Bis(triphenylphosphine)palladium(II) chloride

ChemicalBook > CAS DataBase List > Bis(triphenylphosphine)palladium(II) chloride

Bis(triphenylphosphine)palladium(II) chloride

Structure

Product Name: Bis(triphenylphosphine)palladium(II) chloride
CAS No.: 13965-03-2
Chemical Name: Bis(triphenylphosphine)palladium(II) chloride
Synonyms: DICHLOROBIS(TRIPHENYLPHOSPHINE)PALLADIUM;BIS(TRIPHENYLPHOSPHINE)PALLADIUM(II) DICHLORIDE;(PPh3)2PdCl2;DICHLOROBIS(TRIPHENYLPHOSPHINE)PALLADIUM(II);BIS(TRIPHENYLPHOSPHINE)PALLADIUM CHLORIDE;Bis(triphenylphosphine)dichloropalladium;BIS(TRIPHENYLPHOSPHINE)PALLADIUM(II);TRIPHENYLPHOSPHINE PALLADIUM CHLORIDE;Bis(triphenylphosphine)palladium(ll) chloride;PALLADIUM BIS(TRIPHENYLPHOSPHINE) DICHLORIDE
CBNumber: CB9364066
Molecular Formula: C36H30Cl2P2Pd
Formula Weight: 701.9
MOL File: 13965-03-2.mol

Less

Bis(triphenylphosphine)palladium(II) chloride Property

Melting point:: 260°C
vapor pressure: 0Pa at 25℃
RTECS: RT3578000
storage temp.: Store below +30°C.
solubility: Chloroform (Slightly), Dichloromethane (Slightly, Heated), Methanol (Slightly,
form: Powder
color: Yellow
Water Solubility: Insoluble in water. Soluble in benzene, and toluene.
Sensitive: Hygroscopic
BRN: 4935975
InChI: InChI=1S/2C18H15P.2ClH.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2
InChIKey: ILBDOZRDKNIJBS-UHFFFAOYSA-N
SMILES: P(C1C=CC=CC=1)(C1=CC=CC=C1)C1C=CC=CC=1.P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.[Pd](Cl)Cl
LogP: 5.69 at 20℃
CAS DataBase Reference: 13965-03-2(CAS DataBase Reference)

Less

Safety

Hazard Codes: Xn
Risk Statements: 36/37/38-22-40-19
Safety Statements: 37/39-26-36/37
WGK Germany: 3
F: 3-10-21
TSCA: No
HS Code: 28439090

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H317May cause an allergic skin reaction

H413May cause long lasting harmful effects to aquatic life

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P272Contaminated work clothing should not be allowed out of the workplace.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 8.04174
Product name: Bis(triphenylphosphine)palladium(II) chloride (15.2% Pd)
Purity: for synthesis
Packaging: 1g
Price: $148
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.04174
Product name: Bis(triphenylphosphine)palladium(II) chloride (15.2% Pd)
Purity: for synthesis
Packaging: 5G
Price: $550
Updated: 2024/03/01

Sigma-Aldrich

Product number: 208671
Product name: Bis(triphenylphosphine)palladium(II) dichloride
Purity: 98%
Packaging: 1g
Price: $68.9
Updated: 2024/03/01

Sigma-Aldrich

Product number: 208671
Product name: Bis(triphenylphosphine)palladium(II) dichloride
Purity: 98%
Packaging: 5g
Price: $214
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.04174
Product name: Bis(triphenylphosphine)palladium(II) chloride (15.2% Pd)
Purity: for synthesis
Packaging: 500mg
Price: $111
Updated: 2023/01/07

Less

Bis(triphenylphosphine)palladium(II) chloride Chemical Properties,Usage,Production

Structure

Several crystal structures containing PdCl2(PPh3)2 have been reported. In all of the structures,Bis(triphenylphosphine)palladium(II) chloride adopts a square planar coordination geometry and the trans isomeric form.

Chemical Properties

Bis(triphenylphosphine)palladium chloride is a coordination compound of palladium containing two triphenylphosphine and two chloride ligands. This yellow solid is insoluble in water but can dissolve in some organic solvents, such as toluene and benzene, and is slightly soluble in acetone and chloroform. It is used for palladium-catalyzed coupling reactions, e.g. the Sonogashira–Hagihara reaction. The complex adopts a square planar geometry and numerous similar complexes are known, with different phosphine ligands.

