Isobornyl acrylate
Description Sources- Product Name
- Isobornyl acrylate
- CAS No.
- 5888-33-5
- Chemical Name
- Isobornyl acrylate
- Synonyms
- iboa;IBXA;exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate;sr506;ebecryliboa;(1R,2R,4R)-rel-1,7,7-TriMethylbicyclo[2.2.1]heptan-2-yl acrylate;qm589;EM70DN;sartomer506;al-co-cureiba
- CBNumber
- CB9327469
- Molecular Formula
- C13H20O2
- Formula Weight
- 208.3
- MOL File
- 5888-33-5.mol
Isobornyl acrylate Property
- Melting point:
- <-35°C
- Boiling point:
- 119-121 °C15 mm Hg(lit.)
- Density
- 0.986 g/mL at 25 °C(lit.)
- vapor pressure
- 1.3Pa at 20℃
- refractive index
- n20/D 1.476(lit.)
- Flash point:
- 207 °F
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- solubility
- Chloroform (Slightly), Methanol (Slightly)
- form
- clear liquid
- color
- Colorless to Almost colorless
- Water Solubility
- Difficult to mix in water.
- FreezingPoint
- 5
- Sensitive
- Light Sensitive
- BRN
- 2254825
- Stability:
- Light sensitive
- InChIKey
- PSGCQDPCAWOCSH-BREBYQMCSA-N
- LogP
- 4.52 at 20℃
- CAS DataBase Reference
- 5888-33-5(CAS DataBase Reference)
- EPA Substance Registry System
- Isobornyl acrylate (5888-33-5)
Safety
- Hazard Codes
- Xn,N,Xi
- Risk Statements
- 20/22-36/37/38-51/53
- Safety Statements
- 26-36-61-28
- RIDADR
- UN 3082 9 / PGIII
- WGK Germany
- 2
- RTECS
- UD3940000
- TSCA
- Yes
- HazardClass
- 9
- PackingGroup
- III
- HS Code
- 29161290
- Toxicity
- LD50 oral in rat: 4890mg/kg
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H317May cause an allergic skin reaction
H319Causes serious eye irritation
H335May cause respiratory irritation
H410Very toxic to aquatic life with long lasting effects
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 392103
- Product name
- Isobornyl acrylate
- Purity
- technical grade, contains 200 ppm monomethyl ether hydroquinone as inhibitor
- Packaging
- 100ml
- Price
- $52.6
- Updated
- 2024/03/01
- Product number
- 392103
- Product name
- Isobornyl acrylate
- Purity
- technical grade, contains 200 ppm monomethyl ether hydroquinone as inhibitor
- Packaging
- 1l
- Price
- $225
- Updated
- 2024/03/01
- Product number
- I0638
- Product name
- Isobornyl Acrylate (stabilized with MEHQ)
- Purity
- >90.0%(GC)
- Packaging
- 25g
- Price
- $27
- Updated
- 2024/03/01
- Product number
- I0638
- Product name
- Isobornyl Acrylate (stabilized with MEHQ)
- Purity
- >90.0%(GC)
- Packaging
- 500g
- Price
- $104
- Updated
- 2024/03/01
- Product number
- L09977
- Product name
- Isobornyl acrylate, tech. 85%, stab. with 100ppm 4-methoxyphenol
- Packaging
- 250g
- Price
- $69.3
- Updated
- 2024/03/01
Isobornyl acrylate Chemical Properties,Usage,Production
Description
Isobornyl acrylate can be used to prepare block copolymers with n-butyl acrylate by atom transfer radical polymerization (ATRP)1. It is a photo-polymerizable monomer that is employed in micro-fluidic devices because of desirable properties, such as inertness, transparency, and resolution2.
Sources
- https://www.sigmaaldrich.com/catalog/product/aldrich/392103?lang=en®ion=US
- López-García, M. D. C., D. J. Beebe, and W. C. Crone. Characterization of poly(isobornyl acrylate) as a construction material for microfluidic applications. Journal of Applied Polymer Science. 2007:1894–1902.
Uses
Isobornyl acrylate (IBA) is used as UVcuring EBcuring adhesive, it can also be used to prepare block copolymers with n-butyl acrylate by atom transfer radical polymerization (ATRP).
Application
Isobornyl acrylate can be used as a co-monomer with other acrylic monomers in the preparation of pressure-sensitive adhesives (PSAs) for optical applications. It is also used in the development of high-performance and stable polymer gate dielectrics for organic thin-film transistors (OTFTs). Furthermore, it can also used in the preparation of UV-curable waterborne polyurethane (WPU) by copolymerization.
Hazard
Moderately toxic by ingestion. Low toxicity by skin contact. A moderate skin and mild eye irritant.
Flammability and Explosibility
Non flammable
Synthesis
Isobornyl acrylate is prepared by reacting (-)- borneol,triethylamine with acryloyl chloride in anhydrous THF.Dissolve (-)- borneol (1.00 g, 6.48 mmol, 1 equiv) and triethylamine (0.98 g, 9.72 mmol, 1.5 equiv) in anhydrous THF (20 mL) in a 100 mL round-bottom flask. Add acryloyl chloride (0.88 g, 9.72 mmol, 1.5 equiv) dropwise to the reaction mixture at 0 °C. Allow the reaction to stir at room temperature overnight. Filter the reaction solution. Concentrate the reaction solution on the rotary evaporator. Wash the mixture with water (20 mL). Extract the mixture with dichloromethane (3x20 mL). Dry the combined organic phases over anhydrous sodium sulfate. Filter and concentrate the residue. Purify the crude product further by silica gel column chromatography (petroleum ether/ethyl acetate = 4:1) to obtain isobornyl acrylate.
Isobornyl acrylate Preparation Products And Raw materials
Raw materials
Preparation Products
Isobornyl acrylate Suppliers
- Tel
- --
- Fax
- --
- shawn@gd-dmcc.com
- Country
- United Arab Emirates
- ProdList
- 20
- Advantage
- 58
View Lastest Price from Isobornyl acrylate manufacturers
- Product
- Bornylacrylate 5888-33-5
- Price
- US $70.00/kg
- Min. Order
- 1kg
- Purity
- 99
- Supply Ability
- 5000
- Release date
- 2024-05-22
- Product
- Acrylic acid isobornyl ester 5888-33-5
- Price
- US $70.00/kg
- Min. Order
- 1kg
- Purity
- 99
- Supply Ability
- 5000
- Release date
- 2024-05-23
- Product
- Isobornyl acrylate 5888-33-5
- Price
- US $10.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20ton
- Release date
- 2024-05-15