ChemicalBook > CAS DataBase List > 10-Undecenal

10-Undecenal

Product Name
10-Undecenal
CAS No.
112-45-8
Chemical Name
10-Undecenal
Synonyms
ALDEHYDE C-11 UNDECYLENIC;10-UNDECENYL ALDEHYDE;FEMA 2363;HENDECENAL;9-UNDECENAL;10-UNDECEN-1-AL;INTRELEVEN ALDEHYDE;UNDECYLENIC ALDEHYDE;intreleven aldehyde (IFF);ALDEHYDE C11 ENIC/UNDECYLENIC ALDEHYDE
CBNumber
CB9190322
Molecular Formula
C11H20O
Formula Weight
168.28
MOL File
112-45-8.mol
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10-Undecenal Property

Melting point:
7°C
Boiling point:
98-100 °C3 mm Hg(lit.)
Density 
0.84 g/mL at 25 °C(lit.)
vapor density 
>1 (vs air)
vapor pressure 
8.7Pa at 25℃
FEMA 
3095 | 10-UNDECENAL
refractive index 
n20/D 1.4427(lit.)
Flash point:
199 °F
storage temp. 
2-8°C
solubility 
Chloroform (Sparingly), Ethyl Acetate (Slightly)
pka
0[at 20 ℃]
form 
Crystals or Crystalline Powder
color 
White
Specific Gravity
0.84
Odor
at 1.00 % in dipropylene glycol. waxy aldehydic rose mandarin citrus soapy fatty
Odor Type
aldehydic
Water Solubility 
Insoluble
JECFA Number
330
LogP
4.672 at 25℃
CAS DataBase Reference
112-45-8(CAS DataBase Reference)
NIST Chemistry Reference
10-Undecenal(112-45-8)
EPA Substance Registry System
10-Undecenal (112-45-8)
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Safety

Hazard Codes 
Xi
Risk Statements 
38-10
Safety Statements 
24/25-37/39-26
WGK Germany 
2
RTECS 
YQ2835000
HS Code 
29121900
Toxicity
rabbit,LD50,skin,> 5gm/kg (5000mg/kg),Food and Cosmetics Toxicology. Vol. 11, Pg. 479, 1973.
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H317May cause an allergic skin reaction

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P272Contaminated work clothing should not be allowed out of the workplace.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
W309508
Product name
10-Undecenal
Purity
≥95%, FG, stabilized
Packaging
100g
Price
$68.9
Updated
2023/01/07
Sigma-Aldrich
Product number
132276
Product name
Undecylenic aldehyde
Purity
95%
Packaging
25g
Price
$61.3
Updated
2023/01/07
Sigma-Aldrich
Product number
132276
Product name
Undecylenic aldehyde
Purity
95%
Packaging
100g
Price
$134
Updated
2022/05/15
TCI Chemical
Product number
U0011
Product name
10-Undecenal
Purity
>95.0%(GC)
Packaging
25mL
Price
$45
Updated
2024/03/01
TRC
Product number
U788835
Product name
10-UndecylenicAldehyde
Packaging
25g
Price
$55
Updated
2021/12/16
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10-Undecenal Chemical Properties,Usage,Production

Chemical Properties

Clear colorless liquid

Chemical Properties

10-Undecenal was identified, for example, in coriander leaf extract. It is a colorless liquid with a fatty, green, slightly metallic, heavy, floral odor. The aldehyde can be synthesized from undecylenic acid, for example, by hydrogenation of the acid chloride (Rosenmund reduction) or by reaction with formic acid in the vapor phase in the presence of titanium dioxide. In perfumery, 10-undecenal is one of the aldehydes essential for creating the “aldehydic note.”
Mixtures containing undecenals with the double bond in other positions (9-, 8-, 7-) are also marketed and used in fragrances, for example, Aldehyde C11 Iso (Givaudan), Intreleven aldehyde (IFF).

Chemical Properties

10-Undecenal has a characteristic fatty, rose odor on dilution. It has an unpleasant sweet, fatty taste. This compound tends to polymerize.

Occurrence

Reported found in coriander leaf (Coriandrum sativum L.).

Uses

10-Undecylenic Aldehyde is derived from the reduction of Undecylenic Acid (U788820) which is used for the manufacture of pharmaceuticals, cosmetics and perfumery, including antidandruff shampoos, antimicrobial powders and as a musk in perfumes and aromas.

Definition

ChEBI: 10-undecenal is an undecenal.

Preparation

By oxidation of the corresponding alcohol or reduction of the corresponding acid; by passing vapors of formic acid and undecylenic acid over TiO2 at 250°C under pressure; by passing vapors of undecylenic acid and methanol over a manganese dioxidebased catalyst; or by reduction of ethyl undecylenate with lithium hydride and sodium in tetrahydrofuran solution at very low temperature (–50°C).

Taste threshold values

Taste characteristics at 2.5 ppm: fatty, oily and aldehydic with a mandarin, citrus nuance.

Synthesis Reference(s)

The Journal of Organic Chemistry, 47, p. 4534, 1982 DOI: 10.1021/jo00144a026
Synthetic Communications, 12, p. 839, 1982 DOI: 10.1080/00397918208065961

Flammability and Explosibility

Non flammable

Safety Profile

LOW toxicity by ingestion and skin contact. A skin irritant. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALDEHYDES.

10-Undecenal Preparation Products And Raw materials

Raw materials

Preparation Products

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10-Undecenal Suppliers

Shandong Luoheng Chemical Products Co. , Ltd.
Tel
17362288188
Email
270788802@qq.com
Country
China
ProdList
56
Advantage
58
Shandong Yuxuan Chemical Products Co., Ltd
Tel
18106350153 15315790065
Email
1748782088@qq.com
Country
China
ProdList
73
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44688
Advantage
61
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
jiliang chemicals
Tel
21-62165282 15801962796;
Fax
021 61153784
Email
bidingchem@163.com
Country
China
ProdList
1199
Advantage
60
Beijing Isomersyn Technology CO;LTD
Tel
010-82954736 13391601435
Email
sales@isomersyn.com
Country
China
ProdList
3295
Advantage
57
Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18738
Advantage
57
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View Lastest Price from 10-Undecenal manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd
Product
10-Undecenal 112-45-8
Price
US $45.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20 tons
Release date
2024-11-29
JINING XINHE CHEMICAL CO., LTD
Product
10-Undecenal 112-45-8
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
10ton
Release date
2024-07-22
Hebei Kingfiner Technology Development Co.Ltd
Product
10-Undecenal 112-45-8
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
500000kg
Release date
2023-08-04

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