Uses

Bis(triphenylphosphine)palladium(II) chloride is used primarily in organometallic catalytic reactions due to the palladium content of the compound. It is also involved in crystalized structures of me tallacyclic complexes which show antiinflammatory and antifungal properties.

Synthesis

The synthesis of Bis(triphenylphosphine)palladium(II) chloride can be achieved by the reaction of palladium(II) chloride with triphenylphosphine, resulting in the formation of Bis(triphenylphosphine)palladium(II) chloride. This chemical process is represented by the balanced equation: PdCl2 + 2 PPh3 → PdCl2(PPh3)2.

Reactions

Precatalyst for the carbonylative cyclization of malonate derivatives.
Catalyst used in the double allylation of activated olefins.
Precatalyst for the three-component preparation of 3-arylidene- (or 3-alkenylidene) tetrahydrofurans.
Precatalyst for the homocoupling of terminal alkynes.
Precatalyst in the cross-coupling of alkynylsilanols and aryl halides.
Catalyst for direct Pd-catalyzed alkynylation of N-fused heterocycles.
Catalyst for a tandem Heck reaction/C-H functionalization.
Catalyst for direct arylation of tautomerizable heterocycles.

General Description

Bis(triphenylphosphine)palladium(II) dichloride is an organometallic complex. It is an efficient cross-coupling catalyst for C-C coupling reaction, such as Negishi coupling, Suzuki coupling, Sonogashira coupling and Heck coupling reaction. Detection of bis(triphenylphosphine)palladium(II) dichloride by electrospray ionization quadrupole ion trap mass spectrometry using different imidazolium salts as the charge carrier has been reported. It is employed as catalyst for the Heck reaction medium.

Flammability and Explosibility

Non flammable

Bis(triphenylphosphine)palladium(II) chloride Preparation Products And Raw materials

Raw materials

Acetonitrile Ethanol Toluene Hydrazine hydrate Palladium chloride Ethyl acetate Triphenylphosphine

Preparation Products

5-(2-PHENYLETH-1-YNYL)THIOPHENE-2-CARBALDEHYDE 4-ETHYNYLANILINE 4-Azaindole 4-PHENYLETHYNYLPHTHALIC ANHYDRIDE 2-CHLORO-7H-PYRROLO[2,3-D]PYRIMIDINE

Less

Bis(triphenylphosphine)palladium(II) chloride Suppliers

Americas 1 Australia 1 Belgium 4 Canada 1 China 464 Europe 4 France 2 Germany 10 India 45 Italy 2 Japan 12 Poland 1 South Korea 4 Switzerland 5 Ukraine 1 United Kingdom 17 United States 70 Global 644

Pure Chemistry Scientific Inc.

Tel: 001-857-928-2050 or 1-888-588-9418
Fax: 001-617-206-9595
Email: sales@chemreagents.com
Country: United States
ProdList: 10186
Advantage: 62

HBCChem, Inc.

Tel: +1-510-219-6317
Fax: +1-650-486-1361
Email: sales@hbcchem.com
Country: United States
ProdList: 10648
Advantage: 60

Accela ChemBio Inc.

Tel: +1-858-6993322
Fax: (+1)-858-876-1948
Email: info@accelachem.com
Country: United States
ProdList: 17777
Advantage: 58

Alchem Pharmtech,Inc.

Tel: 8485655694
Email: sales@alchempharmtech.com
Country: United States
ProdList: 63687
Advantage: 58

AB PharmaTech,LLC

Tel: 323-480-4688
Fax: 323-480-4688
Email: sales@acrospharmatech.com
Country: United States
ProdList: 989
Advantage: 55

Aladdin Scientific

Tel: +1-+1(833)-552-7181
Email: sales@aladdinsci.com
Country: United States
ProdList: 57505
Advantage: 58

Synthonix Inc

Tel: --
Fax: --
Email: info@synthonix.com
Country: United States
ProdList: 6872
Advantage: 58

United States Biological

Tel: --
Fax: --
Email: sales@advtechind.com
Country: United States
ProdList: 6075
Advantage: 58

Heraeus Incorporated

Tel: --
Fax: --
Email: douglas.joy@heraeus.com
Country: United States
ProdList: 40
Advantage: 58

SynQuest Laboratories, Inc.,

Tel: --
Fax: --
Country: United States
ProdList: 2301
Advantage: 58

GFS Chemicals, Inc.

