ChemicalBook > CAS DataBase List > Ethyl chrysanthemumate

Ethyl chrysanthemumate

Product Name
Ethyl chrysanthemumate
CAS No.
97-41-6
Chemical Name
Ethyl chrysanthemumate
Synonyms
ETHYL CHRYSANTHEMATE;PNP-α-D-Gal;Ethyl chrysant;Cyclopropaneca;TIMTEC-BB SBB007714;Ethyl chrisanthemate;Ethyl chrysanthemat.;Ethyl chrysanthemuma;Ethyl ChrsantheMuMate;ETHYL CHRYSANTHEMUMATE
CBNumber
CB8400077
Molecular Formula
C12H20O2
Formula Weight
196.29
MOL File
97-41-6.mol
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Ethyl chrysanthemumate Property

Boiling point:
112 °C10 mm Hg(lit.)
Density 
0.906 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.461(lit.)
Flash point:
184 °F
storage temp. 
2-8°C
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Liquid
color 
Yellow
Odor
at 10.00 % in dipropylene glycol. herbal wine fruity everlasting flower chrysanthemum sweet
Odor Type
herbal
BRN 
2045740
LogP
4.181 (est)
CAS DataBase Reference
97-41-6(CAS DataBase Reference)
NIST Chemistry Reference
Ethyl chrysanthemate(97-41-6)
EPA Substance Registry System
Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methyl-1-propenyl)-, ethyl ester (97-41-6)
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Safety

Safety Statements 
24/25
WGK Germany 
2
RTECS 
GZ1727000
TSCA 
Yes
HS Code 
29162090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H227Combustible liquid

H303May be harmfulif swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical
Product number
D2112
Product name
Ethyl 2,2-Dimethyl-3-(2-methyl-1-propenyl)cyclopropane-1-carboxylate
Purity
>95.0%(GC)
Packaging
25g
Price
$47
Updated
2024/03/01
TCI Chemical
Product number
D2112
Product name
Ethyl 2,2-Dimethyl-3-(2-methyl-1-propenyl)cyclopropane-1-carboxylate
Purity
>95.0%(GC)
Packaging
100g
Price
$139
Updated
2024/03/01
Alfa Aesar
Product number
H59589
Product name
Ethyl chrysanthemate, 95%
Packaging
100g
Price
$84.2
Updated
2021/12/16
Alfa Aesar
Product number
H59589
Product name
Ethyl chrysanthemate, 95%
Packaging
25g
Price
$31.3
Updated
2021/12/16
TRC
Product number
E903480
Product name
Ethyl chrysanthemate
Packaging
25g
Price
$130
Updated
2021/12/16
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Ethyl chrysanthemumate Chemical Properties,Usage,Production

Chemical Properties

clear colorless to yellow liquid. Very slightly soluble in water, soluble in alcohol and oils. Powerful, winey-herbaccous, sweet and ethereal, very pleasant odor of intriguing complexity, and with a powerfully lifting minty undertone. The spicy-hcrbaccous, warm and almost green-floral notes resemble certain notes in the Jasmin complex.

Uses

Ethyl Chrysanthemate is an organic building block used in the synthesis of various chemical compounds, such as insecticide, Resmethrin (R144685). It is used in the preparation of trans-norchrysanthemates and trans-norpyrethrates, having insecticidal activity.

Synthesis Reference(s)

Tetrahedron Letters, 22, p. 1783, 1981 DOI: 10.1016/S0040-4039(01)90438-1
Synthesis, p. 600, 1976 DOI: 10.1055/s-1976-24132

Purification Methods

Purify the ester by vacuum distillation. The free trans-acid has m 54o (from EtOAc), and the free cis-acid has m 113-116o (from EtOAc). The 4-nitrophenyl ester has m 44-45o (from pet ether) [Campbell & Harper J Chem Soc 283 1945, IR: Allen et al. J Org Chem 22 1291 1957]. [Beilstein 9 II 45.]

Ethyl chrysanthemumate Preparation Products And Raw materials

Raw materials

Copper diazoacetic acid methyl(±)cis，trans-2，2-dimethyl-3-(2-methyl-1-propenyl cyclopropane carboxylate) Hydroquinone Ethylene glycol 2,5-Dimethyl-2,4-hexadiene Methyl acetate Ethyl diazoacetate

Preparation Products

2,2-Dimethyl-3-(2-methylpropyl)cyclopropanecarboxylic acid p-(methoxymethyl)benzyl ester Allethrin trans-(±)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylic acid 2,2-DIMETHYL-3-(2-METHYLPROP-1-ENYL)CYCLOPROPANECARBOXYLIC ACID Tetramethrin
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View Lastest Price from Ethyl chrysanthemumate manufacturers

Hebei Mujin Biotechnology Co.,Ltd
Product
Ethyl chrysanthemumate 97-41-6
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-06-20
Hebei Weibang Biotechnology Co., Ltd
Product
Ethyl chrysanthemumate 97-41-6
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100 mt
Release date
2024-11-22
Hebei Chuanghai Biotechnology Co,.LTD
Product
Ethyl chrysanthemumate 97-41-6
Price
US $50.00-20.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000kg
Release date
2024-08-16

97-41-6, Ethyl chrysanthemumateRelated Search:

Poly(dimethylsiloxane) Diethyl malonate Dimethyl phthalate Ethyl acetate Ethyl acrylate Ethanol Ethyl propiolate Diethyl methylmalonate Ethyl formate Ethyl pyruvate Cyclopropane Dimethyl fumarate Ethylparaben Triethyl citrate Dimethyl sulfoxide RESMETHRIN Ethyl cinnamate 2-AMINODIETHYLMALONATE

