TRIPHENYLPHOSPHINE RESIN

Product Name: TRIPHENYLPHOSPHINE RESIN
CAS No.: 39319-11-4
Chemical Name: TRIPHENYLPHOSPHINE RESIN
Synonyms: POLYMER-BOUND TRIPHENYLPHOSPHINE;POLYMER SUPPORTED TRIPHENYLPHOSPHINE;TRIPHENYLPHOSPHINE POLYMER BOUND;PL-TPP RESIN;-C6H4P(C6H5)2;PL-TPP MP-RESIN;POLYSTYRENE-PPH2;diphenylphosphinated;TRIPHENYLPHOSPHINE PS;TRIPHENYLPHOSPHINE RESIN
CBNumber: CB9181407
Molecular Formula: C18H15P
Formula Weight: 262.285461
MOL File: 39319-11-4.mol

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TRIPHENYLPHOSPHINE RESIN Property

storage temp.: 2-8°C
form: Beads
color: White to yellow
Sensitive: Air Sensitive

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Safety

Hazard Codes: Xn,Xi
Risk Statements: 22-43-20/21/22-36/37/38
Safety Statements: 36/37-36-26
WGK Germany: 3
F: 10-23
HS Code: 29310099

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 14664
Product name: Triphenylphosphine, polymer-bound
Purity: 100-200?mesh, extent of labeling: ~3.2?mmol/g loading
Packaging: 25g
Price: $304
Updated: 2024/03/01

Alfa Aesar

Product number: L19478
Product name: Triphenylphosphine, polymer-supported
Purity: 1.4-2.0 mmol/g on polystyrene
Packaging: 1g
Price: $31.1
Updated: 2023/06/20

Alfa Aesar

Product number: L19478
Product name: Triphenylphosphine, polymer-supported
Purity: 1.4-2.0 mmol/g on polystyrene
Packaging: 5g
Price: $96.3
Updated: 2021/12/16

Strem Chemicals

Product number: 15-6730
Product name: Triphenylphosphine, polymer-bound, on styrene-divinylbenzene copolymer (20% cross-linked)
Packaging: 1g
Price: $48
Updated: 2021/12/16

Strem Chemicals

Product number: 15-6730
Product name: Triphenylphosphine, polymer-bound, on styrene-divinylbenzene copolymer (20% cross-linked)
Packaging: 5g
Price: $143
Updated: 2021/12/16

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TRIPHENYLPHOSPHINE RESIN Chemical Properties,Usage,Production

Chemical Properties

white to yellow beads

Uses

Polymer-bound triphenylphosphine is a solid-supported reagent that can be used as a better alternative to triphenylphosphine in the Mitsunobu reaction.
It can also be used:

For the esterification of alkylphosphonic acids using primary alcohols in the presence of iodine and imidazole.
To catalyze the conversion of 3-[3-(1,3-dioxolan-2-yl)-1-hydroxypropyl]pyridine to 3-[1-bromo-3-(1,3-dioxolan-2-yl)propyl]pyridine using carbon tetrabromide.
To isomerize (Z)-nitro olefins to the (E)-isomers.
To prepare polymer-bound ylides which are useful in Wittig reactions.
To convert alcohols or carboxylic acids to the corresponding chlorides.
In combination with carbon tetrachloride for the coupling N-alkoxycarbonyl α-amino acids and primary amines to form the corresponding amides.

Uses

Triphenylphosphine resin is used for the preparation of polymer bound ylids which are useful for Wittig reactions.

TRIPHENYLPHOSPHINE RESIN Preparation Products And Raw materials

Raw materials

Preparation Products

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TRIPHENYLPHOSPHINE RESIN Suppliers

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39319-11-4, TRIPHENYLPHOSPHINE RESINRelated Search:

METHYL ISOCYANOACETATE Tris(2,4-pentanedionato)chroMiuM(III) Tosylmethyl isocyanide TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)EUROPIUM(III) N-BUTYLISOCYANIDE DICHLORO(ETHYLENEDIAMINE)PLATINUM(II) TERT-BUTYL ISOCYANIDE TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)DYSPROSIUM(III) PHENYLSELENOL 1,1,3,3-TETRAMETHYLBUTYL ISOCYANIDE 2,4-PENTANEDIONE, SILVER DERIVATIVE COBALT(II) ACETYLACETONATE Benzyl isocyanide SALCOMINE Ferric acetylacetonate Ethyl isocyanoacetate Cupric acetylacetonate TRIPHENYLPHOSPHINE RESIN, 1% DVB; 100-200 MESH; 1-1.5 MMOL/G