Tel: --
Fax: --
Email: Development@gfschemicals.com
Country: United States
ProdList: 338
Advantage: 58

MilliporeSigma (Sigma-Aldrich Corp.)

Tel: --
Fax: --
Email: @sial.com
Country: United States
ProdList: 5414
Advantage: 58

Colonial Metals Inc.,

Tel: --
Fax: --
Country: United States
ProdList: 18
Advantage: 58

Stanford Advanced Materials (SAM)

Tel: --
Fax: --
Email: sales@SAMaterials.com
Country: United States
ProdList: 102
Advantage: 58

Beantown Chemical Corporation

Tel: --
Fax: --
Country: United States
ProdList: 396
Advantage: 58

Redox Scientific

Tel: --
Fax: --
Email: info@redoxsci.com
Country: United States
ProdList: 2380
Advantage: 58

TCI America, Inc. (Tokyo Chemical Industry Co., Ltd.)

Tel: --
Fax: --
Email: .Crew@tcichemicals.com
Country: United States
ProdList: 3164
Advantage: 58

Voigt Global Distribution Inc

Tel: --
Fax: --
Email: Sales@Vgdusa.Com
Country: United States
ProdList: 110
Advantage: 58

Alichem Inc.

Tel: --
Fax: --
Email: sales@alichem.com
Country: United States
ProdList: 6167
Advantage: 58

Fluorochem Ltd.

Tel: --
Fax: --
Email: enquiries@fluorochem.co.uk
Country: United States
ProdList: 4583
Advantage: 58

Spectrum Chemical Mfg. Corp.

Tel: --
Fax: --
Email: marketing@spectrumchemical.com
Country: United States
ProdList: 3113
Advantage: 60

VWR International, LLC.

Tel: --
Fax: --
Email: @sargentwelch.com
Country: United States
ProdList: 6262
Advantage: 58

Rare Earth Products

Tel: --
Fax: --
Email: sales@rareearthproducts.com
Country: United States
ProdList: 42
Advantage: 58

Charkit Chemical Corporation

Tel: --
Fax: --
Email: sales@charkit.com
Country: United States
ProdList: 2993
Advantage: 65

American Elements, USA

Tel: --
Fax: --
Email: customerservice@americanelements.com
Country: United States
ProdList: 251
Advantage: 70

OChem Incorporation

Tel: --
Fax: --
Email: sales@ocheminc.com
Country: United States
ProdList: 6501
Advantage: 60

Oakwood Products, Inc.

Tel: --
Fax: --
Email: sales@oakwoodchemical.com
Country: United States
ProdList: 6193
Advantage: 74

Fine Chem Trading LTD

Tel: --
Fax: --
Email: chemfinder@chemfinder.co.uk
Country: United States
ProdList: 1609
Advantage: 64

Strem Chemicals, Inc.

Tel: --
Fax: --
Email: info@strem.com
Country: United States
ProdList: 4910
Advantage: 86

United States Biological

Tel: --
Fax: --
Email: chemicals@usbio.net
Country: United States
ProdList: 6214
Advantage: 80

Alfa Chemistry

Tel: --
Fax: --
Email: info@Alfa-Chemistry.com
Country: United States
ProdList: 6814
Advantage: 0

Combi-Blocks Inc.

Tel: --
Fax: --
Email: sales@combi-blocks.com
Country: United States
ProdList: 6618
Advantage: 69

Rare Earth Products Inc

Tel: --
Fax: --
Email: sales@rareearthproducts.com
Country: United States
ProdList: 1095
Advantage: 58

GFS Chemicals Inc

Tel: --
Fax: --
Email: service@gfschemicals.com
Country: United States
ProdList: 2329
Advantage: 58

Riedel-de Haen AG

Tel: --
Fax: --
Country: United States
ProdList: 6773
Advantage: 87

TCI America

Tel: --
Fax: --
Email: sales@tciamerica.com
Country: United States
ProdList: 6909
Advantage: 75

Matrix Scientific

Tel: --
Fax: --
Email: sales@matrixscientific.com
Country: United States
ProdList: 6632
Advantage: 80

Frontier Scientific, Inc.

