ChemicalBook > CAS DataBase List > TRIPHENYLPHOSPHINE RESIN

TRIPHENYLPHOSPHINE RESIN

Product Name
TRIPHENYLPHOSPHINE RESIN
CAS No.
39319-11-4
Chemical Name
TRIPHENYLPHOSPHINE RESIN
Synonyms
POLYMER-BOUND TRIPHENYLPHOSPHINE;POLYMER SUPPORTED TRIPHENYLPHOSPHINE;TRIPHENYLPHOSPHINE POLYMER BOUND;PL-TPP RESIN;-C6H4P(C6H5)2;PL-TPP MP-RESIN;POLYSTYRENE-PPH2;diphenylphosphinated;TRIPHENYLPHOSPHINE PS;TRIPHENYLPHOSPHINE RESIN
CBNumber
CB9181407
Molecular Formula
C18H15P
Formula Weight
262.285461
MOL File
39319-11-4.mol
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TRIPHENYLPHOSPHINE RESIN Property

storage temp. 
2-8°C
form 
Beads
color 
White to yellow
Sensitive 
Air Sensitive
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
22-43-20/21/22-36/37/38
Safety Statements 
36/37-36-26
WGK Germany 
3
F 
10-23
HS Code 
29310099
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
14664
Product name
Triphenylphosphine, polymer-bound
Purity
100-200?mesh, extent of labeling: ~3.2?mmol/g loading
Packaging
25g
Price
$304
Updated
2024/03/01
Alfa Aesar
Product number
L19478
Product name
Triphenylphosphine, polymer-supported
Purity
1.4-2.0 mmol/g on polystyrene
Packaging
1g
Price
$31.1
Updated
2023/06/20
Alfa Aesar
Product number
L19478
Product name
Triphenylphosphine, polymer-supported
Purity
1.4-2.0 mmol/g on polystyrene
Packaging
5g
Price
$96.3
Updated
2021/12/16
Strem Chemicals
Product number
15-6730
Product name
Triphenylphosphine, polymer-bound, on styrene-divinylbenzene copolymer (20% cross-linked)
Packaging
1g
Price
$48
Updated
2021/12/16
Strem Chemicals
Product number
15-6730
Product name
Triphenylphosphine, polymer-bound, on styrene-divinylbenzene copolymer (20% cross-linked)
Packaging
5g
Price
$143
Updated
2021/12/16
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TRIPHENYLPHOSPHINE RESIN Chemical Properties,Usage,Production

Chemical Properties

white to yellow beads

Uses

Polymer-bound triphenylphosphine is a solid-supported reagent that can be used as a better alternative to triphenylphosphine in the Mitsunobu reaction.
It can also be used:

  • For the esterification of alkylphosphonic acids using primary alcohols in the presence of iodine and imidazole.
  • To catalyze the conversion of 3-[3-(1,3-dioxolan-2-yl)-1-hydroxypropyl]pyridine to 3-[1-bromo-3-(1,3-dioxolan-2-yl)propyl]pyridine using carbon tetrabromide.
  • To isomerize (Z)-nitro olefins to the (E)-isomers.
  • To prepare polymer-bound ylides which are useful in Wittig reactions.
  • To convert alcohols or carboxylic acids to the corresponding chlorides.
  • In combination with carbon tetrachloride for the coupling N-alkoxycarbonyl α-amino acids and primary amines to form the corresponding amides.

Uses

Triphenylphosphine resin is used for the preparation of polymer bound ylids which are useful for Wittig reactions.

TRIPHENYLPHOSPHINE RESIN Preparation Products And Raw materials

Raw materials

Preparation Products

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TRIPHENYLPHOSPHINE RESIN Suppliers

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39319-11-4, TRIPHENYLPHOSPHINE RESINRelated Search:

METHYL ISOCYANOACETATE Tris(2,4-pentanedionato)chroMiuM(III) Tosylmethyl isocyanide TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)EUROPIUM(III) N-BUTYLISOCYANIDE DICHLORO(ETHYLENEDIAMINE)PLATINUM(II) TERT-BUTYL ISOCYANIDE TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)DYSPROSIUM(III) PHENYLSELENOL 1,1,3,3-TETRAMETHYLBUTYL ISOCYANIDE 2,4-PENTANEDIONE, SILVER DERIVATIVE COBALT(II) ACETYLACETONATE Benzyl isocyanide SALCOMINE Ferric acetylacetonate Ethyl isocyanoacetate Cupric acetylacetonate TRIPHENYLPHOSPHINE RESIN, 1% DVB; 100-200 MESH; 1-1.5 MMOL/G

