ChemicalBook > CAS DataBase List > 3-AMINO-2-BROMO-6-METHOXYPYRIDINE

3-AMINO-2-BROMO-6-METHOXYPYRIDINE

Product Name
3-AMINO-2-BROMO-6-METHOXYPYRIDINE
CAS No.
135795-46-9
Chemical Name
3-AMINO-2-BROMO-6-METHOXYPYRIDINE
Synonyms
2-Bromo-6-methoxy-3-pyridinamine;3-Amino-6-methoxy-2-bromopyridine;5-AMino-6-broMo-2-Methoxypyridine;2-BROMO-3-AMINO-6-METHOXYPYRIDINE;3-AMINO-2-BROMO-6-METHOXYPYRIDINE;3-AMINO-2-CHLORO-6-METHOXYPYRIDINE;3-Pyridinamine, 2-bromo-6-methoxy-;3-Amino-2-bromo-6-methoxypyridine ,97%;3-AMINO-2-BROMO-6-METHOXYPYRIDINE ISO 9001:2015 REACH
CBNumber
CB9485154
Molecular Formula
C6H7BrN2O
Formula Weight
203.04
MOL File
135795-46-9.mol
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3-AMINO-2-BROMO-6-METHOXYPYRIDINE Property

Boiling point:
293.9±35.0 °C(Predicted)
Density 
1.622±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
pka
1.12±0.10(Predicted)
Appearance
Yellow to brown Solid
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Safety

Risk Statements 
20/21/22-36/37/38
Safety Statements 
26-36/37/39
HS Code 
29333990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TRC
Product number
A602193
Product name
3-Amino-2-bromo-6-methoxypyridine
Packaging
100mg
Price
$75
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB140331
Product name
2-Bromo-6-methoxypyridin-3-amine
Packaging
2g
Price
$87
Updated
2021/12/16
Apolloscientific
Product number
OR315074
Product name
2-Bromo-6-methoxypyridin-3-amine
Packaging
1g
Price
$95
Updated
2021/12/16
SynQuest Laboratories
Product number
4H56-9-N9
Product name
2-Bromo-6-methoxypyridin-3-amine
Packaging
1g
Price
$104
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB140331
Product name
2-Bromo-6-methoxypyridin-3-amine
Packaging
5G
Price
$173
Updated
2021/12/16
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3-AMINO-2-BROMO-6-METHOXYPYRIDINE Chemical Properties,Usage,Production

Chemical Properties

Dark red solid

Synthesis

6628-77-9

135795-46-9

General procedure for the synthesis of 3-amino-6-methoxy-2-bromopyridine from 5-amino-2-methoxypyridine: 1. 1.83 g (14.7 mmol) of 5-amino-2-methoxypyridine, 1.21 g (14.7 mmol) of sodium acetate, and 12 mL of acetic acid were sequentially added to a reaction flask and stirred well. 2. 0.75 mL (14.7 mmol) of bromine was slowly added dropwise at room temperature, keeping the reaction at room temperature. 3. 3. After the dropwise addition, continue to stir the reaction mixture at room temperature for 30 minutes. 4. 4. Upon completion of the reaction, 200 mL of saturated sodium thiosulfate solution was added to the reaction mixture to quench the reaction. 5. The reaction mixture was transferred to a partition funnel and the aqueous phase was extracted twice with ethyl acetate. 6. The organic phases were combined, dried over anhydrous magnesium sulfate, filtered and concentrated under reduced pressure to give 3 g of the purple solid product 3-amino-6-methoxy-2-bromopyridine (quantitative yield). Product characterization data: 1H NMR (250 MHz, DMSO-d6) δ: 7.18 (d, 1H), 6.64 (d, 1H), 4.91 (s, 2H), 3.71 (s, 3H).

References

[1] Patent: US2008/200495, 2008, A1. Location in patent: Page/Page column 9
[2] Tetrahedron Letters, 2011, vol. 52, # 41, p. 5292 - 5296
[3] Journal of Medicinal Chemistry, 1995, vol. 38, # 24, p. 4830 - 4838
[4] Patent: WO2005/30213, 2005, A1. Location in patent: Page/Page column 170-171
[5] Patent: US5366972, 1994, A

3-AMINO-2-BROMO-6-METHOXYPYRIDINE Preparation Products And Raw materials

Raw materials

Preparation Products

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3-AMINO-2-BROMO-6-METHOXYPYRIDINE Suppliers

Alchem Pharmtech,Inc.
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View Lastest Price from 3-AMINO-2-BROMO-6-METHOXYPYRIDINE manufacturers

Hebei Xinsheng New Material Technology Co., LTD.
Product
3-AMINO-2-BROMO-6-METHOXYPYRIDINE 135795-46-9
Price
US $35.00-25.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20 Ton
Release date
2023-11-03
Dideu Industries Group Limited
Product
3-AMINO-2-BROMO-6-METHOXYPYRIDINE 135795-46-9
Price
US $1.10/g
Min. Order
1g
Purity
99.00%
Supply Ability
100 Tons min
Release date
2021-09-03
Career Henan Chemical Co
Product
3-AMINO-2-BROMO-6-METHOXYPYRIDINE 135795-46-9
Price
US $5.50/KG
Min. Order
1KG
Purity
98%min
Supply Ability
1kg-1000kg
Release date
2020-01-08

135795-46-9, 3-AMINO-2-BROMO-6-METHOXYPYRIDINERelated Search:


  • 2-Bromo-6-methoxy-3-pyridinamine
  • 5-AMino-6-broMo-2-Methoxypyridine
  • 3-AMINO-2-CHLORO-6-METHOXYPYRIDINE
  • 3-AMINO-2-BROMO-6-METHOXYPYRIDINE
  • 2-BROMO-3-AMINO-6-METHOXYPYRIDINE
  • 3-Amino-2-bromo-6-methoxypyridine ,97%
  • 3-Pyridinamine, 2-bromo-6-methoxy-
  • 3-AMINO-2-BROMO-6-METHOXYPYRIDINE ISO 9001:2015 REACH
  • 3-Amino-6-methoxy-2-bromopyridine
  • 135795-46-9
  • C6H7BrN2O
  • amine| alkyl bromide
  • Pyridine
  • Pyridines