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ChemicalBook > CAS DataBase List > Tris(2-phenylpyridine)iridium (Ir(ppy)3)

Tris(2-phenylpyridine)iridium (Ir(ppy)3)

Applications Reactions
Product Name
Tris(2-phenylpyridine)iridium (Ir(ppy)3)
CAS No.
94928-86-6
Chemical Name
Tris(2-phenylpyridine)iridium (Ir(ppy)3)
Synonyms
Ir(ppy)3;TRIS(2-PHENYLPYRIDINE)IRIDIUM;fac-Tris(2-phenylpyridine)iridium;sublimed grade;tris[2-(2-pyridyl)phenyl]iridium;TRIS(2-PHENYLPYRIDINE)IRIDIUM (III);Tris[2-phenylpyridinato-C2,N]iridium(III);(ppy)3Ir;Tris(2-phenyL;pyridine)iridium
CBNumber
CB8112370
Molecular Formula
C33H24IrN3
Formula Weight
654.79
MOL File
94928-86-6.mol
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Tris(2-phenylpyridine)iridium (Ir(ppy)3) Property

Melting point:
328°C
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
form 
Powder
color 
yellow
Sensitive 
air sensitive
CAS DataBase Reference
94928-86-6(CAS DataBase Reference)
Absorption
λmax?282, 377 nm?in THF
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3
TSCA 
No
HS Code 
28439000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
694924
Product name
Tris[2-phenylpyridinato-C2,N]iridium(III)
Purity
sublimed grade
Packaging
250mg
Price
$715
Updated
2024/03/01
Sigma-Aldrich
Product number
688096
Product name
Tris[2-phenylpyridinato-C2,N]iridium(III)
Purity
99%
Packaging
250mg
Price
$402
Updated
2024/03/01
TCI Chemical
Product number
T3716
Product name
Tris(2-phenylpyridinato)iridium(III)
Purity
>98.0%(HPLC)
Packaging
200mg
Price
$250
Updated
2024/03/01
TCI Chemical
Product number
T1946
Product name
Tris(2-phenylpyridinato)iridium(III) (purified by sublimation)
Purity
>95.0%(HPLC)
Packaging
200mg
Price
$533
Updated
2024/03/01
Strem Chemicals
Product number
77-7015
Product name
Tris(2-phenylpyridinato-C2,N)iridium(III), 95%
Packaging
50mg
Price
$64
Updated
2024/03/01
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Tris(2-phenylpyridine)iridium (Ir(ppy)3) Chemical Properties,Usage,Production

Applications

Tris(2-phenylpyridine)iridium(III), Ir(ppy)3, is used widely in organic light-emitting diodes (OLEDs) due to its high quantum yields and thermal stability.
Utilizing all of its singlet and triplet excitons for the emission, this green light emitting Ir(ppy)3 exhibits a very bright phosphorescence with an internal quantum yield of almost 100%. It is one of the most successful green-triplet emitters in the rapidly developing field of OLED display technology.

Reactions

  1. Photocatalyst for ?-amino C–H arylation of cyano(hetero)arenes by tertiary amines
  2. Photocatalyst for trifluoromethylation of alkenes and alkynes
  3. Photocatalyst for reduction of alkyl, alkenyl, aryl iodides (a) and intramolecular reductive cyclizations (d)
  4. Photocatalyst for organocatalyst assisted direct arylation of allylic sp3 C–H bonds
  5. Photocatalyst for the generation multifluorinated biaryls via functionalization of the C−F bond of a perfluoroarene and C−H bond of the other arene in the presence of amines
  6. Photocatalyst for visible-light photoredox arylation of thiols with various aryl halides

Description

Tris(2-phenylpyridine)iridium(III), Ir(ppy)3, is used widely in organic light-emitting diodes (OLEDs) due to its high quantum yields and thermal stability.

Chemical Properties

Light yellow to red solid

Uses

suzuki reaction

Uses

Tris(2-phenylpyridine)iridium can be useful as a photoredox catalyst in the preparation of fused-quinoxaline derivatives, difluorinated ketones and carbazoles. It can be a useful modifier in optogenetic control of behavior of larva expressing ChR2 in Drosophila melanogaster. It can also be useful in the development of a metal-?containing nucleoside that possesses both therapeutic and diagnostic activity against cancer.

