Ethyl 3-ethoxy-3-iminopropionate hydrochloride

Product Name: Ethyl 3-ethoxy-3-iminopropionate hydrochloride
CAS No.: 2318-25-4
Chemical Name: Ethyl 3-ethoxy-3-iminopropionate hydrochloride
Synonyms: Ethyl 3-ethoxy-3-iMinopropanoate hydrochloride;AURORA KA-6317;IMINOESTERCHLOROHYDRATE;ETHYL-MONO-IMIDO-MALONATE HCL;Ethyl 3-ethoxy-3-iminopropiona...;Ethyl3-ethoxy-3-iminopropionateHCl;3-ethoxy-3-iminopropionate hydrochL;Ethyl 3-ethoxy-3-imino-propanoate HCl;DIETHYL MALONMONOIMIDATE HYDROCHLORIDE;3-ETHOXY-3-IMINOPROPIONIC ACID ETHYL E
CBNumber: CB9213151
Molecular Formula: C7H13NO3.ClH
Formula Weight: 195.64
MOL File: 2318-25-4.mol

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Ethyl 3-ethoxy-3-iminopropionate hydrochloride Property

Melting point:: 111-113 °C (decomp)
storage temp.: 2-8°C
Appearance: White to off-white Solid
InChI: InChI=1S/C7H13NO3.ClH/c1-3-10-6(8)5-7(9)11-4-2;/h8H,3-5H2,1-2H3;1H
InChIKey: HYMXUYQKXCHWDC-UHFFFAOYSA-N
SMILES: C(OCC)(=O)CC(OCC)=N.[H]Cl
CAS DataBase Reference: 2318-25-4(CAS DataBase Reference)
EPA Substance Registry System: Ethyl 3-ethoxy-3-iminopropionate hydrochloride (2318-25-4)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26
WGK Germany: 3
F: 10-21
TSCA: TSCA listed
HS Code: 29252900

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 05563
Product name: Ethyl 3-ethoxy-3-imino-propionate hydrochloride
Purity: technical, ≥85%
Packaging: 5G-F
Price: $30
Updated: 2023/06/20

Sigma-Aldrich

Product number: 05563
Product name: Ethyl 3-ethoxy-3-imino-propionate hydrochloride
Purity: technical, ≥85%
Packaging: 5G
Price: $30
Updated: 2023/01/07

Sigma-Aldrich

Product number: 05563
Product name: Ethyl 3-ethoxy-3-imino-propionate hydrochloride
Purity: technical, ≥85%
Packaging: 25g
Price: $77
Updated: 2023/01/07

TCI Chemical

Product number: E1484
Product name: Ethyl 3-Ethoxy-3-iminopropanoate Hydrochloride
Packaging: 5G
Price: $34
Updated: 2025/07/31

TCI Chemical

Product number: E1484
Product name: Ethyl 3-Ethoxy-3-iminopropanoate Hydrochloride
Packaging: 25G
Price: $102
Updated: 2025/07/31

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Ethyl 3-ethoxy-3-iminopropionate hydrochloride Chemical Properties,Usage,Production

Chemical Properties

White crystalline powder

Synthesis

64-17-5

105-56-6

2318-25-4

Ethyl cyanoacetate (30 mL, 281 mmol) was dissolved with anhydrous ethanol (18.1 mL, 278 mmol) in anhydrous ether (28.1 mL) at 0°C and stirred to form a homogeneous solution. Dry hydrogen chloride gas was passed into the solution until saturation. Subsequently, the reaction mixture was warmed up to 22°C with continuous stirring for 20 hours. Upon completion of the reaction, the solvent was removed by concentration under reduced pressure to afford ethyl 3-ethoxy-3-iminopropionate hydrochloride (54.4 g, 99% yield). The structure of the product was confirmed by 1H NMR (400 MHz, CDCl3): δ 4.73 (q, J = 7.1 Hz, 2H); 4.24 (q, J = 7.2 Hz, 2H); 3.89 (s, 2H); 1.51 (t, J = 7.0 Hz, 3H); 1.30 (t, J = 7.2 Hz, 3H) ppm.

References

[1] Bioorganic and Medicinal Chemistry Letters, 2012, vol. 22, # 23, p. 7207 - 7213
[2] Chemical and Pharmaceutical Bulletin, 1985, vol. 33, # 7, p. 3046 - 3049
[3] Heterocycles, 1996, vol. 43, # 9, p. 1981 - 1989
[4] Tetrahedron, 2009, vol. 65, # 4, p. 757 - 764
[5] Patent: WO2006/7700, 2006, A1. Location in patent: Page/Page column 66-67

Ethyl 3-ethoxy-3-iminopropionate hydrochloride Preparation Products And Raw materials

Raw materials

Ethyl cyanoacetate

Preparation Products

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Ethyl 3-ethoxy-3-iminopropionate hydrochloride Suppliers

Austria 2 China 161 France 1 Germany 6 India 4 Japan 2 Switzerland 1 United Kingdom 3 United States 20 Global 200

Tianjin Lingxi Technology Co., Ltd

Tel: 022-022-60374912 15822944310
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Henan Ruiyun Chang Industrial Co., LTD

Tel: 18539434999
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J & K SCIENTIFIC LTD.

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Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
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Meryer (Shanghai) Chemical Technology Co., Ltd.

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3B Pharmachem (Wuhan) International Co.,Ltd.

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ShangHai DEMO Chemical Co.,Ltd

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Energy Chemical

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Beijing Ouhe Technology Co., Ltd

Tel: 010-010-82967028 13522913783
Fax: +86-10-82967029
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Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696
Email: info@hanhongsci.com
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ProdList: 42934
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View Lastest Price from Ethyl 3-ethoxy-3-iminopropionate hydrochloride manufacturers

Henan Aochuang Chemical Co.,Ltd.

Product: Ethyl 3-ethoxy-3-iminopropionate hydrochloride 2318-25-4
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-09-26

Nanjing Fred Technology Co., Ltd

Product: Ethyl 3-ethoxy-3-iminopropionatehydrochloride 2318-25-4
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1 ton
Release date: 2023-12-28

Honest Joy Holdings Limited

Product: Ethyl 3-ethoxy-3-iminopropionate, HCl 2318-25-4
Price: US $0.00/KG
Min. Order: 1KG
Purity: 97.2%
Supply Ability: 100 tons
Release date: 2022-01-26

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2318-25-4

C7H13NO3HCl

Organic Building Blocks

Esters

Building Blocks

C6 to C7

Carbonyl Compounds