ChemicalBook > CAS DataBase List > 5-Chloro-2-methylbenzoic acid

5-Chloro-2-methylbenzoic acid

Product Name: 5-Chloro-2-methylbenzoic acid
CAS No.: 7499-06-1
Chemical Name: 5-Chloro-2-methylbenzoic acid
Synonyms: RARECHEM AL BO 0471;5-CHLORO-O-TOLUIC ACID;o-Toluic acid, 5-chloro-;5-Chloro-2-methylbenzoic;5-CHLORO-2-METHYLBENZOIC ACID;3-CHLORO-6-METHYLBENZOIC ACID;Benzoic acid, 5-chloro-2-methyl-;5-Chloro-2-methylbenzoic Acid >4-(CHLOROMETHYL)BENZOIC ACID 99+%;5-Chloro-o-toluic acid, 2-Carboxy-4-chlorotoluene
CBNumber: CB9710584
Molecular Formula: C8H7ClO2
Formula Weight: 170.59
MOL File: 7499-06-1.mol

Less

5-Chloro-2-methylbenzoic acid Property

Melting point:: 168-173 °C
Boiling point:: 293.5±20.0 °C(Predicted)
Density: 1.310±0.06 g/cm3(Predicted)
storage temp.: Inert atmosphere,Room Temperature
solubility: soluble in Methanol
form: powder to crystal
pka: 3.50±0.25(Predicted)
color: White to Light yellow to Light orange
InChI: InChI=1S/C8H7ClO2/c1-5-2-3-6(9)4-7(5)8(10)11/h2-4H,1H3,(H,10,11)
InChIKey: CSAPESWNZDOAFU-UHFFFAOYSA-N
SMILES: C(O)(=O)C1=CC(Cl)=CC=C1C
CAS DataBase Reference: 7499-06-1(CAS DataBase Reference)

Less

Safety

Hazard Codes: Xi,Xn
Risk Statements: 36/37/38-41-37/38-22
Safety Statements: 26-36/37/39
WGK Germany: 3
HazardClass: IRRITANT
HS Code: 29163990

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H318Causes serious eye damage

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 694819
Product name: 5-Chloro-2-methylbenzoic acid
Purity: 97%
Packaging: 5g
Price: $60
Updated: 2023/01/07

TCI Chemical

Product number: C2509
Product name: 5-Chloro-2-methylbenzoic Acid
Purity: >98.0%(GC)(T)
Packaging: 5g
Price: $37
Updated: 2025/07/31

TCI Chemical

Product number: C2509
Product name: 5-Chloro-2-methylbenzoic Acid
Purity: >98.0%(GC)(T)
Packaging: 25g
Price: $128
Updated: 2025/07/31

TRC

Product number: C587573
Product name: 5-Chloro-2-methylbenzoic acid
Packaging: 500mg
Price: $45
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FC70098
Product name: 5-Chloro-2-methylbenzoic acid
Packaging: 50g
Price: $60
Updated: 2021/12/16

Less

5-Chloro-2-methylbenzoic acid Chemical Properties,Usage,Production

Chemical Properties

White powder

Definition

ChEBI: 5-chloro-2-methylbenzoic acid is a member of the class of chlorobenzoic acids that is benzoic acid in which the ring hydrogens at positions 2 and 5 are replaced by methyl and chloro groups, respectively. It is a chlorobenzoic acid, a member of monochlorobenzenes and a member of toluenes.

Synthesis

118-90-1

7499-08-3

7499-06-1

133232-56-1

54811-38-0

In a 100 mL three-necked flask equipped with a reflux condenser, 1.36 g (10 mmol) of 2-methylbenzoic acid was suspended in 25 mL of 30% (w/w) sulfuric acid. Subsequently, 2.4 g (15 mmol) of iodine monochloride was dissolved in 5 g of acetic acid and added slowly and dropwise to the above suspension over 40 minutes. The reaction mixture was stirred at 90°C for 5 hours. After completion of the reaction, the mixture was poured into 90 mL of water and the precipitate was collected by filtration. The precipitate was washed with aqueous sodium sulfite to give 1.6 g of crystalline solid product. Analysis of the product showed a composition of 33% 2-methylbenzoic acid, 13% 5-chloro-2-methylbenzoic acid, 9% 3-chloro-2-methylbenzoic acid, 38% 5-iodo-2-methylbenzoic acid, 5% 3-iodo-2-methylbenzoic acid, and 2% other impurities. Attempts were made to purify the above mixture by recrystallization from acetic acid or isopropanol to isolate 5-iodo-2-methylbenzoic acid, but the purity of the mixture was not significantly improved, making it difficult to obtain pure 5-iodo-2-methylbenzoic acid.

