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Hydroxylamine sulfate

Product Name
Hydroxylamine sulfate
CAS No.
10039-54-0
Chemical Name
Hydroxylamine sulfate
Synonyms
HYDROXYLAMINE SULPHATE;HAS;HYDROXYLAMMONIUM SULPHATE;HYDROXYLAMMONIUM SULFATE;Hydroxyamine sulfate;Hydroxylammonium;Hydroxylammoniumsulfat;HuHAS1;amine suL;HA synthase 1
CBNumber
CB8205115
Molecular Formula
H2O4S.2H3NO
Formula Weight
164.14
MOL File
10039-54-0.mol
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Hydroxylamine sulfate Property

Melting point:
170 °C (dec.)(lit.)
Boiling point:
56.5℃
Density 
1.86
vapor pressure 
0.001Pa at 20℃
storage temp. 
-20°C
solubility 
water: soluble(lit.)
form 
Crystals
color 
White
PH
3.6 (10g/l, H2O, 20℃)
Water Solubility 
329 g/L (20 ºC)
Sensitive 
Hygroscopic
Merck 
14,4828
Stability:
Stable, but may be an explosion hazard - do not heat. May decompose explosively in the presence of alkalies. Air sensitive. Hygroscopic. Incompatible with copper, copper alloys, strong oxidising agents, strong bases, nitrites.
LogP
-1.031 (est)
CAS DataBase Reference
10039-54-0(CAS DataBase Reference)
EPA Substance Registry System
Hydroxylamine sulfate (2:1) (10039-54-0)
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Safety

Hazard Codes 
Xn,N,E
Risk Statements 
22-36/38-43-48/22-50-40-21/22-2
Safety Statements 
22-24-37-61-36/37
RIDADR 
UN 2865 8/PG 3
WGK Germany 
3
RTECS 
NC5425000
21
TSCA 
Yes
HazardClass 
8
PackingGroup 
III
HS Code 
28251000
Toxicity
LD50 orally in Rabbit: 842 mg/kg LD50 dermal Rabbit 1500 - 2000 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H290May be corrosive to metals

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H351Suspected of causing cancer

H373May cause damage to organs through prolonged or repeated exposure

H400Very toxic to aquatic life

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
210250
Product name
Hydroxylamine sulfate
Purity
99%
Packaging
1kg
Price
$138
Updated
2024/03/01
Sigma-Aldrich
Product number
1.04617
Product name
Hydroxylammonium sulfate
Purity
GR for analysis
Packaging
500g
Price
$315
Updated
2024/03/01
TCI Chemical
Product number
H0196
Product name
Hydroxylamine Sulfate
Purity
>98.0%(T)
Packaging
25g
Price
$18
Updated
2024/03/01
TCI Chemical
Product number
H0196
Product name
Hydroxylamine Sulfate
Purity
>98.0%(T)
Packaging
500g
Price
$29
Updated
2024/03/01
Alfa Aesar
Product number
088944
Product name
Hydroxylamine sulfate, 99%
Packaging
500g
Price
$54.6
Updated
2024/03/01
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Hydroxylamine sulfate Chemical Properties,Usage,Production

Chemical Properties

Also hydroxylammonium sulfate, or HS, (NH2OH)2·H2S04 is colorless crystals that are soluble in water and slightly soluble in alcohol. The solution has a corrosive action on the skin. Used as a reducing agent, photographic developer, purification agent for aldehydes and ketones, chemical synthesis, textile chemical, oxidation inhibitor for fatty acids, catalyst, in biological and biochemical research, for making oximes for paints and varnishes, and rustproofing.

Physical properties

Colorless, crystalline solid; melts at 177°C (decomposes); very soluble in386 HYDROXYLAMINE HYDROCHLORIDE / HYDROXYLAMINE SULFATEpp-03-25-new dots.qxd 10/23/02 2:38 PM Page 386 water; slightly soluble in alcohol.

Uses

Hydroxylammonium sulfate is a reducing agent in photography; catalyst, swelling agent, and copolymerization inhibitor in polymerization processes; in chemical synthesis; as a textile chemieal; as an oxidation inhibitor; in making oximes for paints and varnishes; in rustproofing; in nondiscoloring short -stoppers for synthetic rubbers; for unhairing hides; in biological and biochemical research; as a purification agent for aldehydes and ketones; converts aldehydes and ketones to oximes and acid chlorides to hydroxamic acids.

Uses

Hydroxylamine sulfate may be used to prepare highly sensitive cellulose tape, used for the detection of formaldehyde gas. It may be used in the quantitative determination of perchlorate in biological fluids by spectrophotometric methods .

Uses

As reducing agent in photography; in synthetic and analytical chemistry; to purify aldehydes and ketones. As antioxidant for fatty acids and soaps. As dehairing agent for hides.

Uses

Used as to purify aldehydes and ketones; reagent for mercury and silver detection in water; reducing agent.

Preparation

Hydroxylamine sulfate may be prepared by mixing stoichiometric amountsof hydroxylamine and sulfuric acid. It also may be prepared by electrolytical-ly reducing an aqueous solution of ammonium sulfate.

General Description

Colorless crystalline solid. Contact may cause severe irritation to skin, eyes, and mucous membranes. May be toxic by ingestion.

Air & Water Reactions

Water soluble.

Reactivity Profile

Sulfuric acid fumes may form in fires [USCG, 1999]. Solid Hydroxylamine sulfate explodes when heated to 170°C., [Chem. Process 26:30(1963)]. Sodium ignites on contact with hydroxylamine. (Mellor, 1940, Vol. 8, 292.)

Hazard

Irritant to tissue.

Health Hazard

Inhalation of dust or ingestion may cause systemic poisoning characterized by cyanosis, methemoglobinemia, convulsions, and coma. Contact with eyes or skin causes irritation.

Fire Hazard

Special Hazards of Combustion Products: Sulfuric acid fumes may form in fires.

Flammability and Explosibility

Non flammable

Safety Profile

Poison by skin contact and intraperitoneal routes. Mutation data reported. A corrosive irritant to skin, eyes, and mucous membranes. Moderately explosive when exposed to heat or by chemical reaction. In the presence of alkalies at elevated temperatures, free hydroxylamine is liberated and may decompose explosively. When heated to decomposition it emits toxic fumes of SOx and NOx. See also AMINES and SULFATES.

Purification Methods

Crystallise it from boiling water (1.6mL/g) by cooling to 0o.

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Hydroxylamine sulfate Suppliers

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View Lastest Price from Hydroxylamine sulfate manufacturers

Hebei Dangtong Import and export Co LTD
Product
Hydroxylamine sulfate 10039-54-0
Price
US $100.00-90.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20Tons
Release date
2023-10-08
Baoji Guokang Bio-Technology Co., Ltd.
Product
Hydroxylamine sulfate 10039-54-0
Price
US $3560.00/T
Min. Order
1T
Purity
98%
Supply Ability
1-100mt
Release date
2021-06-04
Hebei Weibang Biotechnology Co., Ltd
Product
Hydroxylamine sulfate 10039-54-0
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-10-24

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