ChemicalBook > CAS DataBase List > (tert-Butoxycarbonylmethyl)triphenylphosphanium bromide

(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide

Product Name
(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide
CAS No.
59159-39-6
Chemical Name
(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide
Synonyms
(2-(tert-Butoxy)-2-oxoethyl)triphenylphosphonium bromide;NSC 82468;carbo-tert-butoxymethyl triphenylphosp;59159-39-6;(Boc-methyl)triphenylphosphonium Bromide;T-butoxycarbonylMethyltriphenylphosphoniuMbroMide;tert-Butoxycarbonylmethyltriphenylphosphoniumbrom;carbo-tert-butoxymethyl triphenylphosphonium bromide;(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide;(TERT-BUTOXYCARBONYLMETHYL)TRIPHENYLPHOSPHONIUM BROMIDE
CBNumber
CB8388977
Molecular Formula
C24H26BrO2P
Formula Weight
457.34
MOL File
59159-39-6.mol
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(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide Property

Melting point:
178 °C (dec.)(lit.)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
soluble in Methanol
form 
powder to crystal
color 
White to Almost white
BRN 
4631405
CAS DataBase Reference
59159-39-6(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
HS Code 
29319019
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
369047
Product name
(tert-Butoxycarbonylmethyl)triphenylphosphonium bromide
Purity
98%
Packaging
50g
Price
$153
Updated
2024/03/01
Sigma-Aldrich
Product number
369047
Product name
(tert-Butoxycarbonylmethyl)triphenylphosphonium bromide
Purity
98%
Packaging
10g
Price
$75.6
Updated
2023/06/20
TCI Chemical
Product number
B3928
Product name
(tert-Butoxycarbonylmethyl)triphenylphosphonium Bromide
Purity
>98.0%(HPLC)(T)
Packaging
25g
Price
$108
Updated
2024/03/01
Alfa Aesar
Product number
L15165
Product name
(tert-Butoxycarbonylmethyl)triphenylphosphonium bromide, 98%
Packaging
5g
Price
$36.8
Updated
2021/12/16
TRC
Product number
B657120
Product name
(Boc-methyl)triphenylphosphoniumBromide
Packaging
500mg
Price
$60
Updated
2021/12/16
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(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide Chemical Properties,Usage,Production

Uses

Reactant for:

  • Rhodium-catalyzed asymmetric hydrogenation reactions
  • Wittig reaction
  • Wittig methylenation
  • Preparation of N-(phenylmethyl)-cis-pyrrolidinediacetic acid esters via double aza-Michael addition reaction
  • Stereoselective preparation of of α-fluoro-α,β-unsaturated esters via deprotonation, followed by fluorination and stereoselective Wittig olefination with aldehydes
  • Wittig chain extension reactions

(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide Preparation Products And Raw materials

Raw materials

Preparation Products

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(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44688
Advantage
61
Jia Xing Isenchem Co.,Ltd
Tel
0573-85285100 18627885956
Fax
0573-85285100
Email
isenchem@163.com
Country
China
ProdList
9499
Advantage
66
Accela ChemBio Co.,Ltd.
Tel
021-50795510 4000665055
Fax
021-50795055
Email
sales@accelachem.com
Country
China
ProdList
11655
Advantage
64
Nanjing Chemlin Chemical Co., Ltd
Tel
025-83697070
Fax
+86-25-83453306
Email
info@chemlin.com.cn
Country
China
ProdList
19172
Advantage
64
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
Hunan Hui Bai Shi Biotechnology Co., Ltd.
Tel
0731-85526065 13308475853
Email
ivy@hnhbsj.com
Country
China
ProdList
4552
Advantage
62
Sci General Material & Chemical Ltd
Tel
21-58388037 13472507714
Fax
0086-21-56829747 Company QQ: 1589045147
Email
1589045147@qq.com
Country
China
ProdList
730
Advantage
55
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View Lastest Price from (tert-Butoxycarbonylmethyl)triphenylphosphanium bromide manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
(Tert-Butoxycarbonylmethyl)triphenylphosphanium bromide 59159-39-6
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-10
Zhuozhou Wenxi import and Export Co., Ltd
Product
(Tert-Butoxycarbonylmethyl)triphenylphosphanium bromide 59159-39-6
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-08
Career Henan Chemical Co
Product
(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide 59159-39-6
Price
US $6.68/KG
Min. Order
1KG
Purity
97%-99%
Supply Ability
1kg-1000kg
Release date
2020-01-09

59159-39-6, (tert-Butoxycarbonylmethyl)triphenylphosphanium bromideRelated Search:


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  • Synthetic Reagents
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  • Olefination
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  • C-C Bond Formation
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  • Wittig Reagents