TRIPHENYLPHOSPHINE POL. BOUND, 100-200 M ESH, ~1.6 MMOL/G

TRIPHENYLPHOSPHINE POL. BOUND, 200-400 M ESH, ~3 MMOL/G

TriphenylphosphineResin1%DvbMesh,1-1.5Mmol/G

Triphenylphosphine resin, Crosslinked with 1% DVB, 1.2-1.5 mmol/g, 100-200 mesh

Triphenylphosphine resin, 1% crosslinked with DVB

4-DIPHENYLPHOSPHINO POLYSTYRENE RESIN

COPOLYMER OF STYRENE AND DIVINYLBENZENE, DIPHENYLPHOSPHINATED

DIPHENYLPHOSPHINOBENZOYL NOVAGEL(TM) AM RESIN

DIPHENYLPHOSPHINO-POLYSTYRENE

MACROPOROUS POLYMER SUPPORTED TRIPHENYLPHOSPHINE

PL-TPP RESIN

PL-TPP MP-RESIN

POLYMER SUPPORTED TRIPHENYLPHOSPHINE

POLYMER-BOUND TRIPHENYLPHOSPHINE

POLYSTYRENE CROSSLINKED WITH DIVINYL-BENZENE, DIPHENYLPHOSPHINATED

POLYSTYRENE-PPH2

TRIPHENYLPHOSPHINE POLYMER BOUND

TRIPHENYLPHOSPHINE, POLYMER-SUPPORTED

TRIPHENYLPHOSPHINE POLYSTYRENE

TRIPHENYLPHOSPHINE PS

TRIPHENYLPHOSPHINE PS RESIN

TRIPHENYLPHOSPHINE RESIN

TRIPHENYLPHOSPHINE NOVAGEL

TRIPHENYLPHOSPHINE NOVAGEL(TM)

4-DIPHENYLPHOSPHINO POLYSTYRENE RESIN, CROSS-LINKED WITH 2% DVB: (1.0-2.0MMOLP/G), 200-400MESH

Triphenylphosphine polystyrene (100-200 mesh, 0.8-1.6 mmol

Triphenylphosphine polystyrene (200-400 mesh, 1.0-1.5 mmol

4-Diphenylphosphino Polystyrene Resin cross-linked with 2% DVB (200-400mesh) (1.0-2.0mmol/g)

diphenylphosphinated

Copolymer of styrene and divinylbenzene, diphenylphosphinated, Diphenylphosphino-polystyrene, Polystyrene crosslinked with divinylbenzene, diphenylphosphinated

TRIPHENYLPHOSPHINE RESIN, 1% CROSSL.WITH DVB, 1.2-1.5 MMOL/G, 200-400 MESH

Triphenylphosphine resin, 1% crossl. with DVB, 1.2-1.5 mmol/g, 100-200 mesh

4-Diphenylphosphino polystyrene resin, cross-linked with 2% DVB

Diphenyl(4-vinylphenyl)phosphine-divinylbenzene-styrene copolymer

Triphenylphosphine, polyMer-bound 100-200 Mesh, extent of labeling: ~3.0 MMol/g loading, 2 % cross-linked with divinylbenzene

Triphenylphosphine resin(1.0-1.5 meq/g, 100-200 mesh)

Triphenylphosphine, polymer-supported, 1.4 to 2.0mmol/g on polystyrene

Triphenylphosphine resin, 1% crosslinked with DVB, 1.0-1.5mmol/g

-C6H4P(C6H5)2

Triphenylphosphine, polymer supported1.4-2.0mmol/g on polystyrene 200-400 mesh2% DVB loading

Triphenylphosphine, polymer-bound 100-200 mesh, extent of labeling: ~1.6 mmol/g loading

Triphenylphosphine, polymer-bound 100-200 mesh, extent of labeling: ~3 mmol/g triphenylphosphine loading

39319-11-4

C20H17PmC10H10nC8H8x

-C6H4PC6H52

Supported Reagents

Supported Synthesis

Specialty Synthesis

Ligands

Combinatrial Chemistry

Resins

Mitsunobu Reaction

Polymer-Supported Reagents

Phosphines (Mitsunobu Reaction)

Combinatorial Chemistry

Mitsunobu Reaction

Phosphines (Mitsunobu Reaction)

Polymer-Supported Reagents