2,2-Bis(3-amino-4-hydroxyphenyl)propane
Uses- Product Name
- 2,2-Bis(3-amino-4-hydroxyphenyl)propane
- CAS No.
- 1220-78-6
- Chemical Name
- 2,2-Bis(3-amino-4-hydroxyphenyl)propane
- Synonyms
- BHAPP;Oxyindene;4,4''-(Propane;4,4'-Isopropylidenebis(2-aminophenol);2-Bis(3-amino-4-hydroxyphenyl)propane;2,2-Bis(3-amino-4-hydroxyphenyl)propan;2,2-BIS-(3-AMINO-4-HYDROXYPHENYL)PROPANE;2,2-Bis(3-amino-4-hydroxylphenyl)propane;4,4'-(Propane-2,2-diyl)bis(2-aMinophenol);4,4'-(Propane-2,2-diyl)bis(2-aminophenol)
- CBNumber
- CB81090679
- Molecular Formula
- C15H18N2O2
- Formula Weight
- 258.32
- MOL File
- 1220-78-6.mol
2,2-Bis(3-amino-4-hydroxyphenyl)propane Property
- Melting point:
- 248-250 °C
- Boiling point:
- 471.1±45.0 °C(Predicted)
- Density
- 1.265±0.06 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- solubility
- soluble in Dimethylformamide
- form
- powder to crystal
- pka
- 10.62±0.10(Predicted)
- color
- White to Yellow to Orange
- CAS DataBase Reference
- 1220-78-6(CAS DataBase Reference)
Safety
- HS Code
- 29222990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
N-Bromosuccinimide Price
- Product number
- B4429
- Product name
- 2,2-Bis(3-amino-4-hydroxylphenyl)propane
- Purity
- >97.0%(HPLC)(T)
- Packaging
- 5g
- Price
- $77
- Updated
- 2024/03/01
- Product number
- B4429
- Product name
- 2,2-Bis(3-amino-4-hydroxylphenyl)propane
- Purity
- >97.0%(HPLC)(T)
- Packaging
- 25g
- Price
- $245
- Updated
- 2024/03/01
- Product number
- P835308
- Product name
- 4,4''-(Propane-2,2-diyl)bis(2-aminophenol)
- Packaging
- 1g
- Price
- $75
- Updated
- 2021/12/16
- Product number
- Z5449
- Product name
- 2,2-Bis(3-amino-4-hydroxyphenyl)propane
- Packaging
- 5g
- Price
- $37
- Updated
- 2021/12/16
- Product number
- J93774
- Product name
- 2,2-Bis(3-amino-4-hydroxyphenyl)propane
- Packaging
- 10g
- Price
- $41
- Updated
- 2021/12/16
2,2-Bis(3-amino-4-hydroxyphenyl)propane Chemical Properties,Usage,Production
Uses
4,4'-(Propane-2,2-diyl)bis(2-aminophenol) is a useful research chemical.
Description
2,2-Bis(3-amino-4-hydroxyphenyl)propane (BAP) is a diamine organic compound that is used in the synthesis of polyimides.
Uses
2,2-bis(4-hydroxy-3-aminophenyl)propane is used as a polyimide intermediate and functional monomer.
Synthesis
Thedinitro compound (2) (10,000 g, 0.0314 mol) was heated to reflux inabsolute ethanol (100 mL) in the presence of wet 10% Pd/C catalyst(0.650 g). Hydrazine monohydrate (20 mL) was then added dropwiseover a period of 30 min, and the reaction was maintained at reflux for24 h. The hot solution was filtered through Celite to eliminate thecatalyst and partially concentrated under reduced pressure. Afterwards,the concentrate was poured into cold distilled water. The crude productwas filtered, washed with water, dried under vacuum and recrystallizedtwice from methanol to give (3). The diamino compound was obtainedas a white powder: yield: 88%; mp. 263 ??C (DSC); Analysis: Calculatedfor C15H18N2O2: C, 69.74%; H, 7.02%; N, 10.84%. Found: C, 69.35%;H, 7.15%; N, 11.02%. 1H NMR (400 MHz, DMSO-d6): |? (ppm); 8.57 (s,1H, OH), 6.43 (d, J=8.1 Hz, 1H, Har), 6.34 (d, J=1.8 Hz, 1H, Har),6.21 (dd, J=8.1 Hz, 1.8 Hz, 1H, Har), 4.23 (s, 2H, NH) 1.37 (s, 3H, CH3f). 13C NMR (100 MHz, DMSO-d6): |? (ppm) 142.4, 141.4, 135.4, 114.4,113.5, 113.4, 40.8, 30.9.
2,2-Bis(3-amino-4-hydroxyphenyl)propane Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2,2-Bis(3-amino-4-hydroxyphenyl)propane manufacturers
- Product
- 2,2-Bis(3-amino-4-hydroxyphenyl)propane 1220-78-6
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20 tons
- Release date
- 2023-03-09
- Product
- 2,2-Bis(3-amino-4-hydroxylphenyl)propane (BAP) 1220-78-6
- Price
- US $1.00/Kg/Drum
- Min. Order
- 1KG
- Purity
- ≥99%
- Supply Ability
- 10TM
- Release date
- 2021-11-19
- Product
- 2,2-Bis(3-amino-4-hydroxylphenyl) propane
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99% min
- Supply Ability
- 50MT
- Release date
- 2021-12-15