General Description

Tris-(2-phenylpyridine) iridium [Ir(ppy)3] is a heavy metal complex. [Ir(ppy)3] is the most frequently used precursor molecule for the synthesis of electro-phosphorescent materials, which are then used in organic light emitting diodes (OLEDs). It provides green-color emission and high phosphorescence quantum yield close to unity.

Tris(2-phenylpyridine)iridium (Ir(ppy)3) Preparation Products And Raw materials

Raw materials

Preparation Products

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Tris(2-phenylpyridine)iridium (Ir(ppy)3) Suppliers

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View Lastest Price from Tris(2-phenylpyridine)iridium (Ir(ppy)3) manufacturers

Zhejiang Free Trade Zone Violet Trade Co., Ltd.
Product
Fac-Ir (ppy)3 94928-86-6
Price
US $0.00/g
Min. Order
1g
Purity
99.90%
Supply Ability
100kgs
Release date
2021-09-16
WUHAN FORTUNA CHEMICAL CO., LTD
Product
Tris(2-phenylpyridine)iridium /Ir(ppy)3 94928-86-6
Price
US $0.00/g
Min. Order
1g
Purity
98%; 99%
Supply Ability
500G
Release date
2021-05-28
LY Global chemicals co.,ltd .
Product
Tris(2-phenylpyridine)iridium (Ir(ppy)3) 94928-86-6
Price
US $0.00/kg
Min. Order
1kg
Purity
98.0%min
Supply Ability
100kg
Release date
2023-03-15

94928-86-6, Tris(2-phenylpyridine)iridium (Ir(ppy)3)Related Search:

Iridium Pyridine sulfur trioxide 2-Phenylpyridine TRIPHENYLBORANE Triphenylphosphine BIS-Tris BUFFER SOLUTION PH = 6,00 (20 °C) (POTASSIUM DIHYDROGEN PHOSPHATE/SODIUM HYDROXIDE) 2,4,6-Collidine Triphenylphosphine oxide Triphenylmethyl Chloride Tricine Tris(hydroxymethyl)aminomethane Thieno[3,2-b]thiophene tris(2-carboxyethyl)phosphine Tris(2-chloroethyl) phosphate tris-(1,10-phenanthroline)ruthenium N,N'- Dibutylquinacridone Coumarin 6

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  • TRIS(2-PHENYLPYRIDINE)IRIDIUM(III) OLED GREEN LIGHT EMITTER ΛPL 512 NM (FILM)
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  • REF DUPL: fac-tris(2-(2-pyridinyl)phenyl)iridium
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  • Tris[2-phenylpyridinato-C2,N]iridium(III),Ir(ppy)3, Iridium, tris[2-(2-pyridinyl-κN)phenyl-κC]
  • Tris(2-phenylpyridin
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  • Tris[2-phenylpyridinato-C2,N]iridium(III)
  • Tris(2-phenylpyridinato)iridium(III)
  • Ir(ppy)3 , Tris(2-phenylpyridine)iridiuM
  • 1Tris(2-phenylpyridine)iridiuM(III)/ Ir(ppy)3
  • Tris[2-phenylpyridinato-C2
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  • Tris(2-phenylpyridine-C2,N') IridiuM (III)
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  • Tris(2-phenylpyridine)iridium (Ir(ppy)3) ISO 9001：2015 REACH
  • sublimed grade
  • Tris[2-phenylpyridinato-C2,N]iridium
  • 94928-86-6
  • C30H24IrN3
  • C33H27IrN3
  • C33H24IrN3
  • Electronic Chemicals
  • electronic
  • Classes of Metal Compounds
  • Highly Purified Reagents
  • Ir (Iridium) Compounds
  • Other Categories
  • Refined Products by Sublimation
  • Transition Metal Compounds
  • olde Materials
  • oled materials
  • fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis, functional materials
  • OLED
  • 94928-86-6