ChemicalBook > CAS DataBase List > METSULFURON METHYL

METSULFURON METHYL

Product Name
METSULFURON METHYL
CAS No.
74223-64-6
Chemical Name
METSULFURON METHYL
Synonyms
QUIT;ALLY;allie;escort;MALBAN;dpx6376;Gropper;Ally[R];ally20df;dpd63760h
CBNumber
CB9251528
Molecular Formula
C14H15N5O6S
Formula Weight
381.36
MOL File
74223-64-6.mol
More
Less

METSULFURON METHYL Property

Melting point:
158°C
Boiling point:
181°C (rough estimate)
Density 
1.4561 (rough estimate)
refractive index 
1.6460 (estimate)
storage temp. 
0-6°C
solubility 
DMSO (Slightly), Methanol (Slightly, Heated)
form 
Solid
pka
2.55±0.10(Predicted)
color 
White to Off-White
Water Solubility 
27mg/L(temperature not stated)
BRN 
587472
LogP
2.200
CAS DataBase Reference
74223-64-6(CAS DataBase Reference)
EPA Substance Registry System
Metsulfuron-methyl (74223-64-6)
More
Less

Safety

Hazard Codes 
N
Risk Statements 
50/53
Safety Statements 
60-61
RIDADR 
UN3077 9/PG 3
WGK Germany 
2
RTECS 
DH3563000
HS Code 
29339900
Hazardous Substances Data
74223-64-6(Hazardous Substances Data)
Toxicity
LD50 in male and female rats, in male and female rabbits (mg/kg): >5000, >2000 orally; LC50 (96 hour) in American perch, rainbow trout: 150 ppm; LD50 in wild ducks: 2510 mg/kg (Lefebvre)
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P391Collect spillage. Hazardous to the aquatic environment

P501Dispose of contents/container to..…

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
46432
Product name
Metsulfuron-methyl
Purity
PESTANAL
Packaging
100mg
Price
$110
Updated
2024/03/01
Sigma-Aldrich
Product number
N12482
Product name
Metsulfuron-methyl
Purity
analytical standard
Packaging
100mg
Price
$99.3
Updated
2022/05/15
TRC
Product number
M227748
Product name
Metsulfuron-methyl
Packaging
1g
Price
$330
Updated
2021/12/16
Usbiological
Product number
283408
Product name
Metsulfuron methyl
Packaging
50mg
Price
$360
Updated
2021/12/16
AK Scientific
Product number
G186
Product name
Metsulfuronmethyl
Packaging
1g
Price
$413
Updated
2021/12/16
More
Less

METSULFURON METHYL Chemical Properties,Usage,Production

Chemical Properties

Light yellow solid

Chemical Properties

White, off-white or pale yellow crystalline solid. Slight, sweet odor; ester-like.

Uses

Metsulfuron-methyl is a triazine urea herbicide used to control broad-leaved weeds in barley and wheat.

Uses

Metsulfuron-methyl is an organic micro-pollutant.

Uses

Herbicide.

Definition

ChEBI: A N-sulfonylurea in which the sulfonyl group is attached to a 2-(methoxycarbonyl)phenyl group while a (4-methoxy-6-methyl-1,3,5-triazin-2-yl group replaces one of the amino hydrogens of the remaining urea group.

Agricultural Uses

Herbicide: Metsulfuron-methyl is a pre-emergence and post-emergence herbicide used to control annual grasses, brush, woody plants and broadleaf weeds. It can be applied to cereals including barley, rye and wheat and to pastures. It is primarily used to control brush, woody plants and broadleaf weeds on rights-of-way, fence rows, storage areas, highways and other non-crop areas.

Trade name

ALLIE®; ALLY®; ALLY-20DF®; ANSWER®; BRUSH-OFF®; CANVAS®; CIMARRON®; DMC® WEED CONTROL; DPD 63760H®; DPX 6376®; DPX-T 6376®; ESCORT®; FINESSE®; GROPPER®; NUP®; PARTISAN ®; PASTURE® MD; RIVERDALE®; ROSULFURON®

Potential Exposure

Metsulfuron-methyl is a preemergence and postemergence sulfonylurea herbicide used to control annual grasses, brush, woody plants and broadleaf weeds. It can be applied to cereals including barley, rye and wheat and to pastures. It is primarily used to control brush, woody plants and broadleaf weeds on rights-of-way, fence rows, storage areas, highways and other noncrop areas.

Environmental Fate

Soil/Plant. Hydrolyzes in soil and plants to nontoxic products (Hartley and Kidd, 1987). The half-life in soil varies from 7 days to 1 month (Hartley and Kidd, 1987).
Ismail and Lee (1995) studied the persistence of metsulfuron-methyl in a sandy loam (pH 5.1) and clay soil (3.1) under laboratory conditions. Degradation was more rapid in non-sterilized than in sterilized soil. In non-sterilized soil, the rate of degradation increased with increasing soil moisture content. When the moisture level in the sandy loam and clay soil was increased from 20 to 80% of field capacity at 35°C, the half-lives were reduced from 9.0 to 5.7 and 11.2 to 4.6, days, respectively. The investigators concluded that the disappearance of metsulfuron-methyl in soil resulted from microbial degradation and chemical hydrolysis.

