ChemicalBook > CAS DataBase List > 5-Bromopyrimidine

5-Bromopyrimidine

Product Name
5-Bromopyrimidine
CAS No.
4595-59-9
Chemical Name
5-Bromopyrimidine
Synonyms
5-bromo-pyrimidin;5-pyriMidine;5-BROMOPYRIMIDINE;5-Bromo-1,3-diazine;PYRIMIDINE, 5-BROMO-;PYRIMIDINE, 2-BROMO-;5-Bromopyrimidine,98%;5-Bromopyrimidine >5-BROMOPYRIMIDINE 0.98;5 - broMine pyriMidine
CBNumber
CB8853640
Molecular Formula
C4H3BrN2
Formula Weight
158.98
MOL File
4595-59-9.mol
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5-Bromopyrimidine Property

Melting point:
67-73 °C (lit.)
Boiling point:
168°C(lit.)
Density 
1.6448 (rough estimate)
refractive index 
1.5260 (estimate)
storage temp. 
Sealed in dry,Room Temperature
solubility 
Soluble in chloroform.
form 
Crystalline Powder or Chunks
pka
1.40±0.10(Predicted)
color 
Yellow to beige-brown
BRN 
107326
CAS DataBase Reference
4595-59-9(CAS DataBase Reference)
NIST Chemistry Reference
Pyrimidine, 5-bromo-(4595-59-9)
EPA Substance Registry System
Pyrimidine, 5-bromo- (4595-59-9)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38-36/38
Safety Statements 
26-36-37/39
WGK Germany 
3
Hazard Note 
Irritant
TSCA 
T
HazardClass 
IRRITANT, KEEP COLD
HS Code 
29335990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
219142
Product name
5-Bromopyrimidine
Purity
97%
Packaging
5g
Price
$49.2
Updated
2024/03/01
Sigma-Aldrich
Product number
219142
Product name
5-Bromopyrimidine
Purity
97%
Packaging
25g
Price
$85.3
Updated
2024/03/01
TCI Chemical
Product number
B2229
Product name
5-Bromopyrimidine
Purity
>98.0%(GC)
Packaging
5g
Price
$62
Updated
2024/03/01
TCI Chemical
Product number
B2229
Product name
5-Bromopyrimidine
Purity
>98.0%(GC)
Packaging
25g
Price
$247
Updated
2024/03/01
Alfa Aesar
Product number
L14172
Product name
5-Bromopyrimidine, 98%
Packaging
5g
Price
$22.65
Updated
2024/03/01
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5-Bromopyrimidine Chemical Properties,Usage,Production

Chemical Properties

yellow solid crystalline, insoluble in water, soluble in organic solvents such as benzene and toluene.

Uses

5-Bromopyrimidine was used in the synthesis of N-heteroaryl substituted 9-arylcarbazolyl derivatives via palladium-catalyzed aerobic and ligand-free Suzuki reaction, (5-(phenylethynyl)pyrimidine) via microwave assisted organic synthesis (MAOS) Sonogashira protocol.

Uses

5-Bromopyrimidine was used in the synthesis of:
N-heteroaryl substituted 9-arylcarbazolyl derivatives via palladium-catalyzed aerobic and ligand-free Suzuki reaction
(5-(phenylethynyl)pyrimidine) via microwave assisted organic synthesis (MAOS) Sonogashira protocol
Intermediate for the synthesis of plant growth regulator flurprimidol

Application

5-Bromopyrimidine is a compound useful in organic synthesis.

Preparation

5-Bromopyrimidine is prepared by reacting dibromodifuranone with formamide in the presence of B2O2 catalyst at 180-185°C to obtain the product.

General Description

Rapid nucleophilic displacement reactions of 5-bromopyrimidine with nucleophiles under microwave irradiation has been studied. 5-Bromopyrimidine undergoes direct metallation with lithuium diisopropylamide to yield 4-lithio-5-bromopyrimidine.

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5-Bromopyrimidine Suppliers

Hunan Caiya Biological Technology Co., Ltd
Tel
15580017485
Email
2036676503@qq.com
Country
China
ProdList
91
Advantage
58
Zhende Chemical Technology (Shanghai) Co., Ltd.
Tel
15601952568
Fax
3004479441
Email
sales4@myuchem.com
Country
China
ProdList
3069
Advantage
58
Suzhou Xinrui Biotechnology Co., Ltd.
Tel
15062307751
Email
xinruibiotech01@163.com
Country
China
ProdList
2741
Advantage
58
Gretel Chemical (Changzhou) Co., Ltd.
Tel
13606112397
Email
tang13606112397@163.com
Country
China
ProdList
216
Advantage
58
Zhengzhou convergence chemical co., LTD
Tel
0371-0371-55153829 18003835034
Fax
18003835034(微信)
Email
2853979819@qq.com
Country
China
ProdList
9732
Advantage
58
Dream Chemical (Tianjin) Co., Ltd
Tel
16600677255 18522952724
Email
public@dreamchem.cn
Country
China
ProdList
890
Advantage
58
Fuxin Kaituo Fine Chemical Technology Co., Ltd
Tel
15714082442
Email
3757845877@qq.com
Country
China
ProdList
346
Advantage
58
Shandong Yiren Pharmaceutical Co. LTD
Tel
0531-87960445 13046015151
Email
21058366@QQ.COM
Country
China
ProdList
55
Advantage
58
Suzhou Vosun Biotech Co.,Ltd
Tel
0512-66569378-8002 66569378
Fax
0512-82177265
Email
info@vosunchemical.com
Country
China
ProdList
721
Advantage
58
SiChuang NanBu Honesty Technology Co., Ltd.
Tel
0838-5675166 15883665058
Fax
0838-5675535
Email
nbcxkj@126.com
Country
China
ProdList
668
Advantage
55
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View Lastest Price from 5-Bromopyrimidine manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd
Product
5-Bromopyrimidine 4595-59-9
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20 ton
Release date
2024-12-20
WUHAN FORTUNA CHEMICAL CO., LTD
Product
5-Bromopyrimidine 4595-59-9
Price
US $0.00/kg
Min. Order
1kg
Purity
98%min
Supply Ability
100kg
Release date
2023-01-13
Zhengzhou Alfa Chemical Co.,Ltd
Product
5-Bromopyrimidine 4595-59-9
Price
US $238.00/g
Min. Order
1g
Purity
97% min.
Supply Ability
300kg
Release date
2021-03-26

4595-59-9, 5-BromopyrimidineRelated Search:


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