Tel: --
Fax: --
Email: sales@frontiersci.com
Country: United States
ProdList: 6222
Advantage: 86

Abblis Chemicals LLC

Tel: --
Fax: --
Email: info@abblis.com
Country: United States
ProdList: 1272
Advantage: 0

Synthonix

Tel: --
Fax: --
Email: info@synthonix.com
Country: United States
ProdList: 1423
Advantage: 68

Accela ChemBio Inc.

Tel: --
Fax: --
Email: info@accelachem.com
Country: United States
ProdList: 1054
Advantage: 50

Small Molecules, Inc.

Tel: --
Fax: --
Email: sales@small-molecules.com
Country: United States
ProdList: 1218
Advantage: 30

Anvia Chemicals, LLC

Tel: --
Fax: --
Email: sales@anviachem.com
Country: United States
ProdList: 3933
Advantage: 0

Small Molecules, Inc.

Tel: --
Fax: --
Email: sales@small-molecules.com
Country: United States
ProdList: 990
Advantage: 50

Wilshire Chemical Company Inc.

Tel: --
Fax: --
Email: WilshrChem@AOL.COM
Country: United States
ProdList: 3498
Advantage: 58

Ring Specialty Chemicals Inc.

Tel: --
Fax: --
Email: info@ringchemicals.com
Country: United States
ProdList: 888
Advantage: 39

HBCChem Inc.

Tel: --
Fax: --
Email: sales@hbcchem-inc.com
Country: United States
ProdList: 4569
Advantage: 30

Waterstone Technology, LLC

Tel: --
Fax: --
Email: sales@waterstonetech.com
Country: United States
ProdList: 6786
Advantage: 30

Advanced Synthesis Technologies

Tel: --
Fax: --
Email: sales@advancedsynthesis.com
Country: United States
ProdList: 4775
Advantage: 61

Advance Scientific & Chemical

Tel: --
Fax: --
Email: sales@advance-scientific.com
Country: United States
ProdList: 6419
Advantage: 71

Less

View Lastest Price from Bis(triphenylphosphine)palladium(II) chloride manufacturers

Shanghai Daken Advanced Materials Co.,Ltd

Product: Bis(triphenylphosphine)palladium(II) chloride 13965-03-2
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 100KG /month
Release date: 2021-11-05

Hebei Weibang Biotechnology Co., Ltd

Product: Bis(triphenylphosphine)palladium(II) chloride 13965-03-2
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2024-10-28

Hebei Yanxi Chemical Co., Ltd.

Product: Bis(triphenylphosphine)palladium(II) chloride 13965-03-2
Price: US $60.00-20.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 30 tons
Release date: 2023-09-25

13965-03-2, Bis(triphenylphosphine)palladium(II) chlorideRelated Search:

Ammonium chloride Palladium Polyvinyl chloride DICHLOROTRIPHENYLPHOSPHORANE Sodium chloride Triphenylphosphine Potassium chloride Choline chloride Cobalt chloride Calcium chloride Palladium chloride Bis(tricyclohexylphosphine)palladium(II) Dichloride Tetrakis(triphenylphosphine)palladium Bis(dibenzylideneacetone)palladium Bis(acetonitrile)dichloropalladium(II) Trifluoromethanesulfonimide Tris(triphenylphosphine)ruthenium(II) chloride Bisoctyl dimethyl ammonium chloride

PALLADIUM BIS(TRIPHENYLPHOSPHINE) DICHLORIDE

PALLADIUM(II)BIS(TRIPHENYLPHOSPHINE) DICHLORIDE

DICHLOROBIS(TRIPHENYLPHOSPHINE)PALLADATE (II)

DICHLOROBIS(TRIPHENYLPHOSPHINE)PALLADIUM

DICHLOROBIS(TRIPHENYLPHOSPHINE)PALLADIUM(II)

BIS(TRIPHENYLPHOSPHINE)PALLADIUM CHLORIDE

BIS-(TRIPHENYLPHOSPHINE)-PALLADIUM DICHLORIDE

BIS(TRIPHENYLPHOSPHINE)PALLADIUM(II) DICHLORIDE

BIS(TRIPHENYLPHOSPHINE)PALLADIUM(II) CHLORIDE

TRANS-DICHLOROBIS-(TRIPHENYLPHOSPHINE)-PALLADIUM

TRANS-BIS(TRIPHENYLPHOSPHINE)PALLADIUM(II) CHLORIDE

TRIPHENYLPHOSPHINE PALLADIUM CHLORIDE

Bis(triphenylphosphine)dichloropalladium(II)~Dichlorobis(triphenylphosphine)palladium(II)

dichlorobis(triphenylphophine) palladium (II)

