ChemicalBook > CAS DataBase List > 5-Bromopyrimidine

5-Bromopyrimidine

Product Name
5-Bromopyrimidine
CAS No.
4595-59-9
Chemical Name
5-Bromopyrimidine
Synonyms
5-bromo-pyrimidin;5-pyriMidine;5-BROMOPYRIMIDINE;5-Bromo-1,3-diazine;PYRIMIDINE, 5-BROMO-;PYRIMIDINE, 2-BROMO-;5-Bromopyrimidine,98%;5-Bromopyrimidine >5-BROMOPYRIMIDINE 0.98;5 - broMine pyriMidine
CBNumber
CB8853640
Molecular Formula
C4H3BrN2
Formula Weight
158.98
MOL File
4595-59-9.mol
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5-Bromopyrimidine Property

Melting point:
67-73 °C (lit.)
Boiling point:
168°C(lit.)
Density 
1.6448 (rough estimate)
refractive index 
1.5260 (estimate)
storage temp. 
Sealed in dry,Room Temperature
solubility 
Soluble in chloroform.
form 
Crystalline Powder or Chunks
pka
1.40±0.10(Predicted)
color 
Yellow to beige-brown
BRN 
107326
CAS DataBase Reference
4595-59-9(CAS DataBase Reference)
NIST Chemistry Reference
Pyrimidine, 5-bromo-(4595-59-9)
EPA Substance Registry System
Pyrimidine, 5-bromo- (4595-59-9)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38-36/38
Safety Statements 
26-36-37/39
WGK Germany 
3
Hazard Note 
Irritant
TSCA 
T
HazardClass 
IRRITANT, KEEP COLD
HS Code 
29335990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
219142
Product name
5-Bromopyrimidine
Purity
97%
Packaging
5g
Price
$49.2
Updated
2024/03/01
Sigma-Aldrich
Product number
219142
Product name
5-Bromopyrimidine
Purity
97%
Packaging
25g
Price
$85.3
Updated
2024/03/01
TCI Chemical
Product number
B2229
Product name
5-Bromopyrimidine
Purity
>98.0%(GC)
Packaging
5g
Price
$62
Updated
2024/03/01
TCI Chemical
Product number
B2229
Product name
5-Bromopyrimidine
Purity
>98.0%(GC)
Packaging
25g
Price
$247
Updated
2024/03/01
Alfa Aesar
Product number
L14172
Product name
5-Bromopyrimidine, 98%
Packaging
5g
Price
$22.65
Updated
2024/03/01
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5-Bromopyrimidine Chemical Properties,Usage,Production

Chemical Properties

yellow solid crystalline, insoluble in water, soluble in organic solvents such as benzene and toluene.

Uses

5-Bromopyrimidine was used in the synthesis of N-heteroaryl substituted 9-arylcarbazolyl derivatives via palladium-catalyzed aerobic and ligand-free Suzuki reaction, (5-(phenylethynyl)pyrimidine) via microwave assisted organic synthesis (MAOS) Sonogashira protocol.

Uses

5-Bromopyrimidine was used in the synthesis of:
N-heteroaryl substituted 9-arylcarbazolyl derivatives via palladium-catalyzed aerobic and ligand-free Suzuki reaction
(5-(phenylethynyl)pyrimidine) via microwave assisted organic synthesis (MAOS) Sonogashira protocol
Intermediate for the synthesis of plant growth regulator flurprimidol

Application

5-Bromopyrimidine is a compound useful in organic synthesis.

Preparation

5-Bromopyrimidine is prepared by reacting dibromodifuranone with formamide in the presence of B2O2 catalyst at 180-185°C to obtain the product.

General Description

Rapid nucleophilic displacement reactions of 5-bromopyrimidine with nucleophiles under microwave irradiation has been studied. 5-Bromopyrimidine undergoes direct metallation with lithuium diisopropylamide to yield 4-lithio-5-bromopyrimidine.

