ChemicalBook > CAS DataBase List > 3,4-Diaminotoluene

3,4-Diaminotoluene

Product Name
3,4-Diaminotoluene
CAS No.
496-72-0
Chemical Name
3,4-Diaminotoluene
Synonyms
Toluene-3,4-diamine;o-Toluenediamine;1,2-Benzenediamine, 4-methyl-;3,4-DAT;JACS-496-72-0;3.4-Diaminotol;3,4-TOLUOLDIAMINE;3,4-Dhamphetamine;3,4-TOLUENEDIAMINE;3,4-DIAMINOTOLUENE
CBNumber
CB8258207
Molecular Formula
C7H10N2
Formula Weight
122.17
MOL File
496-72-0.mol
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3,4-Diaminotoluene Property

Melting point:
87-89 °C (lit.)
Boiling point:
155-156 °C/18 mmHg (lit.)
Density 
1.2207 (rough estimate)
refractive index 
1.5103 (estimate)
Flash point:
155-156°C/18mm
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
solubility 
Chloroform (Sparingly), Methanol (Slightly)
pka
4.59±0.10(Predicted)
form 
Crystalline Chunks or Flakes
color 
Brown to grayish-brown
Water Solubility 
16 g/L (20 ºC)
BRN 
507965
Stability:
Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference
496-72-0(CAS DataBase Reference)
NIST Chemistry Reference
1,2-Benzenediamine, 4-methyl-(496-72-0)
EPA Substance Registry System
3,4-Diaminotoluene (496-72-0)
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Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22-36/37/38-52/53-40-36-22
Safety Statements 
26-37/39-61-36/37/39
RIDADR 
UN 2811
WGK Germany 
2
RTECS 
XS9820000
TSCA 
Yes
HazardClass 
6.1(b)
PackingGroup 
III
HS Code 
29215119
Hazardous Substances Data
496-72-0(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
33380
Product name
4-Methyl-o-phenylenediamine
Purity
purum, ≥98.0% (NT)
Packaging
100g
Price
$54.7
Updated
2024/03/01
Sigma-Aldrich
Product number
33380
Product name
4-Methyl-o-phenylenediamine
Purity
purum, ≥98.0% (NT)
Packaging
500g
Price
$127
Updated
2023/06/20
TCI Chemical
Product number
D0125
Product name
3,4-Diaminotoluene
Purity
>98.0%(T)
Packaging
25g
Price
$88
Updated
2024/03/01
Alfa Aesar
Product number
B24378
Product name
3,4-Diaminotoluene, 97%
Packaging
100g
Price
$28.65
Updated
2024/03/01
Alfa Aesar
Product number
B24378
Product name
3,4-Diaminotoluene, 97%
Packaging
500g
Price
$122.65
Updated
2024/03/01
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3,4-Diaminotoluene Chemical Properties,Usage,Production

Chemical Properties

Off-white small blocks

Uses

5-Methylbenzotriazole intermediate.

Uses

4-Methyl-o-phenylenediamine was employed as chromogenic reagent in the spectrophotometric determination of selenium(IV). It was used in the synthesis of an asymmetrical tetradentate Schiff base via condensation with dehydroacetic acid and salicylic aldehyde.

Synthesis Reference(s)

Tetrahedron Letters, 42, p. 2277, 2001 DOI: 10.1016/S0040-4039(01)00163-0

General Description

A colorless to brownish purple crystalline solid. Toxic by ingestion and inhalation and an irritant to skin and eyes. Soluble in water, alcohol and ether. Decomposes to emit toxic oxides of nitrogen when heated to high temperature. Used in making dyes.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

3,4-Diaminotoluene neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

Fire Hazard

Flash point data for 3,4-Diaminotoluene are not available. 3,4-Diaminotoluene is probably combustible.

3,4-Diaminotoluene Preparation Products And Raw materials

Raw materials

4-Methyl-2-nitroaniline

Preparation Products

5-METHYL-2,1,3-BENZOTHIADIAZOLE 2,1,3-Benzothiadiazol-5-ylmethanol 2,1,3-Benzothiadiazole-5-carbaldehyde 5-(BROMOMETHYL)-2,1,3-BENZOTHIADIAZOLE
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3,4-Diaminotoluene Suppliers

Americas 1 Belgium 2 Canada 1 China 288 Europe 2 France 1 Germany 10 India 20 Italy 1 Japan 4 Russia 1 Slovakia 1 Switzerland 2 The Netherlands 2 Ukraine 1 United Kingdom 11 United States 34 Global 382
Liling Chuangli Technology Co. LTD
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View Lastest Price from 3,4-Diaminotoluene manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
3,4-Diaminotoluene 496-72-0
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-01-09
Baoji Guokang Bio-Technology Co., Ltd.
Product
3,4-Diaminotoluene 496-72-0
Price
US $30650.00/T
Min. Order
25KG
Purity
98%
Supply Ability
1-200mt
Release date
2021-06-04
Hebei Weibang Biotechnology Co., Ltd
Product
3,4-Diaminotoluene 496-72-0
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-20

496-72-0, 3,4-DiaminotolueneRelated Search:

Kresoxim-methyl Methyl acrylate Bensulfuron methyl Xylene Benzylamine p-Toluidine m-Xylene o-Phenylenediamine 2,5-DIAMINOTOLUENE Methylparaben o-Xylene METHYL THIOPHENE-2-CARBOXYLATE Iminodiacetonitrile Thiophanate-methyl Methyl 2,3-DIAMINOTOLUENE OEKANAL, 250 MG,ORTHO-DIAMINOTOLUENE,2,3-Diaminotoluene 98%,2,3-DIAMINOTOLUENE Parathion-methyl Methyl bromide

  • 1,2-benzenediamine,-methyl-
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  • 3,4- twoaMino toluene
  • 3,4-DiaMinotoluene, 99.5%
  • 3,4-Diaminotoluene, 4-Methylphenylene-1,2-diamine
  • 2-AMino-4-Methylaniline
  • 2-AMino-5-Methylaniline
  • 4-Methyl-2-aMinoan
  • 3,4-Toluenediamine Tolylene-3,4-diamine
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  • 3,4-Diaminotoluene 99%, purified by sublimation
  • 4-Methyl-o-phenylenediamine purum, >=98.0% (NT)
  • 4-Methyl-o-phenylenediamine Vetec(TM) reagent grade, 97%
  • 3.4-Diaminotol
  • 3,4-DAT
  • JACS-496-72-0
  • 3,4-Diaminotoluene &gt
  • 3,4-Diaminotoluene ISO 9001：2015 REACH
  • 3,4-Diaminotoluene(496-72-0)
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