DICHLOROBIS(TRIPHENYLPHOSPHINE)-PALLADIU M(II), 99.99%

Bis(triphenylphosphine)palladium(II) chloride,98%

Bis(triphenylphosphine)palladium(II) chloride,99% (99.9+%-Pd)

Palladium(II)bis(triphenylphosphine)

Bis(triphenylphosphine)palladium(II) dichloride,Dichlorobis(triphenylphosphine)palladium(II), Palladium(II)bis(triphenylphosphine) dichloride

Bis(triphenylphosphine)palladium(II) chloride, 15% Pd, for analysis

trans-Dichlorobis(triphenylphosphine)palladium(II)/potassium phosphate admixture [Catkit single-use vials - 6.32 wt% Pd complex]

Bis(triphenylphosphine)palladium(II) dichloride impregnated tablets, ChemDose(R), Bis(triphenylphosphine)palladium(II) dichloride tablets, Dichlorobis(triphenylphosphine)palladium(II) impregnated tablets, PdCl2(PPh3)2 impregnated tablets, Palladium(II) bis(triphenylphosphine) dichloride impregnated tablets

Bis(triphenylphosphine)palladium(II) dichloride, ChemDose(R) tablets

Dichlorobis(triphenylphosphine)palladium(II) ,98%

trans-Dichlorobis(triphenylphosphine)platinum(Ⅱ)

trans-Dichlorobis(triphenylphosphine)palladium(II), 99.95% trace metals basis

Bis(triphenylphosphine)palladium(Ⅱ) Dichloride

is(triphenylphosphine)palladium(II) chloride

Bis(triphenylphosphine)pa...

Bis(triphenylphosphine)palladiuM(II) chloride, 98% 2.5GR

Bis(triphenylphosphine)palladiuM(II) chloride, 98% 5GR

Bis(triphenylphosphine)dichloropalladium

Bis(triphenylphosphine)palladium(II) dichloride, ChemDose? tablets

Bis(triphenylphosphine)palladium(II) chloride (15.2% Pd) for synthesis

BIS-(TRIPHENYLPHOSPHINE)-PALLADIUM

Bis(triphenylphosphine)palladium(II) Dichloride (PdCl2(PPh3)2)

trans-Dichlorobis(triphenylphosphine)palladium(II),(PPh3)2PdCl2

Bis(triphenylphosphine)palladium(II) chloride (15.2% Pd)

Dichlorobis-(triphenylphosphino)-palladium (II)

Dichlorotris(triphenylphosphine) palladium

TRIPHENYLPHOSPHINE PALLADIUM CHLORIDETRIPHENYLPHOSPHINE PALLADIUM CHLORIDETRIPHENYLPHOSPHINE PALLADIUM CHLORIDE

BIS(TRIPHENYLPHOSPHINE)PALLADIUM(II) DI&

trans-Bis(triphenylphosphine)palladium(II)chloride (15% Pd)

Bis(triphenylphoshine)palladium(II)chloride

BIS(TRIPHENYLPHOSPHINE) PALLADIUM DICHOLORIDE

Bis(triphenylphosphine)palladium(II) chloride, 15% Pd

trans-Dichlorobis(triphenylphosphine)palladium(II),99%(99.9+%-Pd)

Palladium, dichlorobis(triphenylphosphine)-

bis(triphenylphosphine)dichloropalladium(ii)

trans-dichlorobis(triphenylphosphine)palladium(ii), premion

PALLADIUM(II)CHLORIDE-BIS(TRIPHENYLPHOSPHINE)

Bis（triphenylphosphine）palladium(II)dich

BIS(TRIPHENYLPHOSPHINE)PALLADIUML(II)DICHLORIDE

BIS(TRIPHENYLPHOSPHINE)PALLADIUM(II) CHLO

BIS (TRIPHENYLPHOSPHANE) PALLADIUM-2-CHLORIDE

DICHLOROBIS(TRIPHENYLPHOSPHINE)- &

Dichlorodi(trisphenylphosphine) palladium(II)

trans-Dichlorobis(triphenylphosphine)palladium(II), Pd 14.0% min