  • (1R,3S)-2,2-dimethyl-3-(2-methylprop-1-enyl)-1-cyclopropanecarboxylic acid ethyl ester
  • 2,2-DIMETHYL-3-(2-METHYL-1-PROPENYL)CYCLOPROPANE CARBOXYLIC ACID ETHYL ESTER
  • 2,2-DIMETHYL-3-(1-ISOBUTENYL)CYCLOPROPANE-1-CARBOXYLIC ACID ETHYL ESTER
  • ethyl 2,2-dimethyl-3-(2-methylpropenyl)cyclopropanecarboxylate
  • CHRYSANTHEMUM MONOCARBOXYLIC ACID ETHYL ESTER
  • CHRYSANTHEMYLMONOCARBOXYLIC ACID ETHYL ESTER
  • ETHYL CHRYSANTHEMATE
  • ETHYL CHRYSANTHEMUMATE
  • ETHYL 2,2-DIMETHYL-3-(1-ISOBUTENYL)CYCLOPROPANE-1-CARBOXYLATE
  • ETHYL 2,2-DIMETHYL-3-(2-METHYL-1-PROPENYL)CYCLOPROPANECARBOXYLATE
  • TIMTEC-BB SBB007714
  • Chrisanthemic acid ethylester
  • Ethyl chrisanthemate
  • (+/-)-ETHYL CHRYSANTHEMUMATE, 95%, MIXTU RE OF CIS AND TRANS
  • ETHYL CHRYSANTHEMUMATE 95+% MIXTURE O&
  • Ethyl Chrysanthemate (Primary)
  • Ethyl chrysanthemumate, cis + trans, 98%
  • Primary ethyl chrysanthemat
  • Ethyl chrysanthemat.
  • Chrysanthemum monocarboxylic acid ethyl ester, 2,2-Dimethyl-3-(1-isobutenyl)cyclopropane-1-carboxylic acid ethyl ester
  • ethyl(±)cis，trans-2，2-dimethyl-3-(2-methyl propenyl cyclopropane carboxylate)
  • 2,2-dimethyl-3-(2-methyl-1-propenyl)-cyclopropanecarboxylicaciethylester
  • 2,2-Dimethyl-3-(2-methylpropenyl)cyclopropanecarboxylic acid ethyl ester
  • 2,2-dimethyl-3-(2-methylpropenyl)cyclopropanecarboxylicacidethylester
  • 2,2-dimethyl-3-(2-methylpropenyl)-cyclopropanecarboxylicaciethylester
  • chrysanthemicacidethylester
  • Chrysanthemum-monocarboxlic acid ethyl ester
  • Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methyl-1-propenyl)-, ethyl ester
  • Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methylpropenyl)-, ethyl ester
  • ethylchrysanthemumate,mixtureofcisandtrans
  • Ethyl 2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate
  • 2,2-Dimethyl-3-isobutenylcyclopropanecarboxylic acid ethyl ester
  • 3-[2-Methyl-1-propenyl]-2,2-dimethylcyclopropanecarboxylic acid ethyl ester
  • 3-Isobutenyl-2,2-dimethyl-1-cyclopropanecarboxylic acid ethyl ester
  • Ethyl chrysanthemate,95%,mixture of cis and trans
  • 2,2-Dimethyl-3-(2-methylpropenyl)-cyclo
  • Ethyl 2,2-Dimethyl-3-(2-methyl-1-propenyl)cyclopropane-1-carboxylate
  • Ethyl chrysanthemumate (cis/trans mixture)
  • Ethyl chrysanthemuma
  • Ethyl chrysanthemate, mixture of cis and trans, 95%
  • Ethyl chrysantheMate, Mixture of cis and trans, 95% 500GR
  • Chrysanthemylmonocarboxylic Acid Ethyl Ester Ethyl Chrysanthemate Ethyl Chrysanthemumate 2,2-Dimethyl-3-(2-methyl-1-propenyl)cyclopropane-1-carboxylic Acid Ethyl Ester
  • Ethyl ChrsantheMuMate
  • ethyl 2,2-diMethyl-3-(2-Methylprop-1-en-1-yl)cyclopropanecarboxylate
  • Cyclopropanecarboxylicacid, 2,2-diMethyl-3-(2-Methyl-1-propen-1-yl)-, ethyl ester
  • Ethyl chrysant
  • 2,2-dimethyl-3-(2-methylprop-1-enyl)-1-cyclopropanecarboxylic acid ethyl ester
  • 2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylic acid ethyl ester
  • Chrysanthemummonocarboxylic acid, ethyl ester (6CI)
  • Cyclopropaneca
  • L.C. Acid (2,2-Dimethyl-3-Trifloro Propenyl Cyclopropane Carbolic Acid)
  • Ethyl2,2-Dimethyl-3-(2-methyl-1-propenyl)cyclopropane-1-carboxylate&gt
  • Tetramethrin Related Compound 1
  • PNP-α-D-Gal
  • Ethyl 2,2-Dimethyl-3-(2-methyl-1-propenyl)cyclopropane-1-carboxylate, ≥ 95.0%
  • Ethyl chrysanthemate, 10 mM in DMSO
  • 97-41-6
  • C12H20O2C12H20O2C12H20O2C12H20O2C12H20O2