or [Au(CF3)L] and Mel (L = PPh3), or a mixture of these products (L = PMePh2). In some cases reaction of [AuMe(PMe3)] with CF3I gives [AuMe(CF3)I(PMe3)]. Evidence is presented that the reactions proceed, at least in part, by a free-radical chain mechanism.

Chemical Properties

Trifluoromethyl iodide is a colourless gas, it is stable under normal temperatures and pressure. However, upon decomposition, it may form acid halides such as hydrogen fluoride (HF) and hydrogen iodide. It is incompatible with oxidizing materials.

Preparation

Trifluoromethyl iodide's synthesis method:A glass flask provided with a gas outlet is filled with 80 g. (0.153 mole) of CI4 and 30 g. (0.135 mole) of IF5. The gas outlet is connected via short rubber tubes to several gas traps cooled with liquid nitrogen. Agitation of the vessel produces vigorous evolution of gas. When the reaction subsides, the system is heated for 30 min at 90-100°C. The condensate in the gas traps is then washed with 5% NaOH and fractionated. The yield is 90%.

Synthesis Reference(s)

Journal of the American Chemical Society, 107, p. 5014, 1985 DOI: 10.1021/ja00303a042

Flammability and Explosibility

Not classified

Trifluoromethyl iodide Preparation Products And Raw materials

Raw materials

Preparation Products

2-(Trifluoromethyl)nicotinic acid

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Trifluoromethyl iodide Suppliers

China 148 Europe 2 France 3 Germany 5 India 3 Japan 2 Russia 1 Slovakia 1 Switzerland 1 United Kingdom 6 United States 19 Global 191

Yangzhou modier Electronic Materials Co., Ltd

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J & K SCIENTIFIC LTD.

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Alfa Aesar

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ShangHai DEMO Chemical Co.,Ltd

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Beijing Ouhe Technology Co., Ltd

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Shanghai Sinch Parmaceuticals Tech. Co. Ltd.

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Jia Xing Isenchem Co.,Ltd

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View Lastest Price from Trifluoromethyl iodide manufacturers

Henan Aochuang Chemical Co.,Ltd.

Product: Trifluoromethyl iodide 2314-97-8
Price: US $0.00/kg
Min. Order: 25kg
Purity: 99%
Supply Ability: 1ton
Release date: 2024-12-11

Baoji Guokang Bio-Technology Co., Ltd.

Product: Trifluoromethyl iodide 2314-97-8
Price: US $1310.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1-10mt
Release date: 2021-06-22

Henan Fengda Chemical Co., Ltd

Product: Trifluoromethyl iodide 2314-97-8
Price: US $8.00-1.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2024-04-03

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PERFLUOROMETHYL IODIDE

CF3I

CIF3

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Freon13I1

freon13t1

iodotrifluoromethane(trifluoromethyliodide)

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monoiodotrifluoromethane

Trifluoromethyl iodide 99%

R13I1

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Trifluoriodomethane

trifluoroiodo-methan

TRIFLUOROMETHYL IODIDE

TRIFLUOROMETHYL IODIDE CYLINDER WITH

Trifluoromethyliodide,min.97%

Iodotrifluoromethane 99%

Iodotrifluoromethane99%

Trifluoroiodomethane,Iodotrifluoromethane, Perfluoromethyl iodide, Trifluoromethyl iodide

Trifluoromethyliodide, min. 97% (Material sold in non-returnable cylinder)

FIC-13I1

Trifluoroiodomethane, 99.9%

Trifluoroiodomethane, 97+%

trifluoroiodomethane trifluoromethyl iodide

Iodotrifluoromethane, Perfluoromethyl iodide, Trifluoromethyl iodide

Trifluoromethyliodide, min. 97%

IODOTRIFLUOROMETHANE

Trifluoroiodomethane

7-Trifluoromethyl-1H-indole-2-carboxylicacidethylester

Trifluoromethyl iodide 85% 99.5%

uoroiodomethane

Trifluoromethane iodide

Trifluoroiodomethane CF3I

Trifluorolodmethane

2314-97-8

Synthetic Reagents

Compressed and Liquefied Gases

organofluorine compounds