References

[1] Patent: EP1595862, 2005, A1. Location in patent: Page/Page column 11-12

5-Chloro-2-methylbenzoic acid Preparation Products And Raw materials

Raw materials

Preparation Products

Less

5-Chloro-2-methylbenzoic acid Suppliers

Americas 1 China 198 Europe 1 Germany 3 India 7 Japan 1 Switzerland 1 Ukraine 1 United Kingdom 10 United States 23 Global 246

Changzhou Baokang Pharmaceutical & Chemical Co.,Ltd.

Tel: 0519-0519-88494757 15961115886
Fax: +86-519-83756102
Email: sales@baokangchem.com
Country: China
ProdList: 104
Advantage: 60

JOYCHINE BIO-TECH

Tel: 18680818008
Email: 18680818008@163.com
Country: China
ProdList: 35
Advantage: 58

J & K SCIENTIFIC LTD.

Tel: 18210857532; 18210857532
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 4006356688 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

future industrial shanghai co., ltd

Tel: 400-0066400 13621662912
Fax: 021-55660885
Email: sales@jonln.com
Country: China
ProdList: 1995
Advantage: 65

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24529
Advantage: 81

ShangHai DEMO Chemical Co.,Ltd

Tel: 400-021-7337 2355568890
Fax: 0086-21-50182339
Email: sales@demochem.com
Country: China
ProdList: 2572
Advantage: 57

Wuhan Chemwish Technology Co., Ltd

Tel: 86-027-67849912
Fax: 86-027-87531808
Email: sales@chemwish.com
Country: China
ProdList: 35896
Advantage: 56

Capot Chemical Co., Ltd

Tel: +86 (0) 571 85 58 67 18
Fax: 0086-571-85864795
Country: China
ProdList: 18207
Advantage: 66

Beijing Ouhe Technology Co., Ltd

Tel: 010-010-82967028 13522913783
Fax: +86-10-82967029
Email: 2355560935@qq.com
Country: China
ProdList: 12000
Advantage: 60

JinYan Chemicals(ShangHai) Co.,Ltd.

Tel: 13817811078
Fax: 86-021-50426522,50426273
Email: sales@jingyan-chemical.com
Country: China
ProdList: 9976
Advantage: 60

Shanghai Sinch Parmaceuticals Tech. Co. Ltd.

Tel: +86-21-54098501
Fax: +86-21-54096319
Email: sales@sinch.com.cn
Country: China
ProdList: 11598
Advantage: 64

Jia Xing Isenchem Co.,Ltd

Tel: 0573-85285100 18627885956
Fax: 0573-85285100
Email: isenchem@163.com
Country: China
ProdList: 9309
Advantage: 66

Nanjing Chemlin Chemical Co., Ltd

Tel: 025-83697070
Fax: +86-25-83453306
Email: info@chemlin.com.cn
Country: China
ProdList: 16077
Advantage: 64

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696
Email: info@hanhongsci.com
Country: China
ProdList: 42934
Advantage: 64

Beijing Eternalchem Co,. Ltd.

Tel: 010-59484199 18611897322
Email: sales@eternalchem.com
Country: China
ProdList: 4383
Advantage: 60

China DongFan Chemical Co.,LTD

Tel: 86-0571-85151182
Fax: 86-0571-85151182
Country: China
ProdList: 5691
Advantage: 66

Beijing Isomersyn Technology CO;LTD

Tel: 010-82954736 13391601435
Email: sales@isomersyn.com
Country: China
ProdList: 3295
Advantage: 57

Sichuan Kulinan Technology Co., Ltd

Tel: 400-1166-196 18981987031
Fax: 028-84555506 800101999
Email: cdhxsj@163.com
Country: China
ProdList: 11705
Advantage: 57

Tianjin heowns Biochemical Technology Co., Ltd.

Tel: 400 638 7771
Email: sales@heowns.com
Country: China
ProdList: 14435
Advantage: 57

Chengdu Ai Keda Chemical Technology Co., Ltd.

