Chemical Properties Uses
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1,5-Cyclooctadiene

Chemical Properties Uses
Product Name
1,5-Cyclooctadiene
CAS No.
111-78-4
Chemical Name
1,5-Cyclooctadiene
Synonyms
COD;Cycloocta-1,5-diene;1,5-COD;CIS,CIS-1,5-CYCLOOCTADIENE;1,5-CycL;ooctadiene;1,5-CYCLOOCTADIENE;1.5-cyclooctandiene;1,5-Cyclooctanediene;Cyclooctadiene, 1,5-
CBNumber
CB7852853
Molecular Formula
C8H12
Formula Weight
108.18
MOL File
111-78-4.mol
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1,5-Cyclooctadiene Property

Melting point:
-69 °C (lit.)
Boiling point:
149-150 °C (lit.)
Density 
0.882 g/mL at 25 °C (lit.)
vapor pressure 
25.8 mm Hg ( 37.7 °C)
refractive index 
n20/D 1.493
Flash point:
89 °F
storage temp. 
2-8°C
solubility 
soluble in Chloroform
form 
Liquid
color 
Clear colorless
Odor Threshold
0.00084ppm
Water Solubility 
780 mg/L (20 ºC)
BRN 
2036542
Stability:
Stable. Flammable.
LogP
3.16 at 20℃
CAS DataBase Reference
111-78-4(CAS DataBase Reference)
NIST Chemistry Reference
1,5-Cyclooctadiene(111-78-4)
EPA Substance Registry System
1,5-Cyclooctadiene (111-78-4)
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Safety

Hazard Codes 
Xn,N,Xi
Risk Statements 
10-36/38-42/43-65-50/53-22-43-19-20/22-52/53-36/37/38
Safety Statements 
26-36-61-60-16-37/39
RIDADR 
UN 2520 3/PG 3
WGK Germany 
3
RTECS 
GX9620000
F 
10-23
Autoignition Temperature
431 °F
HazardClass 
3.2
PackingGroup 
III
HS Code 
29021990
Hazardous Substances Data
111-78-4(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H226Flammable liquid and vapour

H304May be fatal if swallowed and enters airways

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P273Avoid release to the environment.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P331Do NOT induce vomiting.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
246050
Product name
1,5-Cyclooctadiene
Purity
purified by redistillation, ≥99%
Packaging
100ml
Price
$62
Updated
2024/03/01
Sigma-Aldrich
Product number
246050
Product name
1,5-Cyclooctadiene
Purity
purified by redistillation, ≥99%
Packaging
800ml
Price
$335
Updated
2024/03/01
TCI Chemical
Product number
C0503
Product name
1,5-Cyclooctadiene [stabilized with Octadecyl 3-(3',5'-Di-tert-butyl-4'-hydroxyphenyl)propionate]
Purity
>98.0%(GC)
Packaging
25mL
Price
$23
Updated
2024/03/01
TCI Chemical
Product number
C0503
Product name
1,5-Cyclooctadiene [stabilized with Octadecyl 3-(3',5'-Di-tert-butyl-4'-hydroxyphenyl)propionate]
Purity
>98.0%(GC)
Packaging
100mL
Price
$35
Updated
2024/03/01
Alfa Aesar
Product number
B21196
Product name
cis,cis-1,5-Cyclooctadiene, 99%
Purity
stab. with 50-200ppm Irganox 1076
Packaging
250ml
Price
$32
Updated
2023/06/20
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1,5-Cyclooctadiene Chemical Properties,Usage,Production

Chemical Properties

1,5-Cyclooctadiene is the organic compound with the chemical formula C8H12.It is a colorless liquid with a strong odor. COD has a boiling point of 151°C and a vapor pressure of 6.8mm at 25°C.

Uses

1,5-Cyclooctadiene is generally abbreviated COD, this diene is a useful precursor to other organic compounds and serves as a ligand in organometallic chemistry. 1,5-Cyclooctadiene can be prepared by dimerization of butadiene in the presence of a nickel catalyst, a coproduct being vinylcyclohexene. It is also a chemical intermediate in the production of Nylon.

Chemical Properties

colourless liquid

Uses

Cycloocta-1,5-diene is produced from petroleum distillation fractions and is used as an intermediate in the plastics industry, as a synthetic lubricant, and in numerous other applications.

Synthesis Reference(s)

Tetrahedron Letters, 24, p. 3913, 1983 DOI: 10.1016/S0040-4039(00)94312-0

Carcinogenicity

None of the components present in this material at concentrations of 0.1% are listed by IARC, NTP, or OSHA as a carcinogen.

Purification Methods

Purify it by GLC. It has been purified via the AgNO3 salt. This is prepared by shaking with a solution of 50% aqueous AgNO3 w/w several times (e.g. 3 x 50mLand4x50mL) at 70ofor ca 20minutes to get a good separation of layers. The upper layers are combined and further extracted with AgNO3 at 40o (2 x 20 mL). The upper layer (19 mL) of original hydrocarbon mixture gives colourless needles of the AgNO3 complex on cooling. The adduct is recrystallised from MeOH (and cooling to 0o). The hydrocarbon is recovered by steam distilling the salt. The distillate is extracted with Et2O, dried (MgSO4), filtered, evaporated and distilled. [Jones J Chem Soc 312 1954,[Beilstein 5 H 116, 5 IV 403.]

