5-Fluoro-2-methylaniline

Product Name: 5-Fluoro-2-methylaniline
CAS No.: 367-29-3
Chemical Name: 5-Fluoro-2-methylaniline
Synonyms: 2-AMINO-4-FLUOROTOLUENE;2-METHYL-5-FLUOROANILINE;2-Amino-4-fluorotoluene~5-Fluoro-o-toluidine;TIMTEC-BB SBB004266;5-Fluoro-2-methylani;5-Fluoro-2-toluidine;Fluoromethylaniline7;5-FLUORO-O-TOLUIDINE;4-Fluoro-2-Aminotoluene;5-FLUORO-2-METHYLANILINE
CBNumber: CB8263018
Molecular Formula: C7H8FN
Formula Weight: 125.14
MOL File: 367-29-3.mol

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5-Fluoro-2-methylaniline Property

Melting point:: 38-40 °C (lit.)
Boiling point:: 98-100°C 15mm
Density: 1.13 g/cm3 (20℃)
refractive index: 1.538
Flash point:: 194 °F
storage temp.: Keep in dark place,Inert atmosphere,2-8°C
form: Crystalline Solid or Liquid
pka: 3.44±0.10(Predicted)
color: Purple to brown
Water Solubility: insoluble
BRN: 2637584
InChI: InChI=1S/C7H8FN/c1-5-2-3-6(8)4-7(5)9/h2-4H,9H2,1H3
InChIKey: JLCDTNNLXUMYFQ-UHFFFAOYSA-N
SMILES: C1(N)=CC(F)=CC=C1C
CAS DataBase Reference: 367-29-3(CAS DataBase Reference)
NIST Chemistry Reference: 5-Fluoro-2-methylaniline(367-29-3)

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Safety

Hazard Codes: Xn,T,Xi
Risk Statements: 20/21/22-36/37/38-23/24/25
Safety Statements: 26-27-36/37/39-45-36
RIDADR: UN 1325 4.1/PG 2
WGK Germany: 3
Hazard Note: Toxic/Irritant
HazardClass: 6.1
PackingGroup: III
HS Code: 29214300

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H311Toxic in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

H373May cause damage to organs through prolonged or repeated exposure

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: F10402
Product name: 5-Fluoro-2-methylaniline
Purity: 99%
Packaging: 10g
Price: $31.8
Updated: 2023/01/07

TCI Chemical

Product number: F0232
Product name: 5-Fluoro-2-methylaniline
Purity: >98.0%(GC)
Packaging: 5g
Price: $27
Updated: 2024/03/01

TCI Chemical

Product number: F0232
Product name: 5-Fluoro-2-methylaniline
Purity: >98.0%(GC)
Packaging: 25g
Price: $78
Updated: 2024/03/01

Alfa Aesar

Product number: B25381
Product name: 5-Fluoro-2-methylaniline, 98%
Packaging: 10g
Price: $42.65
Updated: 2024/03/01

Alfa Aesar

Product number: B25381
Product name: 5-Fluoro-2-methylaniline, 98%
Packaging: 50g
Price: $141.65
Updated: 2024/03/01

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5-Fluoro-2-methylaniline Chemical Properties,Usage,Production

Chemical Properties

purple to brown crystalline solid

Uses

Used as a pharmaceutical intermediate in organic synthesis.

Synthesis

In a nitrogen-fed glovebox, Pd(P(o-tol)3)2 and CyPF-PtBu (1:1 ratio) were dissolved in dioxane and mixed for 5 min. A 20 mL scintation vial was charged with aryl halide (0.60 mmol, 1 equiv), ammonium sulfate (0.90 mmol, 1.5 equiv), and sodium tert-butoxide (2.7 mmol, 4.5 equiv). To this vial was added 6 mL of anhydrous dioxane and the appropriate amount of catalyst from the stock solution. The reaction vial was sealed with a Teflon-lined screw cap and removed from the glovebox. The reaction was stirred at the desired temperature for 12 h. The reaction mixture was diluted with EtOAc and filtered through a pad of Celite. The filtrate was concentrated in vacuo, and the crude product was purified by flash column chromatography. 5-Fluoro-2-methylaniline (Table 3, 2s) (CAS: 367-29-3) The reaction to form this product was conducted with 0.5 mol % Pd(P(o-tol)3)2 and 0.5 mol % CyPF-PtBu for 8 h. The crude product was isolated by flash column chromatography (5:1 Hexanes:EtOAc). 5-Fluoro-2-methylaniline was isolated as an oil in 76% yield. 1(600 MHz, CDCl3): δ 6.97 (t, J= 7.2 Hz, 1H), 6.40 (t, J= 9.9 Hz, 2H), 3.69 (s, 2H), 2.12 (s, 3H). 13C-NMR(151 MHz, CDCl3): δ 162.24 (d, JC-F= 240.9 Hz), 145.82 (d, JC-F= 10.6 Hz), 131.12 (d, JC-F= 9.6 Hz), 117.62 (d, JC-F = 2.6 Hz), 104.67 (d, JC-F= 21.0 Hz), 101.56 (d, JC-F= 24.6 Hz), 16.62 (s).

5-Fluoro-2-methylaniline Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 5-Fluoro-2-methylaniline manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: 5-Fluoro-2-methylaniline 367-29-3
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20t
Release date: 2024-06-18

Henan Aochuang Chemical Co.,Ltd.

Product: 5-Fluoro-2-methylaniline 367-29-3
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-09-27

Honest Joy Holdings Limited

Product: 5-Fluoro-2-methylaniline 367-29-3
Price: US $0.00/KG
Min. Order: 1KG
Purity: 97.4%
Supply Ability: 100 tons
Release date: 2022-02-18

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Nitrogen Compounds

Organic Building Blocks

C7

Building Blocks

Amines

Miscellaneous

Halogen toluene

Aniline

Fluorobenzene

Aromatic Hydrocarbons (substituted) & Derivatives

Anilines, Aromatic Amines and Nitro Compounds