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Methadone hydrochloride

Product Name
Methadone hydrochloride
CAS No.
1095-90-5
Chemical Name
Methadone hydrochloride
Synonyms
adolan;Methadone ELISA;althosehydrochloride;Methadone hydrochloride;METHADONEHYDROCHLORIDE,USP;rac Methadone Hydrochloride;FJQXCDYVZAHXNS-UHFFFAOYSA-N;Methadone Hydrochloride {D.D.};Methadone Hydrochloride (CII), USP;(±)-Methadone (hydrochloride) (CRM)
CBNumber
CB8497437
Molecular Formula
CH3ClO
Formula Weight
66.49
MOL File
1095-90-5.mol
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Methadone hydrochloride Property

Melting point:
232-2340C
Density 
1.0103 (rough estimate)
refractive index 
1.5790 (estimate)
Flash point:
11 °C
storage temp. 
2-8°C
solubility 
Soluble in water, freely soluble in ethanol (96 per cent)
form 
powder
color 
white to off-white
Water Solubility 
120 mg/mL
Stability:
Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference
1095-90-5(CAS DataBase Reference)
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Safety

Hazard Codes 
T,F
Risk Statements 
25-39/23/24/25-23/24/25-11
Safety Statements 
45-36/37-16
RIDADR 
UN 2811
WGK Germany 
3
RTECS 
MJ6300000
HS Code 
2922310000
Toxicity
LD50 orally in rats: 95 mg/kg (Finnegan)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H300Fatal if swallowed

H336May cause drowsiness or dizziness

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
1398009
Product name
Methadone hydrochloride
Purity
United States Pharmacopeia (USP) Reference Standard
Packaging
200mg
Price
$581
Updated
2024/03/01
Cayman Chemical
Product number
ISO60145
Product name
(±)-Methadone (hydrochloride) (CRM)
Packaging
1mg
Price
$20
Updated
2023/06/20
Cayman Chemical
Product number
ISO00145
Product name
(±)-Methadone (hydrochloride)
Packaging
10mg
Price
$95
Updated
2023/06/20
Sigma-Aldrich
Product number
M0267
Product name
(±)-Methadone hydrochloride
Purity
powder, ≥98%
Packaging
50mg
Price
$101
Updated
2023/06/20
Sigma-Aldrich
Product number
M0267
Product name
(±)-Methadone hydrochloride
Purity
powder, ≥98%
Packaging
1g
Price
$120
Updated
2023/06/20
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Methadone hydrochloride Chemical Properties,Usage,Production

Description

(±)-Methadone (hydrochloride) (Item No. ISO00145) is an analytical reference material categorized as an opioid. (±)-Methadone has analgesic activity. Formulations containing (±)-methadone have been used in the treatment of opioid addiction. (±)-Methadone is regulated as a Schedule II compound in the United States. This product is intended for research and forensic applications.

Chemical Properties

White Solid

Originator

Dolophine ,Lilly,US,1947

Uses

Controlled substance (opiate). Methadone hydrochloride is used in treatment of opioid dependence.

Definition

A synthetic narcotic.

Manufacturing Process

Diphenylacetonitrile is condensed with 2-chloro-1-dimethylaminopropane to give 4-(dimethylamino)-2,2-diphenyl valeronitrile. It is then reacted with ethyl magnesium bromide and then hydrolyzed using HCl to give methadone hydrochloride.

brand name

Dolophine Hydrochloride (Roxane); Dolophine Hydrochloride (Xanodyne); Methadose (Mallinckrodt); Westadone (Sandoz).

Therapeutic Function

Narcotic analgesic

Hazard

Toxic. Addictive narcotic. Use restricted.

Clinical Use


Treatment of opioid drug addiction
Analgesic for moderate to severe pain

Drug interactions

Metabolised in the liver to the Potentially hazardous interactions with other drugs Analgesics: possible opioid withdrawal with buprenorphine and pentazocine. Antibacterials: metabolism increased by rifampicin; increased risk of ventricular arrhythmias with delamanid and telithromycin. Antidepressants: concentration possibly increased by fluoxetine, fluvoxamine, paroxetine and sertraline; possible CNS excitation or depression with MAOIs and moclobemide - avoid; possibly increased sedative effects with tricyclics; concentration possibly reduced by St John's wort. Antiepileptics: concentration reduced by carbamazepine, phenobarbital and phenytoin. Antifungals: concentration increased by fluconazole, ketoconazole, voriconazole and possibly itraconazole - may need to reduce methadone dose with voriconazole, avoid with ketoconazole. Antihistamines: increased sedative effects with sedating antihistamines.
Antimalarials: increased risk of ventricular arrhythmias with piperaquine with artenimol - avoid.
Antipsychotics: enhanced hypotensive and sedative effects; increased risk of ventricular arrhythmias with antipsychotics that prolong the QT interval - avoid with amisulpride.
Antivirals: methadone possibly increases
concentration of zidovudine; concentration reduced by efavirenz, fosamprenavir and ritonavir; concentration possibly reduced by abacavir, nevirapine and rilpivirine; concentration possibly affected by boceprevir; concentration of didanosine possibly reduced; increased risk of ventricular arrhythmias with saquinavir and telaprevir - avoid with saquinavir and use with caution with telaprevir.
Atomoxetine: increased risk of ventricular arrhythmias.
Cytotoxics: possible increased risk of ventricular arrhythmias with bosutinib, ceritinib, panobinostat and vandetanib.
Dopaminergics: avoid with selegiline.
Nalmefene: avoid concomitant use.
Sodium oxybate: enhanced effect of sodium oxybate - avoid

Metabolism

Metabolised in the liver to the major metabolite 2-ethylidine-1,5-dimethyl-3,3-diphenylpyrrolidine and the minor metabolite 2-ethyl-3,3-diphenyl-5- methylpyrrolidine, both of them inactive. Two other metabolites have also been identified. These metabolites are excreted in the faeces and urine with unchanged methadone

Purification Methods

The salt crystallises from EtOH, or EtOH/Et2O.

Methadone hydrochloride Preparation Products And Raw materials

Raw materials

Preparation Products

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Methadone hydrochloride Suppliers

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