Trifluoromethylthiobenzene
- Product Name
- Trifluoromethylthiobenzene
- CAS No.
- 456-56-4
- Chemical Name
- Trifluoromethylthiobenzene
- Synonyms
- (TRIFLUOROMETHYLTHIO)BENZENE;PHENYL TRIFLUOROMETHYL SULFIDE;TRIFLUOROMETHYL PHENYL SULFIDE;Phenyl(trifluoromethyl)sulfane;PHENYL TRIFLUOROMETHYL SULPHIDE;PhenylTrifluoromethylSulfide>Trifluoromethyl Phenyl Sulpuide;Phenyltrifluoromethylsulphide98%;Trifluoromethyl phenyl thioether;Benzene, [(trifluoromethyl)thio]-
- CBNumber
- CB8257169
- Molecular Formula
- C7H5F3S
- Formula Weight
- 178.17
- MOL File
- 456-56-4.mol
Trifluoromethylthiobenzene Property
- Boiling point:
- 142 °C (lit.)
- Density
- 1.249 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.466(lit.)
- Flash point:
- 100 °F
- form
- clear liquid
- color
- Colorless to Almost colorless
- Sensitive
- Stench
- BRN
- 2043134
- CAS DataBase Reference
- 456-56-4(CAS DataBase Reference)
- NIST Chemistry Reference
- Phenyl trifluoromethyl sulfide(456-56-4)
Safety
- Hazard Codes
- T
- Risk Statements
- 10-36/37/38
- Safety Statements
- 16-36-36/37/39-23
- RIDADR
- UN 1993 3/PG 3
- WGK Germany
- 3
- Hazard Note
- Toxic/Stench
- HazardClass
- 3
- PackingGroup
- III
- HS Code
- 29309090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H226Flammable liquid and vapour
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- P1693
- Product name
- Phenyl Trifluoromethyl Sulfide
- Purity
- >97.0%(GC)
- Packaging
- 5g
- Price
- $48
- Updated
- 2024/03/01
- Product number
- P1693
- Product name
- Phenyl Trifluoromethyl Sulfide
- Purity
- >97.0%(GC)
- Packaging
- 25g
- Price
- $184
- Updated
- 2024/03/01
- Product number
- L10114
- Product name
- Phenyl trifluoromethyl sulfide, 98%
- Packaging
- 1g
- Price
- $24.65
- Updated
- 2024/03/01
- Product number
- L10114
- Product name
- Phenyl trifluoromethyl sulfide, 98%
- Packaging
- 5g
- Price
- $66.65
- Updated
- 2024/03/01
- Product number
- P399545
- Product name
- Phenyl Trifluoromethyl Sulfide
- Packaging
- 500mg
- Price
- $75
- Updated
- 2021/12/16
Trifluoromethylthiobenzene Chemical Properties,Usage,Production
Uses
Phenyl trifluoromethyl sulfide may be used in the preparation of:
- sulfoxides, dithiane dioxide, and dithiolane dioxide via iron-catalyzed oxidation of sulfides, dithiane, or dithiolane with hydrogen peroxide
- benzophenone hydrazone derivatives
- trifluoro- and difluoromethylsilanes by reductive coupling of fluoromethyl sulfones, sulfoxides and sulfides with chlorosilanes
Synthesis Reference(s)
The Journal of Organic Chemistry, 50, p. 4047, 1985 DOI: 10.1021/jo00221a017
Synthesis, p. 721, 1975 DOI: 10.1055/s-1975-23905
General Description
Phenyl trifluoromethyl sulfide (PTFMS) is an aryl trifluoromethyl sulfide. PTFMS with (triethylgermyl)sodium forms a reagent system that has been employed for the trifluoromethylation of certain imines. The reaction between OH radical and PTFMS has been analyzed using pulse radiolysis technique and quantum chemical calculations.
Trifluoromethylthiobenzene Preparation Products And Raw materials
Raw materials
Preparation Products
Trifluoromethylthiobenzene Suppliers
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View Lastest Price from Trifluoromethylthiobenzene manufacturers
- Product
- Trifluoromethylthiobenzene 456-56-4
- Price
- US $3.00/KG
- Min. Order
- 1KG
- Purity
- 98%min
- Supply Ability
- 200KG
- Release date
- 2020-01-07