BOC-SER(TOS)-OCH3
- Product Name
- BOC-SER(TOS)-OCH3
- CAS No.
- 56926-94-4
- Chemical Name
- BOC-SER(TOS)-OCH3
- Synonyms
- BOC-SER(TOS)-OME;BOC-SER(TOS)-OCH3;BOC-L-SER(OTS)-OME;Boc-L-Ser(Tos)-OCH3;REF DUPL: Boc-Ser(Tos)-OMe;N-Boc-O-tosylserine methyl ester;(Tert-Butoxy)Carbonyl Ser(Tos)-OMe;N-Boc-O-tosyl-L-serine Methyl Ester;methyl N-(tert-butoxycarbonyl)-O-tosyl-L-serinate;N-Boc-3-(p-toluenesulfonyloxy)-L-serine Methyl ester, 98%
- CBNumber
- CB8767228
- Molecular Formula
- C16H23NO7S
- Formula Weight
- 373.42
- MOL File
- 56926-94-4.mol
BOC-SER(TOS)-OCH3 Property
- Melting point:
- 74-75℃
- Boiling point:
- 520.0±50.0 °C(Predicted)
- Density
- 1.236
- storage temp.
- 2-8°C
- solubility
- Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
- form
- Powder
- pka
- 10.28±0.46(Predicted)
- color
- White to off-white
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
N-Bromosuccinimide Price
- Product number
- J93724
- Product name
- Boc-Ser(Tos)-OMe
- Packaging
- 1g
- Price
- $14
- Updated
- 2021/12/16
- Product number
- AS33268
- Product name
- Boc-Ser(Tos)-OMe
- Purity
- 97+%
- Packaging
- 1g
- Price
- $23
- Updated
- 2021/12/16
- Product number
- 075711
- Product name
- Boc-Ser(Tos)-OMe
- Purity
- 95+%
- Packaging
- 1g
- Price
- $59
- Updated
- 2021/12/16
- Product number
- CS-M3183
- Product name
- L-Serine,N-[(1,1-dimethylethoxy)carbonyl]-O-[(4-methylphenyl)sulfonyl]-,methylester
- Packaging
- 10g
- Price
- $59
- Updated
- 2021/12/16
- Product number
- FB72160
- Product name
- Boc-Ser(Tos)-OMe
- Packaging
- 5G
- Price
- $63
- Updated
- 2021/12/16
BOC-SER(TOS)-OCH3 Chemical Properties,Usage,Production
Uses
Boc-Ser(Tos)-OMe is a serine derivative[1].
Synthesis
2766-43-0
98-59-9
56926-94-4
To a pyridine (10 mL) solution of Boc-L-serine methyl ester (0.67 g, 3.1 mmol) cooled in an ice bath was added p-toluenesulfonyl chloride (3.0 g, 15.7 mmol). The reaction mixture was stirred in an ice bath under nitrogen protection for 8 hours. Subsequently, ether (10 mL) was added to the reaction system and the mixture was transferred to room temperature to continue stirring for 14 hours. Upon completion of the reaction, the reaction solution was washed sequentially with deionized water, 10% potassium bisulfate solution, saturated sodium bicarbonate solution and brine. The organic layer was separated, dried with anhydrous magnesium sulfate and concentrated under reduced pressure to remove the solvent. The colorless oil obtained was purified by silica gel column chromatography (eluent ratio hexane:ethyl acetate=2:1) to afford (S)-methyl 2-((tert-butoxycarbonyl)amino)-3-(p-toluyloxy)propionate (1.05 g, 91% yield) as a white solid. The spectral data of the product were in agreement with literature reports and the purity was confirmed by 1H NMR.
References
[1] Luckose F, et al. Effects of amino acid derivatives on physical, mental, and physiological activities. Crit Rev Food Sci Nutr. 2015;55(13):1793-1144. DOI:10.1080/10408398.2012.708368
BOC-SER(TOS)-OCH3 Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from BOC-SER(TOS)-OCH3 manufacturers
- Product
- BOC-SER(TOS)-OCH3 56926-94-4
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- ≥98%
- Supply Ability
- g/kg/Ton
- Release date
- 2019-12-25