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Triphenylbismuth

Product Name
Triphenylbismuth
CAS No.
603-33-8
Chemical Name
Triphenylbismuth
Synonyms
TPB;Aerotex;(C6H5)3Bi;Trifenylbismutin;TRIPHENYLBISMUTH;BISMUTH TRIPHENYL;triphenyl-bismuthin;TRIPHENYLBISMUTHINE;Triphenylbismuth,99%;Triphenylbismuth,98%
CBNumber
CB7478628
Molecular Formula
C18H15Bi
Formula Weight
440.29
MOL File
603-33-8.mol
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Triphenylbismuth Property

Melting point:
78-80 °C
Boiling point:
310°C
Density 
1,585 g/cm3
refractive index 
1.7040
Flash point:
242°C/14mm
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)
form 
crystal
color 
white
Specific Gravity
1.585
Water Solubility 
insoluble
Sensitive 
Moisture Sensitive
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
CAS DataBase Reference
603-33-8(CAS DataBase Reference)
NIST Chemistry Reference
Bismuthine, triphenyl-(603-33-8)
EPA Substance Registry System
Triphenylbismuth (603-33-8)
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Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22
Safety Statements 
24/25-36/37
WGK Germany 
3
RTECS 
EB2980000
TSCA 
Yes
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P330Rinse mouth.

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N-Bromosuccinimide Price

Alfa Aesar
Product number
012545
Product name
Triphenylbismuth
Purity
99+%
Packaging
5g
Price
$36.8
Updated
2023/06/20
Alfa Aesar
Product number
012545
Product name
Triphenylbismuth
Purity
99+%
Packaging
25g
Price
$129
Updated
2023/06/20
Strem Chemicals
Product number
93-8350
Product name
Triphenylbismuth, 99%
Packaging
10g
Price
$96
Updated
2024/03/01
Strem Chemicals
Product number
93-8350
Product name
Triphenylbismuth, 99%
Packaging
50g
Price
$432
Updated
2024/03/01
Alfa Aesar
Product number
012545
Product name
Triphenylbismuth
Purity
99+%
Packaging
100g
Price
$389
Updated
2023/06/20
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Triphenylbismuth Chemical Properties,Usage,Production

Chemical Properties

white to off-white crystalline powder

Uses

Triphenylbismuth, as an volatile organometallic used in the preparation of thin films of superconducting oxides by CVD. It is also added to the fuel of rocket as cruing agent. It acts as a solidifying catalyst for butyl hydroxyl propellants.

Preparation

Triphenylbismuth is conveniently prepared by reaction of Phenylmagnesium Bromide with BiCl3 in ether.

storage

It ?must be stored in dark bottles in the absence of moisture or acidic vapors. Use in a fume hood.

Purification Methods

Dissolve it in EtOH, precipitate it with H2O, extract with Et2O, dry and evaporate till the residue crystallises. It has been recrystallised from EtOH and Et2O/EtOH and is a stable compound. [Forward et al. J Chem Soc suppl p121 1949, Pfeiffer et al. Chem Ber 37 4620 1904, Gilman & Yablunky J Am Chem Soc 62 665 1940, UV: Jaffé J Chem Phys 22 1430 1954, Beilstein 4 III 1841.]

Triphenylbismuth Preparation Products And Raw materials

Raw materials

Preparation Products

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Triphenylbismuth Suppliers

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View Lastest Price from Triphenylbismuth manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
Triphenylbismuth 603-33-8
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-02-08
Hebei Yanxi Chemical Co., Ltd.
Product
Triphenylbismuth 603-33-8
Price
US $0.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
20tons
Release date
2023-10-09
Hebei Chuanghai Biotechnology Co,.LTD
Product
Triphenyl Bismuth 603-33-8
Price
US $5.00-2.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000kg
Release date
2024-08-21

603-33-8, TriphenylbismuthRelated Search:

Triphenylphosphine (FORMYLMETHYLENE)TRIPHENYLPHOSPHORANE Triphenyltin acetate Lactulose Triphenylmethyl Chloride Triphenylantimony 2,3,5-Triphenyltetrazolium chloride TRIPHENYLBORANE Trityl olmesartan DICHLORO(TRI-O-TOLYL)BISMUTH TRI-P-TOLYLBISMUTHINE BIS(ACETATO-O)TRIPHENYLBISMUTH Tetrachloro-o-benzoquinone TRIPHENYLBISMUTH(V) DICHLORIDE,TRIPHENYLBISMUTH DICHLORIDE Bismuth Triphenylbismuth TRIS(4-ETHOXYPHENYL)BISMUTH TRIS(2-METHOXYPHENYL)BISMUTHINE

  • BISMUTH TRIPHENYL
  • Triphenylbismuth,99%
  • Bismuthine, triphenyl-
  • TRIPHENYLBISMUTH
  • TRIPHENYLBISMUTHINE
  • TPB
  • (C6H5)3Bi
  • Aerotex
  • Trifenylbismutin
  • triphenyl-bismuthin
  • TRIPHENYLBISMUTH(III) 99%
  • TRIPHENYL BISMUTH ANHYDROUS
  • Tri(phenyl)bismuthane
  • Triphenylbismuth,98%
  • Triphenylbismuthine &gt
  • Triphenylbismuth ISO 9001：2015 REACH
  • 1,1',1''-Methanetriyltris(1H-benzotriazole)
  • 603-33-8
  • BiC6H53
  • C18H15Bi
  • Furans
  • Organometallics
  • organobismuth compound
  • blocks
  • BuildingBlocks