Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)

Reaction

Product Name: Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)
CAS No.: 887919-35-9
Chemical Name: Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)
Synonyms: Pd132;Pd(amphos)Cl2;Pd(Amphos)2Cl2;PdCl2(Amphos)2;(A-taPhos)2PdCl2;PdAMPHOS;BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM(II);pall;Bis[4-[bis(1,1-diMethylethyl)phosphino-κ…;Dichlorobis[di-tert-butyl(p-dimethylaminophenyl)phosphino]palladium(II)
CBNumber: CB8972714
Molecular Formula: C32H58Cl2N2P2Pd
Formula Weight: 710.1
MOL File: 887919-35-9.mol

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Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) Property

storage temp.: Keep in dark place,Sealed in dry,Room Temperature
form: Powder
color: yellow
Water Solubility: Insoluble in water.
InChI: InChI=1S/2C16H28NP.2ClH.Pd/c2*1-15(2,3)18(16(4,5)6)14-11-9-13(10-12-14)17(7)8;;;/h2*9-12H,1-8H3;2*1H;
InChIKey: AWOFSUFKCXRJMV-UHFFFAOYSA-N
SMILES: P(C1C=CC(N(C)C)=CC=1)(C(C)(C)C)(C(C)(C)C)[Pd+2]([Cl-])([Cl-])P(C1C=CC(N(C)C)=CC=1)(C(C)(C)C)C(C)(C)C

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26
WGK Germany: 3
TSCA: No
HS Code: 28439000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 678740
Product name: Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)
Purity: 95%
Packaging: 1g
Price: $163
Updated: 2024/03/01

Sigma-Aldrich

Product number: 678740
Product name: Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)
Purity: 95%
Packaging: 5g
Price: $776
Updated: 2024/03/01

Alfa Aesar

Product number: 045511
Product name: Dichlorobis[di-tert-butyl(4-dimethylaminophenyl)phosphine]palladium(II), Pd 15%
Packaging: 1g
Price: $236.65
Updated: 2024/03/01

Strem Chemicals

Product number: 46-0825
Product name: Dichlorobis{[4-(N,N-dimethylamino)phenyl]di-t-butylphosphino}palladium(II), min. 98% PdAmphos
Packaging: 250mg
Price: $55
Updated: 2024/03/01

Strem Chemicals

Product number: 46-0825
Product name: Dichlorobis{[4-(N,N-dimethylamino)phenyl]di-t-butylphosphino}palladium(II), min. 98% PdAmphos
Packaging: 1g
Price: $162
Updated: 2024/03/01

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Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) Chemical Properties,Usage,Production

Reaction

Useful catalyst for the Suzuki Cross-Coupling of dioxolanylethyltrifluorborate and aryl/heteroaryl chlorides.
Useful catalyst for the Suzuki Cross-Coupling of benzyloxyethyltrifluoroborate.

Chemical Properties

Yellow powder

Uses

Dichlorobis[di-tert-butyl(4-dimethylaminophenyl)phosphine]palladium(II) is a highly active, air-stable catalyst for Suzuki-Miyaura cross-coupling with aryl halides including 5- and 6-membered heteroaryl chlorides.

Uses

Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium is useful catalyst for the Suzuki Cross-Coupling of dioxolanylethyltrifluorborate and aryl/heteroaryl chlorides.

Synthesis

To a 500 mL reaction was added 10 g (1,5-cyclooctadiene) palladium dichloride, the reaction flask was replaced with a nitrogen atmosphere,19.6 g of di-tert-butyl-4-dimethylaminophenylphosphine and 200 mL of anhydrous tetrahydrofuran were added. The mixture was stirred at room temperature for 16 hours; There was a solid precipitation; filtration and drying gave a pale yellow powder product bis (di-tert-butyl-4-dimethylaminophenylphosphine) palladium chloride. The yield was 97 percent.

Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) Preparation Products And Raw materials

Raw materials

Preparation Products

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Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) Suppliers

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View Lastest Price from Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) manufacturers

Shanghai Daken Advanced Materials Co.,Ltd

Product: Dichlorobis[di-tert-butyl(4-diMethylaMinophenyl)phosphino]palladium(II) 887919-35-9
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 100KG /month
Release date: 2021-11-12

Henan Fengda Chemical Co., Ltd

Product: Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium (II) 887919-35-9
Price: US $8.00-0.80/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2024-01-22

Zhuozhou Wenxi import and Export Co., Ltd

Product: BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM(II) 887919-35-9
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-06-27

887919-35-9, Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)Related Search:

DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(II) (R)-(-)-1-[(S)-2-(DI(3,5-BIS-TRIFLUOROMETHYLPHENYL)PHOSPHINO)FERROCENYL]ETHYLDI(3,5-DIMETHYLPHENYL)PHOSPHINE (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE (S,S)-[2-(4'-i-Propyloxazolin-2'-yl)ferrocenyldiphenylphosphine, min. 97% (R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE DICHLOROBIS(TRI-O-TOLYLPHOSPHINE)PALLADIUM(II) DICHLORO(N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE)PALLADIUM(II) DICHLOROBIS(INDENYL)TITANIUM(IV) Ruthenium(II) chloride mesitylene dimer Bis(diphenylphosphinophenyl)ether palladium (II) dichloride BrettPhos Pd G4 XPhos Pd G2 SPhos Pd G2 Dichloro[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene]palladium(II), min. 98% DI-TERT-BUTYLPHENYLPHOSPHINE Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) dichlorobis(di-tert-butylphenylphosphine)palladium(II) Bis(di-tert-butyl)-4-dimethylaminophenylphosphine

Pd(aMphos)Cl2, 15% Pd, Product of UMicore

Bis[4-[bis(1,1-diMethylethyl)phosphino-κ…

Palladium,bis[4-[bis(1,1-dimethylethyl)phosphino-kP]-N,N-dimethylbenzenamine]dichloro-, (SP-4-1)-

palladium(2+) ion bis(4-(di-tert-butylphosphanyl)-N,N-dimethylaniline) dichloride

Bis{bis(tert-butyl)[4-(dimethylamino)phenyl]phosphine}palladium(II) chloride 95+%

Bis{bis(tert-butyl)[4-(dimethylamino)phenyl]phosphine}palladium(II) chloride

Dichlorobis{[4-(N,N-dimethylamino)phenyl]di-t-butylphosphino}palladium(II), min. 98% PdAmphos

Pd132

PdAMPHOS

Pd(amphos)Cl2 / Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)

palladium(2+) io

Bis[4-[bis(1,1-diMethylethyl)phosphino-Palladium,bis[4-[bis(1,1-dimethylethyl)phosphino-kP]-N,N-dimethylbenzenamine]dichloro-, (SP-4-1)-

pall

Dichlorobis[di-tert-butyl(4-diMethylaMinophenyl)phosphine]palladiuM(II)

Bis(4-(di-tert-Butylphosphanyl)-N,N-dimethylaniline)

Dichlorobis{[4-(N,N-dimethylamino)phenyl]di-t-butylphosphino}palladium(II), min. 98%

BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM(II)

(A-taPhos)2PdCl2

Dichlorobis(di-tert-butyl-4-dimethylaminophenylphosphine)palladium(11)

(SP-4-1)-Palladium dichloro-bis[4-[bis(1,1-dimethylethyl)phosphino-P]-N,N-dimethylbenzenamine]

PdCl2(Amphos)2

BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM(II) PdCl2(AMphos)2

Dichlorobis[di-tert-butyl(4-diMethylaMinophenyl)phosphino]palladiuM(II), Pd 15%

Bis(di-tert-butyl(4-diMethyl

Bis[(4-(N,N-DiMethylaMino)phenyl)di-tert-butyl phosphine] palladiuM(II) chloride

Dichlorobis[di-tert-butyl(4-diMethylaMinophenyl)phosphine]palladiuM(II), Pd 15%

Pd(amphos)Cl2

Bis{bis(tert-butyl)[4-(dimethylamino)phenyl]phosphine}dichloropalladium(II), Bis{4-[bis(tert-butyl)phosphanyl]-N,N-dimethylaniline}dichloropalladium(II)

Bis[di-tert-butyl(4-diMethylaMinophenyl)phosphine]dichloropalladiuM, 95%

Dichlorobis{[4-(N,N-dimethylamino)phenyl]di-t-butylphosphino}palladium(II)

Dichlorobis[di-t-butyl(p-dimethylaminophenyl)phosphino]palladium(Ⅱ)

Bis{bis(tert-butyl)[4-(dimethylamino)phenyl]phosphine}palladium(II)

adium

Bis[di-tert-butyL

Dichlorobis[di-tert-butyl(p-dimethylaminophenyl)phosphino]palladium(II)

Pd(Amphos)2Cl2

BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM ISO 9001：2015 REACH

Bis(di-tert-butyl(4-methylaminophenyl)phosphine)dichloropalladium(II)

Dichlorobis[di-tert-butyl(4-dimethylaminophenyl)phosphino]pa...

Bis{bis(tert-butyl)[4-(dimethylamino)phenyl]phosphine}palladium(II) chloride (Pd-132)

TIANFU-CHEM -BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM(II)

4-lsopropylaniline(99-88-7)

bis[4- [bis(1,1-dimethylethyl)phosphino-kP]-N,N- dimethylbenzenamine]dichloro-palladium(II)

Dichlorodi-tert-butyl - (4-dimethylaminophenyl) phosphopalladium (II)

Dichlorobis[di-tert-butyl(4-dimethylaminophenyl)phosphino]palladium(II)

(AMPHOS)2PDCL2

(SP-4-1)-Bis[4-[bis(1,1-dimethylethyl)phosphino-κP]-N,N-dimethylbenzenamine]dichloropalladium

(SP-4-1)-Bis[4-[bis(1,1-dimethylethyl)phosphino-κP]-N,N-dimethylbenzenamine]dichloropalladium (ACI)

887919-35-9

C32H56Cl2N2P2Pd

Pd