ChemicalBook > CAS DataBase List > (2R)-Bornane-10,2-sultam

(2R)-Bornane-10,2-sultam

Product Name
(2R)-Bornane-10,2-sultam
CAS No.
94594-90-8
Chemical Name
(2R)-Bornane-10,2-sultam
Synonyms
D-SultaM;(1S,2R)-(-)-;(2R)-Bornane-10;L-(+)-CAMPHOR SULTAM;(2R)-Bornane-10,2-su;(-)-10,2-CAMPHORSULTAM;(1S)-(-)-Camphorsultam;(2R)-Borne-10,2-sultam;(-)-2,10-Camphorsultam;(1S)-2,10-CAMPHORSULTAM
CBNumber
CB9468760
Molecular Formula
C10H17NO2S
Formula Weight
215.31
MOL File
94594-90-8.mol
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(2R)-Bornane-10,2-sultam Property

Melting point:
183-185 °C
alpha 
-33 º (c=4.9, CHCl3)
Boiling point:
324.8±25.0 °C(Predicted)
Density 
1.1469 (rough estimate)
refractive index 
-31 ° (C=1, CHCl3)
storage temp. 
Sealed in dry,Room Temperature
solubility 
Chloroform, Ethanol, Methanol
form 
Liquid
pka
11.05±0.40(Predicted)
color 
Clear colorless
optical activity
[α]19/D 32°, c = 5 in chloroform
Water Solubility 
Slightly soluble in water.
BRN 
83811
CAS DataBase Reference
94594-90-8(CAS DataBase Reference)
NIST Chemistry Reference
(-)-10,2-Camphorsultam(94594-90-8)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39-36
WGK Germany 
3
HS Code 
29349990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
298352
Product name
(1S)-(?)-2,10-Camphorsultam
Purity
98%
Packaging
5g
Price
$94.2
Updated
2024/03/01
TCI Chemical
Product number
C1325
Product name
(-)-10,2-Camphorsultam
Purity
>98.0%(GC)
Packaging
1g
Price
$25
Updated
2024/03/01
TCI Chemical
Product number
C1325
Product name
(-)-10,2-Camphorsultam
Purity
>98.0%(GC)
Packaging
5g
Price
$64
Updated
2024/03/01
Alfa Aesar
Product number
A15897
Product name
(1S,2R)-(-)-10,2-Camphorsultam, 99%
Packaging
5g
Price
$196.65
Updated
2024/03/01
Alfa Aesar
Product number
A15897
Product name
(1S,2R)-(-)-10,2-Camphorsultam, 99%
Packaging
1g
Price
$68.5
Updated
2021/12/16
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(2R)-Bornane-10,2-sultam Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powde

Uses

(1S,2R)-(-)-10,2-Camphorsultam is used in the asymmetric synthesis of (S)- and (R)-N-Fmoc-S-trityl-α-methylcysteine. It is used as proton source in the synthesis of chiral α,γ-substituted γ-butyrolactones. It is also employed as a chiral probe for the optical resolution by HPLC and X-ray crystallographic determination of the absolute stereochemistry of carboxylic acids. Also used to prepare N-acryloyl derivatives which are employed as dienophiles in asymmetric Diels-Alder reactions. and for other asymmetric transformations.

Uses

(1S)-(?)-2,10-Camphorsultam may be used in the asymmetric synthesis of (S)- and (R)-N-Fmoc-S-trityl-α-methylcysteine. It may be used as proton source in the synthesis of chiral α,γ-substituted γ-butyrolactones.

Uses

(2R)-Bornane-10,2-sultam is a reagent used to make Camphorsultam conjugates.

General Description

(1S,2R,4R)-(?)-2,10-Camphorsultam may be employed as a chiral probe for the optical resolution by HPLC and X-ray crystallographic determination of the absolute stereochemistry of carboxylic acids.