Metabolic pathway

In soils, under aerobic conditions, metsulfuron methyl is degraded by the cleavage of the sulfonylurea linkage, resulting in the formation of methyl 2- (aminosulfonyl)benzoate, 4-methoxy-6-methyl-2-amino- 1,3,5-triazine, and saccharin as major products. Under anaerobic conditons, free acid of metsulfuron methyl and the resulting O-demethylation product are identified. The formation of two ring-opening products at the triazine moiety is observed. Under acidic conditions, hydrolytic degradation products identified are involved in the soil degradation products. In plants, the specific metabolites are identified as the hydroxylation product of the phenyl ring of metsulfuron methyl and 4-methoxy-6-hydroxymethyl-2-amino-1,3,5- triazine. Mammalian metabolites are also included in the soil metabolites.

Shipping

UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.

Incompatibilities

Strong oxidizers. Stable in air to about 140 C. It is hydrolyzed in acid solutions.

Waste Disposal

It is the responsibility of chemical waste generators to determine the toxicity and physical properties and of a discarded chemical and to properly identify its classification and certification as a hazardous waste and to determine the disposal method. United States Environmental Protection Agency guidelines for the classification determination are listed in 40 CFR Parts 261.3. In addition, waste generators must consult and follow all regional, national, state and local hazardous waste laws to ensure complete and accurate classification and disposal methods. Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Offer surplus and nonrecyclable solutions to a licensed disposal company. Dissolve or mix the pesticide with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.

More
Less

METSULFURON METHYL Suppliers

HBCChem, Inc.
Tel
+1-510-219-6317
Fax
+1-650-486-1361
Email
sales@hbcchem.com
Country
United States
ProdList
10648
Advantage
60
TargetMol Chemicals Inc.
Tel
+1-781-999-5354 +1-00000000000
Email
marketing@targetmol.com
Country
United States
ProdList
32165
Advantage
58
Aladdin Scientific
Tel
+1-+1(833)-552-7181
Email
sales@aladdinsci.com
Country
United States
ProdList
57505
Advantage
58
United States Biological
Tel
--
Fax
--
Email
sales@advtechind.com
Country
United States
ProdList
6075
Advantage
58
AccuStandard Inc
Tel
--
Fax
--
Email
info@bester.nl
Country
United States
ProdList
5300
Advantage
76
United States Biological
Tel
--
Fax
--
Email
chemicals@usbio.net
Country
United States
ProdList
6214
Advantage
80
MedChemExpress
Tel
--
Fax
--
Email
sales@medchemexpress.com
Country
United States
ProdList
6398
Advantage
58
Riedel-de Haen AG
Tel
--
Fax
--
Country
United States
ProdList
6773
Advantage
87
HBCChem Inc.
Tel
--
Fax
--
Email
sales@hbcchem-inc.com
Country
United States
ProdList
4569
Advantage
30
Fragmenta
Tel
--
Fax
--
Email
sales@fragmenta.com
Country
United States
ProdList
1068
Advantage
0
3B Scientific Corporation
Tel
--
Fax
--
Email
sales@3bsc.com
Country
United States
ProdList
6962
Advantage
56
AlliChem, LLC
Tel
--
Fax
--
Email
sales@allichemllc.com
Country
United States
ProdList
6516
Advantage
60
ChemService Inc.
Tel
--
Fax
--
Country
United States
ProdList
6379
Advantage
68
Waterstone Technology, LLC
Tel
--
Fax
--
Email
sales@waterstonetech.com
Country
United States
ProdList
6786
Advantage
30
AnsisChem
Tel
--
Fax
--
Country
United States
ProdList
409
Advantage
38
A.P.T. Labs, Inc.
Tel
--
Fax
--
Country
United States
ProdList
304
Advantage
42
DuPont Specialty Colorants & Additives
Tel
--
Fax
--
Country
United States
ProdList
1186
Advantage
87
HONEST JOY HOLDINGS LIMITED
Tel
--
Fax
--
Email
sales@honestjoy.cn
Country
United States
ProdList
6675
Advantage
54
2A PharmaChem USA
Tel
--
Fax
--
Email
sales@2apharmachem.com
Country
United States
ProdList
6137
Advantage
39
3B Scientific Corporation
Tel
--
Fax
--
Email
sales@3bsc.com
Country
United States
ProdList
6718
Advantage
47
APAC Pharmaceutical, LLC
Tel
--
Fax
--
Email
sales@apacpharma.com
Country
United States
ProdList
6322
Advantage
38
ChemPacific Corporation
Tel
--
Fax
--
Email
sales@chempacific.com
Country
United States
ProdList
6891
Advantage
51
Crescent Chemical Co., Inc.
Tel
--
Fax
--
Email
sales@creschem.com
Country
United States
ProdList
4597
Advantage
68
BOSCHE SCIENTIFIC, LLC
Tel
--
Fax
--
Email
Sales@BoscheSci.com
Country
United States
ProdList
6477
Advantage
55
AK Scientific, Inc.
Tel
--
Fax
--
Email
sales@aksci.com
Country
United States
ProdList
6347
Advantage
65
Beta Pharma, Inc.
Tel
--
Fax
--
Email
sales@betapharma.com
Country
United States
ProdList
6226
Advantage
60
More
Less

