ChemicalBook > CAS DataBase List > (tert-Butoxycarbonylmethyl)triphenylphosphanium bromide

(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide

Product Name
(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide
CAS No.
59159-39-6
Chemical Name
(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide
Synonyms
(2-(tert-Butoxy)-2-oxoethyl)triphenylphosphonium bromide;NSC 82468;carbo-tert-butoxymethyl triphenylphosp;59159-39-6;(Boc-methyl)triphenylphosphonium Bromide;T-butoxycarbonylMethyltriphenylphosphoniuMbroMide;tert-Butoxycarbonylmethyltriphenylphosphoniumbrom;carbo-tert-butoxymethyl triphenylphosphonium bromide;(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide;(TERT-BUTOXYCARBONYLMETHYL)TRIPHENYLPHOSPHONIUM BROMIDE
CBNumber
CB8388977
Molecular Formula
C24H26BrO2P
Formula Weight
457.34
MOL File
59159-39-6.mol
More
Less

(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide Property

Melting point:
178 °C (dec.)(lit.)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
soluble in Methanol
form 
powder to crystal
color 
White to Almost white
BRN 
4631405
CAS DataBase Reference
59159-39-6(CAS DataBase Reference)
More
Less

Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
HS Code 
29319019
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
369047
Product name
(tert-Butoxycarbonylmethyl)triphenylphosphonium bromide
Purity
98%
Packaging
50g
Price
$153
Updated
2024/03/01
Sigma-Aldrich
Product number
369047
Product name
(tert-Butoxycarbonylmethyl)triphenylphosphonium bromide
Purity
98%
Packaging
10g
Price
$75.6
Updated
2023/06/20
TCI Chemical
Product number
B3928
Product name
(tert-Butoxycarbonylmethyl)triphenylphosphonium Bromide
Purity
>98.0%(HPLC)(T)
Packaging
25g
Price
$108
Updated
2024/03/01
Alfa Aesar
Product number
L15165
Product name
(tert-Butoxycarbonylmethyl)triphenylphosphonium bromide, 98%
Packaging
5g
Price
$36.8
Updated
2021/12/16
TRC
Product number
B657120
Product name
(Boc-methyl)triphenylphosphoniumBromide
Packaging
500mg
Price
$60
Updated
2021/12/16
More
Less

(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide Chemical Properties,Usage,Production

Uses

Reactant for:

  • Rhodium-catalyzed asymmetric hydrogenation reactions
  • Wittig reaction
  • Wittig methylenation
  • Preparation of N-(phenylmethyl)-cis-pyrrolidinediacetic acid esters via double aza-Michael addition reaction
  • Stereoselective preparation of of α-fluoro-α,β-unsaturated esters via deprotonation, followed by fluorination and stereoselective Wittig olefination with aldehydes
  • Wittig chain extension reactions

(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide Suppliers

Americas 1 Canada 1 China 79 Europe 1 France 2 Germany 2 India 5 Japan 1 Slovakia 1 Switzerland 3 The Netherlands 1 United Kingdom 7 United States 11 Global 115
Brunschwig chemie
Tel
--
Fax
--
Email
brunschwig@brunschwig.nl
Country
The Netherlands
ProdList
4996
Advantage
67
More
Less

View Lastest Price from (tert-Butoxycarbonylmethyl)triphenylphosphanium bromide manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
（Tert-Butoxycarbonylmethyl)triphenylphosphanium bromide 59159-39-6
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-10
Zhuozhou Wenxi import and Export Co., Ltd
Product
（Tert-Butoxycarbonylmethyl)triphenylphosphanium bromide 59159-39-6
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-08
Career Henan Chemical Co
Product
(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide 59159-39-6
Price
US $6.68/KG
Min. Order
1KG
Purity
97%-99%
Supply Ability
1kg-1000kg
Release date
2020-01-09

59159-39-6, (tert-Butoxycarbonylmethyl)triphenylphosphanium bromideRelated Search:

Ethidium bromide tert-Butanol Tetrabutylammonium bromide Rocuronium bromide Allyl bromide Sodium bromate Sodium bromide Tetrabutyl titanate Chlorodimethylphenylsilane Methylmagnesium Bromide Potassium bromide Methyl bromide Methyltriphenylphosphonium bromide (2-HYDROXYETHYL)TRIPHENYLPHOSPHONIUM BROMIDE (Carbomethoxymethyl)triphenylphosphonium bromide (Carbethoxymethyl)triphenylphosphonium bromide CARBOXYMETHYL DIPHENYLPHOSPHINE OXIDE (ETHOXYCARBONYLMETHYL)DIPHENYLPHOSPHINE

  • [2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]-triphenylphosphonium bromide
  • tert-Butoxycarbonylmethyltriphenylphosphoniumbrom
  • (tert-Butoxycarbonylmethyl)tripheenyphosphonium bromide
  • (TERT-BUTOXYCARBONYLMETHYL)TRIPHENYLPHOSPHONIUM BROMIDE
  • carbo-tert-butoxymethyl triphenylphosphonium bromide
  • (tert-Butoxycarbonylmethyl)triphenylphosphanium bromide
  • (tert-Butoxycarbonylmethyl)triphenylphosphonium bromide, 98 %
  • carbo-tert-butoxymethyl triphenylphosp
  • triphenyl tert butoxycarbonyl Methyl phosphoniuM broMide
  • T-butoxycarbonylMethyltriphenylphosphoniuMbroMide
  • NSC 82468
  • (2-(tert-Butoxy)-2-oxoethyl)triphenylphosphonium bromide
  • (tert-Butoxycarbonylmethyl)triphenylphosphonium bromide 98%
  • tert-Butoxycarbonylmethyl triphenylphosphonium bromide,97%
  • Phosphonium,[2-(1,1-dimethylethoxy)-2-oxoethyl]triphenyl-, bromide (1:1)
  • (tert-Butoxycarbonylmethyl)triphenylphosphonium Bromide &gt
  • (iterti-Butoxycarbonylmethyl)triphenylphosphoniumBromide
  • (Boc-methyl)triphenylphosphonium Bromide
  • [2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]-triphenylphosphanium
  • <font color="#ff0000">59159-39-6</font>
  • 2-(1,1-dimethylethoxy)-2-oxoethyl]triphenyl-Phosphonium bromide (1:1)
  • 59159-39-6
  • CH33CO2CCH2PC6H53Br
  • Synthetic Reagents
  • Wittig Reagents
  • Olefination
  • C-C Bond Formation
  • C-C Bond Formation
  • Olefination
  • Wittig Reagents