Purification Methods

The (-)-enantiomer is recrystallised from 95% EtOH and dried in a vacuum desiccator. It dissolves in dilute aqueous NaOH and can be precipitated without hydrolysis by acidifying. It forms the N-Na salt in EtOH (by addition of Na to the EtOH solution), and the salt can be methylated with MeI to give the (-)-N-Me lactam with m 80o after recrystallisation from hot H2O and has []D -59.6o (c 5, CHCl3) [Shriner et al. J Am Chem Soc 60 2794 1938]. [Oppolzer et al. Helv Chim Acta 69 1142 1986, Weismiller et al. Org Synth 69 154 1955, Beilstein 27 III/IV 1007.]

(2R)-Bornane-10,2-sultam Preparation Products And Raw materials

Raw materials

Preparation Products

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(2R)-Bornane-10,2-sultam Suppliers

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View Lastest Price from (2R)-Bornane-10,2-sultam manufacturers

HebeiShuoshengImportandExportco.,Ltd
Product
(2R)-Bornane-10,2-sultam 94594-90-8
Price
US $6.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
2000KG/Month
Release date
2024-08-05
Hebei Longbang Technology Co., Ltd
Product
(2R)-Bornane-10,2-sultam 94594-90-8
Price
US $7.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20TONS
Release date
2024-05-24
Hebei Weibang Biotechnology Co., Ltd
Product
(2R)-Bornane-10,2-sultam 94594-90-8
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-11

94594-90-8, (2R)-Bornane-10,2-sultamRelated Search:

N-Acetylsulfanilyl chloride p-Toluenesulfonamide (1R)-(-)-10-Camphorsulfonic acid Dimethyl ether ETHANE Dimethyl phthalate Dimethyl sulfide Dimethyl fumarate Sulfanilamide N,N-Dimethylformamide (-)-CAMPHOR Benzenesulfonamide Dimethyl sulfoxide L(-)-10-Camphorsulfonyl chloride (1R,2R)-(-)-1,2-Diaminocyclohexane Ethyl (S)-9,10-difluoro-3-methyl-7-oxo-2,3-dihydro-7H-pyrido[1,2,3-de]-1,4-benzoxazine-6-carboxylate 3-METHOXY-DL-TYROSINE L(-)-Carvone