1,5-Cyclooctadiene Preparation Products And Raw materials

Raw materials

Preparation Products

(3S,4R)-4-Acetoxy-3-[(R)-1-(tert-butyldimethylsilyloxy)ethyl]azetidin-2-one Chloro(1,5-cyclooctadiene)iridium(I) dimer Dichloro(cycloocta-1,5-diene)ruthenium(II) Dichloro(1,5-cyclooctadiene)palladium(II) Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Dichloro(1,5-cyclooctadiene)platinum(II) Chloro(1,5-cyclooctadiene)rhodium(I) dimer
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1,5-Cyclooctadiene Suppliers

Americas 1 Belgium 3 Canada 1 China 108 Czech 1 Europe 2 France 1 Germany 3 India 5 Japan 9 Russia 1 South Korea 1 Spain 1 Switzerland 2 Ukraine 1 United Kingdom 6 United States 36 Global 182
Matrix Fine Chemicals GmbH
Tel
--
Fax
--
Email
nfo@matrix-fine-chemicals.com
Country
Switzerland
ProdList
6968
Advantage
58
SIGMA-RBI
Tel
--
Fax
--
Country
Switzerland
ProdList
6896
Advantage
91
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View Lastest Price from 1,5-Cyclooctadiene manufacturers

Hebei Yanxi Chemical Co., Ltd.
Product
1,5-Cyclooctadiene 111-78-4
Price
US $100.00/kgkg
Min. Order
1kgkg
Purity
0.99
Supply Ability
1000
Release date
2023-09-28
Wuhan Boyuan Import & Export Co., LTD
Product
COD
Price
US $6.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000ton
Release date
2023-08-14
Henan Fengda Chemical Co., Ltd
Product
1,5-Cyclooctadiene 111-78-4
Price
US $100.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-26

111-78-4, 1,5-CyclooctadieneRelated Search:

1,7-Octadiene Dichloro(cycloocta-1,5-diene)ruthenium(II) dichloro[(1,2,5,6-eta)-1,5-cyclooctadiene]-palladi ((1,2,5,6-eta)-1,5-cyclooctadiene)(2,4-pentanedionato-o,o’)-rhodi dichloro[(1,2,5,6-eta)-1,5-cyclooctadiene]-platin (1,5-CYCLOOCTADIENE)DIMETHYLPLATINUM(II) 1,3-CYCLOOCTADIENE Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate chloro(1,5-cyclooctadiene)iridium(i bis(1,5-cyclooctadiene)-nick Dichloro-bis-1,5-cyclooctadiene dirhodium,Di-mu-chlorobis(1,5-cyclooctadiene)dirhodium,di-mu-chlorobis[(1,2,5,6-eta)-1,5-cyclooctadiene]di-rhodi RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE) COPPER(I) HEXAFLUORO-2,4-PENTANEDIONATE-CYCLOOCTADIENE COMPLEX (R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DIPHENYLPHOSPHINO)-3,3'-BIPYRIDINE(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE 1,3-CYCLOOCTADIENE (+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM (I) TRIFLUOROMETHANESULFONATE (1Z,5Z)-1,5-cyclooctadien Antioxidant 1076

  • Cycloocta-1,5-diene
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  • 1,5-CYCLOOCTADIENE, REDISTILLED, 99+%
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  • 1,5-COD
  • CIS,CIS-1,5-CYCLOOCTADIENE , STABILIZED WITH 50-200PPM IRGANOX 1076
  • 1,5-Cyclooctadiene [stabilized with Octadecyl 3-(3',5'-Di-tert-butyl-4'-hydroxyphenyl)propionate]
  • Cyclooctadiene, 1,5-
  • 1,5-Cyclooctanediene
  • cis,cis-1,5-Cyclooctadiene: 99%, stabilized with 50-200ppm Irganox 1076
  • 1,5-Cyclooctadiene,99%,stabilized
  • 1,5-Cyclooctadiene ,98.5% [stabilized]
  • [stabilized with Octadecyl 3-(3 ,5 -Di-tert-butyl-4 -hydroxyphenyl)propionate]
  • 1,5-Cyclooctadiene&nbsp
  • 1,5-Cyclooctadiene, 99+%, stabilized, purified by redistillation, AcroSeal
  • 1,5-Cyclooctadiene contains 50-150 ppM 4-tert-Butylcatechol, 99%
  • 1,5-Cyclooctadiene purified by redistillation, >=99%
  • 1,5-Cyclooctadiene(COD)
  • 1,5-CYCLOOCTADIENE, 98+%1,5-CYCLOOCTADIENE, 98+%1,5-CYCLOOCTADIENE, 98+%1,5-CYCLOOCTADIENE, 98+%
  • 1,5-Cyclooctadiene[stabilizedwithOctadecyl3-(3',5'-Di-tert-butyl-4'-hydroxyphenyl)propionate]&gt
  • 1,5-CycL
  • ooctadiene
  • 1,5-Cyclooctadiene ISO 9001：2015 REACH
  • (5Z)-cycloocta-1,5-diene
  • 1.5-cyclooctandiene
  • 1,5-Cyclooctadiene, stabilized with Octadecyl 3-(3',5'-Di-tert-butyl-4'-hydroxyphenyl)propionate，≥ 98.0%
  • 111-78-4
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