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TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV)

Product Name
TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV)
CAS No.
31011-57-1
Chemical Name
TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV)
Synonyms
Titanium(iv) chloride tet;Tetrachlorobis(THF)titanium;oxolane:tetrachlorotitanium;Titanium (IV) Chloride THF Complex;TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM;Bis(tetrahydrofuran)tetrachlorotitanium;TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV);Titanium tetrachloride bis(tetrahydrofuran);TITANIUM(IV) CHLORIDE-TETRAHYDOFURAN COMPLEX;Tetrachlorobis(tetrahydrofurane)titanium(IV)
CBNumber
CB9359422
Molecular Formula
C8H16Cl4O2Ti
Formula Weight
333.89
MOL File
31011-57-1.mol
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TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV) Property

Melting point:
126-128 °C(lit.)
Flash point:
1 °F
storage temp. 
2-8°C
form 
crystal
color 
yellow
Water Solubility 
Reacts with water
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
Sensitive 
Moisture Sensitive
InChI
InChI=1S/2C4H8O.4ClH.Ti/c2*1-2-4-5-3-1;;;;;/h2*1-4H2;4*1H;/q;;;;;;+4/p-4
InChIKey
LXWBMENBONGPSB-UHFFFAOYSA-J
SMILES
[Ti](Cl)(Cl)(Cl)Cl.C1COCC1.C1COCC1
CAS DataBase Reference
31011-57-1(CAS DataBase Reference)
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Safety

Hazard Codes 
C
Risk Statements 
14-34-37
Safety Statements 
26-36/37/39-45
RIDADR 
UN 2925 4.1/PG 2
WGK Germany 
3
3-10
TSCA 
No
HazardClass 
8
PackingGroup 
II
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H228Flammable solid

H314Causes severe skin burns and eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P240Ground/bond container and receiving equipment.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
395404
Product name
Titanium(IV) chloride tetrahydrofuran complex
Purity
97%
Packaging
5g
Price
$90.1
Updated
2025/07/31
Sigma-Aldrich
Product number
395404
Product name
Titanium(IV) chloride tetrahydrofuran complex
Purity
97%
Packaging
25g
Price
$276.45
Updated
2025/07/31
Strem Chemicals
Product number
22-1080
Product name
Tetrachlorobis(tetrahydrofuran)titanium(IV), min. 97%
Packaging
5g
Price
$63
Updated
2024/03/01
Strem Chemicals
Product number
22-1080
Product name
Tetrachlorobis(tetrahydrofuran)titanium(IV), min. 97%
Packaging
25g
Price
$244
Updated
2024/03/01
Strem Chemicals
Product number
22-1080
Product name
Tetrachlorobis(tetrahydrofuran)titanium(IV), min. 97%
Packaging
100g
Price
$732
Updated
2024/03/01
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TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV) Chemical Properties,Usage,Production

Chemical Properties

The reaction of tetrachlorodi(tetrahydrofuran)titanium(IV) and magnesium in tetrahydrofuran under argon protection gives [Ti(MgCl)2(THF)]2. It reacts with magnesium directly in a nitrogen atmosphere to give TiN(MgCl)2(THF), which can then be reacted with iodine, via the ITiN(MgCl)2 intermediate, to produce Ti=N(MgCl). Stannous chloride can also reduce it to produce TiCl3(THF)3 and green [TiCl2(THF)4][SnCl5(THF)]: 2 TiCl4(THF)2 + SnCl2 → [trans-TiCl2(THF)4][SnCl5(THF)] + TiCl3(THF)3

Uses

Titanium(IV) chloride tetrahydrofuran complex can be used as a catalyst in intermolecular hydroamination reactions.

reaction suitability

core: titanium
reagent type: Lewis acid
reagent type: catalyst

TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV) Preparation Products And Raw materials

Raw materials

Preparation Products

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TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV) Suppliers

Aladdin Scientific
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tp@aladdinsci.com
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United States
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Ereztech LLC
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Strem Chemicals, Inc.
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Riedel-de Haen AG
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Ereztech LLC
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Anvia Chemicals, LLC
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Country
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3933
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Gelest, Inc.
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Alfa Aesar
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3B Scientific Corporation
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31011-57-1, TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV)Related Search:


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  • Tetrachlorobis(tetrahydrofuran)titanium(IV),min.97%
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  • Titanium(IV) chloride tetrahydrofuran complex 97%
  • Tetrachlorobis(tetrahydrofuran)titanium (IV), 97+%
  • Bis(tetrahydrofuran)tetrachlorotitanium
  • Tetrachlorobis(THF)titanium
  • Titanium tetrachloride bis(tetrahydrofuran)
  • oxolane:tetrachlorotitanium
  • TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV) ISO 9001:2015 REACH
  • Titanium (IV) Chloride THF Complex
  • 31011-57-1
  • C8H16Cl4O2Ti
  • TiCl42C4H8O
  • TiCl42THF
  • 2C4H8OCl4Ti
  • TiCl4C4H8O2
  • Lewis Acids
  • Synthetic Reagents
  • Titanium
  • metal halide