BrettPhos Pd G4
Reactions- Product Name
- BrettPhos Pd G4
- CAS No.
- 1599466-83-7
- Chemical Name
- BrettPhos Pd G4
- Synonyms
- BrettPhos Palladacycle Gen. 4;BrettPhos Pd G4;BrettPhos Pd G4c;Gingerol Impurity 5;dicyclohexyl[3,6-dimethoxy-2,4,6-tris(propan-2-yl)-[1,1-;Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2;Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II);Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II);[2'-(Methylamino)-2-biphenylyl]palladium(1+) methanesulfonate-dicyclohexyl(2',4',6'-triisopropyl-3,6-dimethoxy-2-biphenylyl)phosphine (1:1:1);Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II), min
- CBNumber
- CB83148149
- Molecular Formula
- C49H68NO5PPds
- Formula Weight
- 920.53
- MOL File
- 1599466-83-7.mol
BrettPhos Pd G4 Property
- form
- Powder
- color
- off-white to beige
- InChI
- InChI=1S/2C35H53O5PS.C13H12N.CH4.Pd/c2*1-22(2)25-19-28(23(3)4)32(29(20-25)24(5)6)33-30(39-7)21-31(42(36,37)38)34(40-8)35(33)41(26-15-11-9-12-16-26)27-17-13-10-14-18-27;1-14-13-10-6-5-9-12(13)11-7-3-2-4-8-11;;/h2*19-24,26-27H,9-18H2,1-8H3,(H,36,37,38);2-7,9-10,14H,1H3;1H4;/q;;;;+1/p-2
- InChIKey
- ZTBOMOZSCNBFNQ-UHFFFAOYSA-L
- SMILES
- C1(C2=C(C(C)C)C=C(C(C)C)C=C2C(C)C)=C(OC)C=C(S([O-])(=O)=O)C(OC)=C1P(C1CCCCC1)C1CCCCC1.C1(C2=C(C(C)C)C=C(C(C)C)C=C2C(C)C)=C(OC)C=C(S([O-])(=O)=O)C(OC)=C1P(C1CCCCC1)C1CCCCC1.[Pd+]C1=CC=CC=C1C1=CC=CC=C1NC.C
Safety
- HS Code
- 2843909000
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
N-Bromosuccinimide Price
- Product number
- 804355
- Product name
- BrettPhos Pd G4
- Packaging
- 250MG
- Price
- $106
- Updated
- 2023/06/20
- Product number
- 804355
- Product name
- BrettPhos Pd G4
- Packaging
- 1G
- Price
- $326
- Updated
- 2023/06/20
- Product number
- 46-0333
- Product name
- Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [BrettPhos Palladacycle Gen. 4]
- Packaging
- 250mg
- Price
- $95
- Updated
- 2024/03/01
- Product number
- 46-0333
- Product name
- Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [BrettPhos Palladacycle Gen. 4]
- Packaging
- 1g
- Price
- $290
- Updated
- 2024/03/01
- Product number
- 46-0333
- Product name
- Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [BrettPhos Palladacycle Gen. 4]
- Packaging
- 5g
- Price
- $1158
- Updated
- 2024/03/01
BrettPhos Pd G4 Chemical Properties,Usage,Production
Reactions
Catalyst used for the N-arylation of amines.
General Description
BrettPhos Pd G4 is an N-substituted 2-aminobiphenylpalladium methanesulfonate precatalyst. It is a fourth generation (G4) Buchwald precatalyst that is similar to the third generation (G3) precatalysts except that the amino group on the biphenyl backbone is methylated. This modification helps to prevent the limitations of using the third generation precatalysts. It is air, moisture and thermally-stable and shows good solubility in common organic solvents. BrettPhos Pd G4 is highly useful in cross-coupling reactions. Some of its excellent features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.
BrettPhos Pd G4 Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from BrettPhos Pd G4 manufacturers
- Product
- BrettPhos Pd G4 1599466-83-7
- Price
- US $0.00-0.00/G
- Min. Order
- 1G
- Purity
- 98%
- Supply Ability
- 500
- Release date
- 2024-03-07
- Product
- Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) 1599466-83-7
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20T
- Release date
- 2020-04-21
- Product
- Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) / BrettPhos Pd G4 1599466-83-7
- Price
- US $10.00-10.00/g
- Min. Order
- 1g
- Purity
- 0.98
- Supply Ability
- 50kg
- Release date
- 2020-12-01