View Lastest Price from METSULFURON METHYL manufacturers

qingdao trust agri chemical co.,ltd
Product
METSULFURON METHYL 74223-64-6
Price
US $0.00/kg
Min. Order
100kg
Purity
20%
Supply Ability
20tons
Release date
2024-07-03
R&D Scientific Inc.
Product
Metsulfuron methyl 74223-64-6
Price
US $850.00/g
Min. Order
1g
Purity
98
Supply Ability
500 Kg
Release date
2024-04-24
Career Henan Chemical Co
Product
metsulfuron methyl 74223-64-6
Price
US $1.00/kg
Min. Order
1g
Purity
99%
Supply Ability
100KG
Release date
2018-12-25

74223-64-6, METSULFURON METHYLRelated Search:


  • QUIT
  • allie
  • ally20df
  • benzoicacid,2-(((((4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino)carbonyl)amino
  • Benzoicacid,2-[[[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino]carbonyl]amino]sulfonyl]-,methylester
  • brush-off
  • dpd63760h
  • dpx6376
  • methyl2-(((((4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino)carbonyl)amino)sulfo
  • methyl2-(3-(4-methoxy-6-methyl-1,3,5-triazin-2yl)ureidosulfonyl)benzoate
  • methyl2-(3-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)ureidosulphonyl)benzoate
  • Methyl2-[3-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)ureidosulphonyl]benzoate
  • n-((4-methoxy-6-methyl-1,3,5-triazin-2-yl)aminocarbonyl)-2-methoxycarbonylbenz
  • nyl)benzoate
  • oicacidmethylester
  • 2-(((((4-methoxy-6-methyl-1,3,5-triazin-2yl)amino)carbonyl)amino)sulfonyl)benz
  • ALLY
  • ALLY 60 DF WEED KILLER(R)
  • DPX-T6376
  • 2-[[[[(4-Methoxy-6-methyl-1,3,5-triazin-2-yl)amino]carbonyl]amino]sulfonyl]benzoic acid methyl ester
  • Methyl 2-(N-((4-Methoxy-6-Methyl-1,3,5-triazin-2-yl)carbaMoyl)sulfaMoyl)benzoate
  • methyl 2-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamoylsulfamoyl]benzoate
  • escort
  • Gropper
  • METHYL 2[[[[(4-METHOXY-6-METHYL-1,3,5-TRIAZIN-2-YL)AMINO]CARBONYL]AMINO]-SULFONYL]BENZOATE
  • MALBAN
  • Metsulfuron Me
  • METSULFURON-METHYL
  • metsulfuron-methyl DPX-6376
  • Messulfuron-methyl
  • METSULFURON METHYL, 100MG,NEAT
  • Ally[R]
  • Escort[R]
  • Gropper[R]
  • Methsulfuron Methyl Sodium
  • METASULFURONMETHYL
  • METSULPHURON-METHYL
  • METSULFRON-METHYL
  • metsulfuron-methyl 2-(4-methoxy-6-methyl-1,3,5-triazin-2-ylcarbamoylsulfamoyl) benzoic acid
  • Methsulfuron-methyl
  • methyl-2-[3-(4-methoxyl-6-methyl-1,3,5-triazin-2-yl) ureidosulphonyl] benzoate
  • Metsulfuron-methyl ,95%
  • 2-[[[[(4-METHOXY-6-METHYL-1,3,5-TRIAZIN-2-YL)AMINO]CARBONYL]AMINO]SULFONYL]BENZOIC ACIDETHYL ESTER
  • 1-(4-(methylsulfonyl)phenoxy)-4-(trifluoromethoxy)benzene
  • Metsulfuron methyl 100mg [74223-64-6]
  • Metsulfuron-methyl @100 μg/mL in MeOH
  • Metsulfuron-methylSolution,1000mg/L,1ml
  • Metsulfuron-methyl Standard
  • 74223-64-6 Metsulfuron Methyl herbicide for broadleaf weeds , annual grasses
  • TIANFU-CHEM CAS:74223-64-6 2-[[[[(4-Methoxy-6-methyl-1,3,5-triazin-2-yl)amino]carbonyl]amino]sulfonyl]benzoic acid methyl ester
  • C15210000 Metsulfuron-methyl
  • Metsulfuron-methyl 10.0 μg/ml Acetonitrile
  • 74223-64-6
  • 76223-64-6
  • C14H15N5O6S
  • Pesticides intermediate
  • Others chemical reagents
  • Herbicide