tert-Butyl bromoacetate

Product Name: tert-Butyl bromoacetate
CAS No.: 5292-43-3
Chemical Name: tert-Butyl bromoacetate
Synonyms: TERT-BUTYL 2-BROMOACETATE;T-BUTYL BROMOACETATE;1-Butylbromoacetate;BROMOACETIC ACID TERT-BUTYL ESTER;tert-Butyl Bromoacet;T-BUTYL 2-BROMOACETATE;2-Methyl-2-propanyl bromoacetate;BrCH2C(O)OC(CH3)3;BUTYLBROMOACETATE-TERT;ert-Butyl bromoacetate
CBNumber: CB7853739
Molecular Formula: C6H11BrO2
Formula Weight: 195.05
MOL File: 5292-43-3.mol

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tert-Butyl bromoacetate Property

Melting point:: 44-47 °C
Boiling point:: 50 °C10 mm Hg(lit.)
Density: 1.338
vapor pressure: 1.62hPa at 25℃
refractive index: n20/D 1.445(lit.)
Flash point:: 121 °F
storage temp.: 0-6°C
solubility: Chloroform, Ethyl Acetate (Slightly)
form: Liquid
Specific Gravity: 1.333 (20/4℃)
color: Clear colorless to yellow
Water Solubility: Miscible with ethanol, chloroform and ethyl acetate. Immiscible with water.
Sensitive: Lachrymatory
BRN: 1753010
InChIKey: BNWCETAHAJSBFG-UHFFFAOYSA-N
CAS DataBase Reference: 5292-43-3(CAS DataBase Reference)
NIST Chemistry Reference: Acetic acid, bromo-, 1,1-dimethylethyl ester(5292-43-3)
EPA Substance Registry System: Acetic acid, bromo-, 1,1-dimethylethyl ester (5292-43-3)

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Safety

Hazard Codes: Xi,F
Risk Statements: 10-36/37/38
Safety Statements: 26-24/25-16
RIDADR: UN 1993 3/PG 3
WGK Germany: 3
F: 19
Hazard Note: Irritant/Flammable/Lachrymatory
TSCA: T
HazardClass: 3
PackingGroup: III
HS Code: 29159080

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H226Flammable liquid and vapour

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 124230
Product name: tert-Butyl bromoacetate
Purity: 98%
Packaging: 10g
Price: $32.7
Updated: 2024/03/01

Sigma-Aldrich

Product number: 124230
Product name: tert-Butyl bromoacetate
Purity: 98%
Packaging: 50g
Price: $131
Updated: 2024/03/01

TCI Chemical

Product number: B1473
Product name: tert-Butyl Bromoacetate
Purity: >98.0%(GC)
Packaging: 25g
Price: $62
Updated: 2024/03/01

TCI Chemical

Product number: B1473
Product name: tert-Butyl Bromoacetate
Purity: >98.0%(GC)
Packaging: 250g
Price: $323
Updated: 2024/03/01

Alfa Aesar

Product number: A14917
Product name: tert-Butyl bromoacetate, 98%
Packaging: 10g
Price: $33.2
Updated: 2024/03/01

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tert-Butyl bromoacetate Chemical Properties,Usage,Production

Chemical Properties

clear colorless to yellow liquid

Uses

tert-Butyl Bromoacetate is a halogenated t-butyl acetate commonly used as an alkylating agent. tert-Butyl Bromoacetate is used in the synthesis of collagenase inhibitors.

Uses

tert-Butyl bromoacetate is used as an intermediate in the production of dyes, pharmaceuticals, agrochemicals and in organic compounds. It finds application as an alkylating agent. It plays an important role to prepare (2-oxo-4-vinyl-azetidin-1-yl)-acetic acid tert-butyl ester and in collagenase inhibitors synthesis.

Application

tert-Butyl bromoacetate has been used in the synthesis of:
nitrilotriacetic acid end-functionalized polystyrene by atom transfer radical polymerization
building block for substituted t-butyl acetates
dihydropyranyl prelinker which is useful in polymer-assisted deprotection of oligosacchararides
collagenase inhibitor (S,S,R)-(-)-actinonin It is the starting reagent for the synthesis of N-Oxalylglycine derivatives.