  • (-)-EXO-10,2-BORNANESULTAM
  • (-)-D-2,10-CAMPHORSULTAM
  • (-)-D-2,10-CAMPHOSULTAM
  • D(-)-10,2-CAMPHORSULTAME
  • (2R)-BORNANE-10,2-SULTAM
  • (1S)-(-)-2,10-CAMPHORSULTAM
  • (1S)-2,10-CAMPHORSULTAM
  • (1S,2R)-(-)-2,10-CAMPHORSULTAM
  • (1S,5R)-10,10-DIMETHYL-3-THIA-4-AZATRICYCLO[5.2.1.0(1,5)]DECANE 3,3-DIOXIDE
  • (-)-10,2-CAMPHORSULTAM
  • [3AS-(3A-ALPHA,6-ALPHA,7A-BETA)]-HEXAHYDRO-8,8-DIMETHYL-2,2-DIOXIDE-3H-3A,6-METHANO-2,1-BENZISOTHIAZOLE
  • [3as-(3aalpha,6alpha,7abeta)]-hexahydro-8,8-dimethyl-2,2-dioxide-3h-3a,6-methano-2,1-benzisothiazole
  • [3AS-(3AALPHA,6ALPHA,7ABETA)]-HEXAHYDRO-8,8-DIMETHYL-3H-3A,6-METHANO-2,1-BENZISOTHIAZOLE-2,2-DIOXIDE
  • (1S)-(-)-Camphorsultam
  • (1S,2R)-(-)-10,2-Camphorsultam
  • (1S,2R)-(-)-2,10-CAMPHORSULTAME
  • 3H-3a,6-Methano-2,1-benzisothiazole, hexahydro-8,8-dimethyl-, 2,2-dioxide, (3aS,6R,7aR)-
  • (-)-exo-10,2-Bornanesultam, (1S,5R)-10,10-Dimethyl-3-thia-4-azatricyclo[5.2.1.01,5]decane 3,3-dioxide
  • (-)-10,2-Camphorsultam, (-)-exo-10,2-Bornanesultam, [3aS-(3aα,6α,7aβ)]-hexahydro-8,8-dimethyl-3H-3a,6-methano-2,1-benzisothiazole-2,2-dioxide, (1S,5R)-10,10-Dimethyl-3-thia-4-azatricyclo[5.2.1.01,5]decane 3,3-dioxide
  • (2R)-10,2-Camphorsultam
  • (2R)-Bornane-10,2-sultam, 99+%, ee:>99%
  • D-(+)-CAMPHOR SULTAM INFRA-ACIDAMIDE
  • L-(+)-CAMPHOR SULTAM
  • (IS)-(-)-2,10-Camphorsultam
  • (2R)-Bornane-10,2-sultam ,98%
  • [3aS-(3aα,6α,7aβ)]-hexahydro-8,8-dimethyl-3H-3a,6-methano-2,1-benzisothiazole-2,2-dioxide
  • (2R)-Bornane-10,2-sultam99+%(>99% ee)
  • (3aR)-Hexahydro-8,8-dimethyl-3H-3aα,6α-methano-2,1-benzisothiazole 2,2-dioxide
  • (3aS)-1,3,5,6,7,7aα-Hexahydro-4H-3aβ,6β-isopropylidene-2,1-benzisothiazole 2,2-dioxide
  • (3aS)-1,4,5,6,7,7aα-Hexahydro-8,8-dimethyl-3H-3aβ,6β-methano-2,1-benzisothiazole 2,2-dioxide
  • (3aS,7aα)-8,8-Dimethyl-3aβ,6β-methanooctahydro-2,1-benzisothiazole 2,2-dioxide
  • (7aα)-8,8-Dimethyl-3aβ,6β-methanooctahydro-2,1-benzisothiazole 2,2-dioxide
  • [3aS,7aα,(-)]-Hexahydro-8,8-dimethyl-3H-3aβ,6β-methano-2,1-benzisothiazole 2,2-dioxide
  • (1S,2R)-(-)-
  • (2R)-Bornane-10,2-su
  • (2R)-Bornane-1,2-sultaM
  • (1S)-(-)-10,2-CaMphorsultaM
  • Hexahydro-8,8-diMethyl-3H-3a,6-Methano-2,1-benzisothiazole
  • D-SultaM
  • (2R)-Bornane-10,2-sultam (1S,5R)-10,10-Dimethyl-3-thia-4-azatricyclo[5.2.1.0(1,5)]decane 3,3-Dioxide
  • (2R)-Bornane-10,2-sultaM, 99+%
  • (1S,2R)-(-)-2,10-CAMPHORSULTAME FOR SYNT
  • (3aS,6S,7aS)-8,8-DiMethylhexahydro-1H-3a,6-Methanobenzo[c]isothiazole 2,2-dioxide
  • (2R)-Bornane-10,2-sultam (1S)-(-)-2,10-Camphorsultam
  • (1<i>S</i>)-(-)-2,10-Camphorsultam
  • (2R)-Borne-10,2-sultam
  • D-2,10-Camphorsultam,99%e.e.
  • (2R)-Bornane-10, 2-sultam, ≥99% ee
  • (-)-10,2-Camphorsultam &gt
  • (1S)-(?)-2,10-CamphorsuL
  • (-)-10,2-Camphorsultam?
  • (1S)-(-)-2,11-Camphorsultam
  • (2R)-Bornane-10,2-sultam ISO 9001：2015 REACH
  • (-)-2,10-Camphorsultam
  • (1S,2R)-(-)-10,2-Camphorsultam, 99%,
  • (5R,7R)-10,10-dimethyl-3thia-4-azatricyclo[5.2.1.01?]decane 3,3-dioxide
  • (3aS,6R,7aR)-8,8-Dimethylhexahydro-1H-3a,6-methanobenzo[c]isothiazole 2,2-dioxide
  • (2R)-Bornane-10