5-Bromopyrimidine Preparation Products And Raw materials

Raw materials

2,3-Dihydrofuran 4-Hydroxy-2,5-dimethyl-3(2H)furanone

Preparation Products

5-HYDROXYPYRIMIDINE 5-Pyrimidinecarboxylic acid 5-Pyrimidinylboronic acid Pyrimidine-5-carboxaldehyde 5-Hydroxypyrimidine
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5-Bromopyrimidine Suppliers

Americas 1 Belgium 3 Canada 3 China 398 Europe 5 Germany 6 India 23 Japan 6 Slovakia 1 South Korea 1 Switzerland 5 The Netherlands 2 Ukraine 1 United Kingdom 19 United States 69 Global 543
Pure Chemistry Scientific Inc.
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View Lastest Price from 5-Bromopyrimidine manufacturers

Zhengzhou Alfa Chemical Co.,Ltd
Product
5-Bromopyrimidine 4595-59-9
Price
US $238.00/g
Min. Order
1g
Purity
97% min.
Supply Ability
300kg
Release date
2021-03-26
Hebei Zhuanglai Chemical Trading Co Ltd
Product
5-Bromopyrimidine 4595-59-9
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20 ton
Release date
2024-12-20
Hebei Mujin Biotechnology Co.,Ltd
Product
5-Bromopyrimidine 4595-59-9
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-10-13

4595-59-9, 5-BromopyrimidineRelated Search:

5-Bromo-2,4-dichloropyrimidine Fluorocytosine Alloxan Pyrimethamine Cytosine Silver sulfadiazine Sulfadiazine Pyrimidine Uracil 5-Bromophthalide 5-Bromonicotinic acid 5-Bromoindole 2-AMINO-5-BROMOPYRIMIDINE,2-Amino-5-bromopyrimidine ,98% 2-AMINO-5-BROMO-4-HYDROXY-6-METHYLPYRIMIDINE 5-Bromo-4,6-dichloropyrimidine 2-Amino-5-bromo-4,6-dimethylpyrimidine 5-Bromo-4,6-dihydroxypyrimidine 5-BROMO-2,4-DIMETHOXYPYRIMIDINE

  • 5-bromo-pyrimidin
  • PYRIMIDINE, 2-BROMO-
  • PYRIMIDINE, 5-BROMO-
  • 5-BROMOPYRIMIDINE
  • 5-Bromopyrimidine,98%
  • Pyrimidine,5-bromo-(6CI,7CI,8CI,9CI)
  • 5-BROMOISATINIC ANHYDRIDE
  • 5-BROMOPYRIMIDINE, 99% MIN
  • 5-BROMOPYRIMIDINE 0.98
  • 5-BroMopyriMidine, 98% 25GR
  • 5-pyriMidine
  • 5-Bromo-1,3-diazine
  • 5-BroMopyriMidine, 97+%
  • 5 - broMine pyriMidine
  • 5-Bromopyrimidine Vetec(TM) reagent grade, 97%
  • 5-Bromopyrimidine &gt
  • 27540 5-Bromopyrimidine
  • 5-BROMOPYRIMIDINE 4595-59-9
  • 5-Bromopyrimidine ISO 9001：2015 REACH
  • 4595-59-9
  • 4595-59-5
  • C4H3BrN2
  • Building Blocks
  • Halogenated Heterocycles
  • Heterocyclic Building Blocks
  • Pyrimidines
  • Halides
  • Pyrazines, Pyrimidines & Pyridazines
  • Aromatics Compounds
  • Aromatics
  • Heterocycles
  • Pyrazines, Pyrimidines & Pyridazines
  • Building Blocks
  • Halogenated Heterocycles
  • Heterocyclic Building Blocks
  • Pyrimidines
  • PyrimidinesHeterocyclic Building Blocks
  • Pyrimidine
  • Heterocycle-Pyrimidine series
  • HALIDE
  • Pyridines, Pyrimidines, Purines and Pteredines
  • bc0001
  • 4595-59-9