Preparation

Tert-butyl bromoacetate ester was synthesized using bromoacetic acid and isobutylene as raw materials,Amberlyst 15,a strong acidic cation exchange resin,as catalyst,and tert-butanol as modifier.

General Description

tert-Butyl bromoacetate serves as building blocks during the synthesis of model N-substituted oligoglycines (peptoids) containing an N-linked lactoside side-chain.

Flammability and Explosibility

Flammable

Safety

Tert-Butyl bromoacetate is a lachrymator. The reagent, reaction and its work-up should be handled in an adequately ventilated fume hood while wearing gloves, safety glasses and laboratory coat.

Purification Methods

Dissolve the ester in Et2O, wash it well with ice cold 10% aqueous K2CO3, dry it over CaCl2, filter and evaporate the Et2O, then fractionate it through a Vigreux column (p 11) in a vacuum. LACHRYMATORY. [Abramovitch et al. J Am Chem Soc 64 2274 1942, Abramovitch & Hauser J Am Chem Soc 65 986 1943, Beilstein 2 III 482.]

tert-Butyl bromoacetate Preparation Products And Raw materials

Raw materials

Preparation Products

DIETHYLAMINO-ACETIC ACID (4-ACETYL-PIPERAZIN-1-YL)-ACETIC ACID MORPHOLIN-4-YL-ACETIC ACID TRI-TERT-BUTYL 1 4 7 10-TETRAAZACYCLODOD trans-3,4-Difluorocinnamic acid TERT-BUTYL 2-(N-(3-AMINOBENZYL)-N-METHYLAMINO)ACETATE (S)-4-BOC-MORPHOLINE-3-CARBOXYLIC ACID

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tert-Butyl bromoacetate Suppliers

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View Lastest Price from tert-Butyl bromoacetate manufacturers

Jinan Finer Chemical Co., Ltd

Product: tert-Butyl bromoacetate 5292-43-3
Price: US $5.00/KG
Min. Order: 1KG
Purity: ≥99%
Supply Ability: 500mt/year
Release date: 2023-09-15

Hebei Miaoyin Technology Co.,Ltd

Product: tert-Butyl bromoacetate 5292-43-3
Price: US $10.00/kg
Min. Order: 1kg
Purity: 99.9%
Supply Ability: 10000
Release date: 2023-04-18

Hebei Weibang Biotechnology Co., Ltd

Product: tert-Butyl bromoacetate 5292-43-3
Price: US $9.90/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 5tons
Release date: 2024-10-30

5292-43-3, tert-Butyl bromoacetateRelated Search:

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T-BUTYL BROMOACETATE

1,1-Dimethylethyl 2-bromoacetate

1,1-Dimethylethyl bromoacetate

bromoacetic acid T-butyl ester

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<i>tert</i>-Butyl bromoacetate

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BroMine tertiary butyl acetate

2-Methyl-2-propanyl bromoacetate

1-Butylbromoacetate

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aceticacid,bromo-,1,1-dimethylethylester

BrCH2C(O)OC(CH3)3

2-BROMOACETIC ACID-TERT-BUTYL ESTER

BROMOACETIC ACID TERT-BUTYL ESTER

BUTYLBROMOACETATE-TERT

TERT-BUTYL 2-BROMOACETATE

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T-BUTYL 2-BROMOACETATE

tert-Butyl Bromoacetate &gt

High Purity 99% 2-Methyl-2-Propanyl Bromoacetate

T-BUTYL BROMOACETATE,CAS:5292-43-3

ert-Butyl bromoacetate

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tert-Butyl Bromoacetate, ≥ 98.0%

Flufenamic Acid Impurity 12

TERT-BUTYL BROMOACETATE 99% MIN

5292-43-3

BrCH2CO2CCH33

Esters

Organic Building Blocks

Building Blocks

Carbonyl Compounds

C6 to C7

Pharmaceutical intermediates

organic chemical

Building Blocks

C6 to C7

Carbonyl Compounds

Chemical Synthesis

Organic Building Blocks

ACID BASED BROMO COMPOUNDS

C6 to C7

Carbonyl Compounds

Esters

K00001