ChemicalBook > CAS DataBase List > DIETHYL BROMOMALONATE

DIETHYL BROMOMALONATE

Product Name
DIETHYL BROMOMALONATE
CAS No.
685-87-0
Chemical Name
DIETHYL BROMOMALONATE
Synonyms
Diethyl 2-bromomalonate;Diethylbrommalonat;RARECHEM AL BI 0815;ETHYL BROMOMALONATE;Diethyl bromalonate;DIETHYL BROMOMALONATE;Diethylebromomalonate;BROMO DIETHYL MALONATE;DiethylBromomalonate>alpha-Bromomalonic ester
CBNumber
CB9294925
Molecular Formula
C7H11BrO4
Formula Weight
239.06
MOL File
685-87-0.mol
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DIETHYL BROMOMALONATE Property

Melting point:
-54°C
Boiling point:
233-235 °C (lit.)
Density 
1.402 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.451(lit.)
Flash point:
>230 °F
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
solubility 
Chloroform, Hexanes
form 
Liquid
pka
9.29±0.46(Predicted)
Specific Gravity
1.402
color 
Clear colorless to slightly yellow
Water Solubility 
Does not mix well with water.
Sensitive 
Lachrymatory
BRN 
509768
CAS DataBase Reference
685-87-0(CAS DataBase Reference)
EPA Substance Registry System
Propanedioic acid, 2-bromo-, 1,3-diethyl ester (685-87-0)
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Safety

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3265 8/PG 2
WGK Germany 
3
F 
19
Hazard Note 
Corrosive/Lachrymator
TSCA 
Yes
HazardClass 
8
PackingGroup 
III
HS Code 
29171900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
D91209
Product name
Diethyl bromomalonate
Purity
92%
Packaging
25g
Price
$119
Updated
2024/03/01
Sigma-Aldrich
Product number
D91209
Product name
Diethyl bromomalonate
Purity
92%
Packaging
100g
Price
$312
Updated
2024/03/01
TCI Chemical
Product number
B1205
Product name
Diethyl Bromomalonate
Purity
>85.0%(GC)
Packaging
25g
Price
$22
Updated
2024/03/01
TCI Chemical
Product number
B1205
Product name
Diethyl Bromomalonate
Purity
>85.0%(GC)
Packaging
500g
Price
$194
Updated
2024/03/01
Alfa Aesar
Product number
A10965
Product name
Diethyl bromomalonate, 90+%
Packaging
25g
Price
$33.65
Updated
2024/03/01
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DIETHYL BROMOMALONATE Chemical Properties,Usage,Production

Chemical Properties

CLEAR COLOURLESS TO SLIGHTLY YELLOW LIQUID

Uses

Diethyl bromomalonate is used in perfumes. It is also used to synthesize other compounds such as barbiturates, artificial flavorings, vitamin B1, and vitamin B6.

Uses

Diethyl Bromomalonate is a chemical constituent of the asymmetric cyclopropanation of chalcones. Also used in the preparation of nanaplatforms for NIR imaging-guided photodynamic therapy of cancer cel ls.

Purification Methods

Purify the ester by fractional distillation in a vacuum. IR: max 1800 and 1700cm-1 [Abramovitch Can J Chem 37 1146 1959, Bretschneider & Karpitschka Monatsh Chem 84 1091 1053]. [Beilstein 2 IV 1904.]

DIETHYL BROMOMALONATE Preparation Products And Raw materials

Raw materials

Carbon tetrachloride Tetrahydrofuran Ethyl acetate Government regulation Diethyl malonate PETROLEUM ETHER Sodium carbonate

Preparation Products

5-METHOXYBENZOFURAN-2-BORONIC ACID Benzofuran-2-carboxylic acid 3-Methylbenzofuran-2-carboxylic acid
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DIETHYL BROMOMALONATE Suppliers

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View Lastest Price from DIETHYL BROMOMALONATE manufacturers

Henan Fengda Chemical Co., Ltd
Product
ethyl bromomalonate 685-87-0
Price
US $8.00-0.80/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-01-22
Hebei Duling International Trade Co. LTD
Product
DIETHYL BROMOMALONATE 685-87-0
Price
US $34.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000 tons
Release date
2023-04-19
Hebei Mojin Biotechnology Co., Ltd
Product
DIETHYL BROMOMALONATE 685-87-0
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-10-16

685-87-0, DIETHYL BROMOMALONATERelated Search:

2-Bromomalonaldehyde (1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide BROMOMALEIC ANHYDRIDE BROMOTRIS(TRIPHENYLPHOSPHINE)COPPER(I)& Bromoacetaldehyde diethyl acetal N-Bromoisocyanuric acid monosodium salt 1-BROMO-2-BUTANONE Ethyl nitroacetate Methyl Bromopyruvate Bromo-PEG2-acid Chloromethyl pivalate NEOPENTYLBORONIC ACID DIMETHYL BROMOMALONATE 2-Bromopropionic acid Diethyl 2-bromo-2-methylmalonate 2-Bromoethyl ethyl ether (R)-(+)-2-BROMOPROPIONIC ACID Ethyl bromoacetate

  • alpha-Bromomalonic ester
  • bromo-propanedioicacidiethylester
  • Diethyl 2-bromomalonate
  • Diethyl alpha-bromomalonate
  • Malonic acid, bromo-, diethyl ester
  • ETHYL BROMOMALONATE
  • DIETHYL BROMOMALONATE
  • BROMO DIETHYL MALONATE
  • BROMOMALONIC ACID DIETHYL ESTER
  • RARECHEM AL BI 0815
  • 2-BROMO-MALONIC ACID DIETHYL ESTER
  • DIETHYL BROMOMALONATE, ~85-95%
  • Diethyl bromomalonate, 95+%
  • Diethyl bromomalonate, 90-95%
  • Diethyl 2-bromopropane-1,3-dioate
  • Diethyl broMoMalonate, 90-95% 100ML
  • Diethyl broMoMalonate, 90-95% 25ML
  • Propanedioic acid, bromo-, diethyl ester
  • Diethyl bromomalonate, 90+%
  • Diethylebromomalonate
  • BroMine generation of diethyl Malonate
  • Diethyl bromomalonate 92%
  • Diethylbrommalonat
  • DiethylBromomalonate&gt
  • Propanedioic acid, 2-bromo-, 1,3-diethyl ester
  • Diethyl bromalonate
  • diethyl 2-bromopropanedioate
  • DI ETHYL BROMO MALONATE (DEBM)
  • 685-87-0
  • C7H11BrO4
  • BrCHCO2CH2CH32
  • C6 to C7
  • Carbonyl Compounds
  • Building Blocks
  • HALOGEN
  • Esters
  • Organic Building Blocks
  • Building Blocks
  • C6 to C7
  • Carbonyl Compounds
  • Chemical Synthesis
  • Organic Building Blocks
  • C6 to C7
  • Carbonyl Compounds
  • Esters
  • bc0001