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(METHOXYMETHYL)DIPHENYLPHOSPHINE OXIDE

Product Name
(METHOXYMETHYL)DIPHENYLPHOSPHINE OXIDE
CAS No.
4455-77-0
Chemical Name
(METHOXYMETHYL)DIPHENYLPHOSPHINE OXIDE
Synonyms
diphenyl(methoxymethyl)-phosphineoxid;(METHOXYMETHYL)DIPHENYLPHOSPHINE OXIDE;DIPHENYL(METHOXYMETHYL)PHOSPHINE OXIDE;[Methoxymethyl(phenyl)phosphoryl]benzene;Methoxymethyl(diphenyl)phosphineOxide>Phosphine oxide, (methoxymethyl)diphenyl-;(Methoxymethyl)diphenylphosphine oxide 98%;(METHOXYMETHYL)DIPHENYLPHOSPHINE OXIDE, 98+%;(MethoxyMethyl)diphenylphosphine oxide, 98% 5GR
CBNumber
CB8116257
Molecular Formula
C14H15O2P
Formula Weight
246.24
MOL File
4455-77-0.mol
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(METHOXYMETHYL)DIPHENYLPHOSPHINE OXIDE Property

Melting point:
115-117 °C(lit.)
Boiling point:
334.7±25.0 °C(Predicted)
Density 
1.14±0.1 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
solubility 
methylene chloride: 0.1 g/mL, clear
form 
Crystalline Powder
color 
White to pale yellow
BRN 
649558
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Safety

Hazard Codes 
Xn
Risk Statements 
22
Safety Statements 
22-36/37
WGK Germany 
3
RTECS 
SZ0199360
HS Code 
29199000
Toxicity
mouse,LD50,oral,1500mg/kg (1500mg/kg),Khimiko-Farmatsevticheskii Zhurnal. Chemical Pharmaceutical Journal. For English translation, see PCJOAU. Vol. 24(4), Pg. 22, 1990.
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P330Rinse mouth.

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N-Bromosuccinimide Price

TCI Chemical
Product number
M1210
Product name
Methoxymethyl(diphenyl)phosphine Oxide
Purity
>98.0%(GC)
Packaging
5g
Price
$77
Updated
2024/03/01
TCI Chemical
Product number
M1210
Product name
Methoxymethyl(diphenyl)phosphine Oxide
Purity
>98.0%(GC)
Packaging
25g
Price
$305
Updated
2024/03/01
Alfa Aesar
Product number
L00912
Product name
(Methoxymethyl)diphenylphosphine oxide, 98+%
Packaging
5g
Price
$77.65
Updated
2024/03/01
Alfa Aesar
Product number
L00912
Product name
(Methoxymethyl)diphenylphosphine oxide, 98+%
Packaging
25g
Price
$274.65
Updated
2024/03/01
TRC
Product number
M219615
Product name
Methoxymethyl(diphenyl)phosphine Oxide
Packaging
500mg
Price
$75
Updated
2021/12/16
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(METHOXYMETHYL)DIPHENYLPHOSPHINE OXIDE Chemical Properties,Usage,Production

Chemical Properties

White to pale yellow crystalline powder

Uses

Catalyst for:

  • Molybdenum hexacarbonyl-mediated Pauson-Khand reactions
  • Rhodium-catalyzed hydroformylation reaction

Application

Horner-Wittig reagent for the preparation of methoxyvinyl ethers and hence homologous aldehydes; the  anion has greater stability and nucleophilicity than the analogous phosphonium ylide.

storage

Commercial material (97-98%) is satisfactory as received. The  toxicological properties of the reagent are unknown.

(METHOXYMETHYL)DIPHENYLPHOSPHINE OXIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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(METHOXYMETHYL)DIPHENYLPHOSPHINE OXIDE Suppliers

Aladdin Scientific
Tel
Email
tp@aladdinsci.com
Country
United States
ProdList
57505
Advantage
58
Combi-Blocks Inc.
Tel
--
Fax
--
Email
sales@combi-blocks.com
Country
United States
ProdList
6618
Advantage
69
SynQuest Laboratories, Inc.
Tel
--
Fax
--
Email
info@synquestlabs.com
Country
United States
ProdList
6871
Advantage
62
TCI America
Tel
--
Fax
--
Email
sales@tciamerica.com
Country
United States
ProdList
6909
Advantage
75
Riedel-de Haen AG
Tel
--
Fax
--
Country
United States
ProdList
6773
Advantage
87
Alfa Aesar
Tel
--
Fax
--
Email
tech@alfa.com
Country
United States
ProdList
6814
Advantage
81
3B Scientific Corporation
Tel
--
Fax
--
Email
sales@3bsc.com
Country
United States
ProdList
6718
Advantage
47
Chemiplus Corporation
Tel
--
Fax
--
Email
okazaki@chemiplus.com
Country
United States
ProdList
3198
Advantage
38
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View Lastest Price from (METHOXYMETHYL)DIPHENYLPHOSPHINE OXIDE manufacturers

Career Henan Chemical Co
Product
(METHOXYMETHYL)DIPHENYLPHOSPHINE OXIDE 4455-77-0
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100
Release date
2019-06-28

4455-77-0, (METHOXYMETHYL)DIPHENYLPHOSPHINE OXIDERelated Search:


  • diphenyl(methoxymethyl)-phosphineoxid
  • Phosphine oxide, (methoxymethyl)diphenyl-
  • (METHOXYMETHYL)DIPHENYLPHOSPHINE OXIDE, 98+%
  • DIPHENYL(METHOXYMETHYL)PHOSPHINE OXIDE
  • (METHOXYMETHYL)DIPHENYLPHOSPHINE OXIDE
  • (MethoxyMethyl)diphenylphosphine oxide, 98% 5GR
  • (Methoxymethyl)diphenylphosphine oxide 98%
  • Methoxymethyl(diphenyl)phosphineOxide&gt
  • [Methoxymethyl(phenyl)phosphoryl]benzene
  • 4455-77-0
  • C6H52POCH2OCH3
  • Catalysis and Inorganic Chemistry
  • Phosphine Ligands
  • Phosphorus Compounds
  • Horner-Emmons Reaction
  • Wittig & Horner-Emmons Reaction
  • Wittig & Horner-Emmons Reaction
  • Horner-Emmons Reaction
  • Synthetic Organic Chemistry