  • TRIPHENYLPHOSPHINE POL. BOUND, 100-200 M ESH, ~1.6 MMOL/G
  • TRIPHENYLPHOSPHINE POL. BOUND, 200-400 M ESH, ~3 MMOL/G
  • TriphenylphosphineResin1%DvbMesh,1-1.5Mmol/G
  • Triphenylphosphine resin, Crosslinked with 1% DVB, 1.2-1.5 mmol/g, 100-200 mesh
  • Triphenylphosphine resin, 1% crosslinked with DVB
  • 4-DIPHENYLPHOSPHINO POLYSTYRENE RESIN
  • COPOLYMER OF STYRENE AND DIVINYLBENZENE, DIPHENYLPHOSPHINATED
  • DIPHENYLPHOSPHINOBENZOYL NOVAGEL(TM) AM RESIN
  • DIPHENYLPHOSPHINO-POLYSTYRENE
  • MACROPOROUS POLYMER SUPPORTED TRIPHENYLPHOSPHINE
  • PL-TPP RESIN
  • PL-TPP MP-RESIN
  • POLYMER SUPPORTED TRIPHENYLPHOSPHINE
  • POLYMER-BOUND TRIPHENYLPHOSPHINE
  • POLYSTYRENE CROSSLINKED WITH DIVINYL-BENZENE, DIPHENYLPHOSPHINATED
  • POLYSTYRENE-PPH2
  • TRIPHENYLPHOSPHINE POLYMER BOUND
  • TRIPHENYLPHOSPHINE, POLYMER-SUPPORTED
  • TRIPHENYLPHOSPHINE POLYSTYRENE
  • TRIPHENYLPHOSPHINE PS
  • TRIPHENYLPHOSPHINE PS RESIN
  • TRIPHENYLPHOSPHINE RESIN
  • TRIPHENYLPHOSPHINE NOVAGEL
  • TRIPHENYLPHOSPHINE NOVAGEL(TM)
  • 4-DIPHENYLPHOSPHINO POLYSTYRENE RESIN, CROSS-LINKED WITH 2% DVB: (1.0-2.0MMOLP/G), 200-400MESH
  • Triphenylphosphine polystyrene (100-200 mesh, 0.8-1.6 mmol
  • Triphenylphosphine polystyrene (200-400 mesh, 1.0-1.5 mmol
  • 4-Diphenylphosphino Polystyrene Resin cross-linked with 2% DVB (200-400mesh) (1.0-2.0mmol/g)
  • diphenylphosphinated
  • Copolymer of styrene and divinylbenzene, diphenylphosphinated, Diphenylphosphino-polystyrene, Polystyrene crosslinked with divinylbenzene, diphenylphosphinated
  • TRIPHENYLPHOSPHINE RESIN, 1% CROSSL.WITH DVB, 1.2-1.5 MMOL/G, 200-400 MESH
  • Triphenylphosphine resin, 1% crossl. with DVB, 1.2-1.5 mmol/g, 100-200 mesh
  • 4-Diphenylphosphino polystyrene resin, cross-linked with 2% DVB
  • Diphenyl(4-vinylphenyl)phosphine-divinylbenzene-styrene copolymer
  • Triphenylphosphine, polyMer-bound 100-200 Mesh, extent of labeling: ~3.0 MMol/g loading, 2 % cross-linked with divinylbenzene
  • Triphenylphosphine resin(1.0-1.5 meq/g, 100-200 mesh)
  • Triphenylphosphine, polymer-supported, 1.4 to 2.0mmol/g on polystyrene
  • Triphenylphosphine resin, 1% crosslinked with DVB, 1.0-1.5mmol/g
  • -C6H4P(C6H5)2
  • Triphenylphosphine, polymer supported1.4-2.0mmol/g on polystyrene 200-400 mesh2% DVB loading
  • Triphenylphosphine, polymer-bound 100-200 mesh, extent of labeling: ~1.6 mmol/g loading
  • Triphenylphosphine, polymer-bound 100-200 mesh, extent of labeling: ~3 mmol/g triphenylphosphine loading
  • 39319-11-4
  • C20H17PmC10H10nC8H8x
  • -C6H4PC6H52
  • Supported Reagents
  • Supported Synthesis
  • Specialty Synthesis
  • Ligands
  • Combinatrial Chemistry
  • Resins
  • Mitsunobu Reaction
  • Polymer-Supported Reagents
  • Phosphines (Mitsunobu Reaction)
  • Combinatorial Chemistry
  • Mitsunobu Reaction
  • Phosphines (Mitsunobu Reaction)
  • Polymer-Supported Reagents