ChemicalBook > CAS DataBase List > METHYL 2-BROMO-5-CHLOROBENZOATE

METHYL 2-BROMO-5-CHLOROBENZOATE

Product Name: METHYL 2-BROMO-5-CHLOROBENZOATE
CAS No.: 27007-53-0
Chemical Name: METHYL 2-BROMO-5-CHLOROBENZOATE
Synonyms: Methylz-Bromo-5-Chlorobenzoate;METHYL 2-BROMO-5-CHLOROBENZOATE;Methyl2-Bromo-5-chlorobenzoate>Methyl 2-bromo-5-chlorobenzoate 98%;2-bomo-5-chlorobenzoic acid methyl ester;2-Bromine-5-Chloride Benzioc Acids Methyl;2-BROMO-5-CHLOROBENZOIC ACID METHYL ESTER;Benzoic acid, 2-bromo-5-chloro-, methyl ester
CBNumber: CB8776057
Molecular Formula: C8H6BrClO2
Formula Weight: 249.49
MOL File: 27007-53-0.mol

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METHYL 2-BROMO-5-CHLOROBENZOATE Property

Melting point:: 37-40°C
Boiling point:: 278.4±20.0 °C(Predicted)
Density: 1.604±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
form: powder to lump
color: White to Orange to Green
Water Solubility: Slightly soluble in water.
InChI: InChI=1S/C8H6BrClO2/c1-12-8(11)6-4-5(10)2-3-7(6)9/h2-4H,1H3
InChIKey: BIECSXCXIXHDBC-UHFFFAOYSA-N
SMILES: C(OC)(=O)C1=CC(Cl)=CC=C1Br
CAS DataBase Reference: 27007-53-0(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 20/22-36/37/38
Safety Statements: 36/37/39-45-37-26
HS Code: 29163990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical

Product number: M2033
Product name: Methyl 2-Bromo-5-chlorobenzoate
Purity: >98.0%(GC)
Packaging: 5g
Price: $27
Updated: 2025/07/31

TCI Chemical

Product number: M2033
Product name: Methyl 2-Bromo-5-chlorobenzoate
Purity: >98.0%(GC)
Packaging: 25g
Price: $78
Updated: 2025/07/31

TRC

Product number: M296123
Product name: Methyl 2-Bromo-5-chlorobenzoate
Packaging: 2.5g
Price: $65
Updated: 2021/12/16

TRC

Product number: M296123
Product name: Methyl 2-Bromo-5-chlorobenzoate
Packaging: 1g
Price: $55
Updated: 2021/12/16

AK Scientific

Product number: J56281
Product name: Methyl 2-Bromo-5-chlorobenzoate
Packaging: 25g
Price: $59
Updated: 2021/12/16

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METHYL 2-BROMO-5-CHLOROBENZOATE Chemical Properties,Usage,Production

Chemical Properties

Colorless liquid

Uses

Methyl 2-bromo-5-chlorobenzoate is used as pharmaceutical intermediate.

Synthesis

21739-93-5

27007-53-0

Step 1. To a stirred solution of 2-bromo-5-chlorobenzoic acid (11 g, 46.7 mmol, HPLC retention time = 2.99 min) in methanol (250 mL) at 0 °C was passed dry HCl gas. The reaction mixture was gradually warmed to room temperature and stirred overnight. Upon completion of the reaction, the mixture was concentrated under reduced pressure to give an orange colored oil. The oily substance was purified by fast column chromatography using hexane as eluent to afford methyl 2-bromo-5-chlorobenzoate as a colorless oil (10.7 g, 92% yield). Thin-layer chromatography (TLC) Rf = 0.6 (5% ethyl acetate-hexane); high-performance liquid chromatography (HPLC) retention time = 3.48 min (Method A); 1H NMR (CDCl3, 400 MHz) δ 7.78 (d, 1H, J = 2.6 Hz), 7.59 (d, 1H, J = 12.8 Hz), 7.30 (dd, 1H, J = 8.6, 2.5Hz), 3.94 (s, 3H).

References

[1] Patent: US2003/13700, 2003, A1
[2] Patent: US6528503, 2003, B2
[3] Patent: US2002/119992, 2002, A1

METHYL 2-BROMO-5-CHLOROBENZOATE Preparation Products And Raw materials

Raw materials

Preparation Products

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METHYL 2-BROMO-5-CHLOROBENZOATE Suppliers

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View Lastest Price from METHYL 2-BROMO-5-CHLOROBENZOATE manufacturers

Hebei Chuanghai Biotechnology Co., Ltd

Product: METHYL 2-BROMO-5-CHLOROBENZOATE 27007-53-0
Price: US $30.00-10.00/KG
Min. Order: 50KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2024-10-24

Hebei Chuanghai Biotechnology Co., Ltd

Product: METHYL 2-BROMO-5-CHLOROBENZOATE 27007-53-0
Price: US $10.00-8.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2025-03-14

Hebei Yanxi Chemical Co., Ltd.

Product: METHYL 2-BROMO-5-CHLOROBENZOATE 27007-53-0
Price: US $0.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 20 tons
Release date: 2023-11-29

27007-53-0, METHYL 2-BROMO-5-CHLOROBENZOATERelated Search:

Methyl 2-chloro-4-fluorobenzoate Methyl formate METHYL 3-BROMO-5-CHLOROBENZOATE METHYL-4-BROMO-3-CHLOROBENZOATE methyl 3-bromo-4-chlorobenzoate METHYL 5-BROMO-2-CHLOROBENZOATE 2-fluoro-3-methyl-2-Butenoic acid ethyl ester 2-Bromo-5-chlorobenzoic acid 4-Bromochlorobenzene 2-BROMO-5-CHLOROBENZYL ALCOHOL 1-Bromo-4-chloro-2-methylbenzene 2-BROMO-5-CHLOROBENZOIC ACID ETHYL ESTER METHYL 2-BROMO-5-CHLOROBENZOATE 2-Bromo-5-chlorobenzaldehyde 2-Bromobenzoic acid

2-bomo-5-chlorobenzoic acid methyl ester

2-BROMO-5-CHLOROBENZOIC ACID METHYL ESTER

METHYL 2-BROMO-5-CHLOROBENZOATE

2-Bromine-5-Chloride Benzioc Acids Methyl

Methylz-Bromo-5-Chlorobenzoate

Methyl 2-bromo-5-chlorobenzoate 98%

Methyl2-Bromo-5-chlorobenzoate&gt

Benzoic acid, 2-bromo-5-chloro-, methyl ester

27007-53-0

C8H6O2BrCl

Bromine Compounds

Chlorine Compounds

Aromatic Esters

Acids & Esters