Tel: 4008-755-333 18080918076
Fax: 028-86757656
Email: 800078821@qq.com
Country: China
ProdList: 9718
Advantage: 55

Shanghai civi chemical technology co.,Ltd

Tel: 86-21-34053660
Fax: 86-21-34053661
Email: sale@labgogo.com
Country: China
ProdList: 9865
Advantage: 52

Shanghai Topbiochem Technology Co., Ltd

Tel: 021-58170097
Email: info@topbiochem.com
Country: China
ProdList: 9510
Advantage: 58

9ding chemical ( Shanghai) Limited

Tel: 4009209199
Fax: 86-021-52271987
Email: sales@9dingchem.com
Country: China
ProdList: 22514
Advantage: 55

The future of Shanghai Industrial Co., Ltd.

Tel: 021-61552785
Fax: 021-55660885
Email: sales@shshiji.com
Country: China
ProdList: 9546
Advantage: 55

Chengdu AstaTech Trading Co., Ltd./AstaTech (Chengdu) Pharma. Co., Ltd.

Tel: +86-28-85122536 85324413
Fax: +86-28-85326443
Email: market@astatech.cn
Country: China
ProdList: 8026
Advantage: 55

Wuxi Zhangkun Biochemical Technology Co., Ltd.

Tel: +86 0510-85629785
Fax: +86 0510-85625359
Country: China
ProdList: 2327
Advantage: 58

Quzhou Juhua Friendship Co., Ltd

Tel: 0570-3066667
Fax: 0570-3063388
Country: China
ProdList: 3930
Advantage: 58

Amatek Scientific Co. Ltd.

Tel: 0512-56316828 4008675858
Fax: +86-512-56316826
Email: sales@amateksci.com
Country: China
ProdList: 9874
Advantage: 55

Shanghai JONLN Reagent Co., Ltd.

Tel: 400-0066400 13621662912
Fax: 021-55660885
Email: 422131432@qq.com
Country: China
ProdList: 9979
Advantage: 55

RiZhao LiDeShi Chemical Co., Ltd.

Tel: 010-51268198
Fax: 010-63833209
Email: leadershipchem@126.com
Country: China
ProdList: 2546
Advantage: 58

Mei Lan Industrial (Shanghai) Co., Ltd.

Tel: 021-58958189
Fax: 021-58957967
Email: wouchina@126.com
Country: China
ProdList: 2666
Advantage: 55

Shanghai ideal Industrial Co., Ltd.

Tel: 021-58957966 18930537195
Fax: 021-60899437
Email: wouchina@126.com
Country: China
ProdList: 3027
Advantage: 58

Chengdu HuaXia Chemical Reagent Co. Ltd

Tel: 400-1166-196 13458535857
Fax: QQ：800101999
Email: cdhxsj@163.com
Country: China
ProdList: 13350
Advantage: 58

GuangTuo Chemical (Shanghai) Co., Ltd.

Tel: 021-60899189-8001 18918189673
Fax: 021-60899304
Email: gtchem@126.com
Country: China
ProdList: 2656
Advantage: 58

Wuxi Zhongkun Biochemical Technology Co., Ltd.

Tel: 0510-85629785 18013409632
Fax: 051085625359
Email: sales@reading-chemicals.com
Country: China
ProdList: 15178
Advantage: 58

Hunan HuaTeng Pharmaceutical Co., Ltd.,

Tel: 400-8592883
Fax: 0731-82251112
Email: sales@huatengsci.com
Country: China
ProdList: 5872
Advantage: 58

Credit-Chem Co., Ltd.

Tel: 400-821-5857 021-64326257
Fax: 021-64393586 QQ;2798200800
Email: credit-chem@foxmail.com
Country: China
ProdList: 5219
Advantage: 58

Shanghai YuLue Chemical Co., Ltd.

Tel: 021-60345187 13671753212
Fax: 021-34702061
Email: lzz841106@aliyun.com
Country: China
ProdList: 10263
Advantage: 55

SHANGHAI BANGCHENG CHEMICAL Co.,Ltd.

Tel: 021-69106960 13701823733
Fax: 021-69106780
Email: 13701823733@163.com
Country: China
ProdList: 4641
Advantage: 60

Shanghai HuanChuan Industry Co.,Ltd.

Tel: 021-61478794
Fax: 021-61478794
Email: sales@hcshhai.com
Country: China
ProdList: 9793
Advantage: 50

Shanghai Yongye Biotechnology Co., Ltd.

Tel: 86-021-61559134 15921386130
Fax: 021-55068248
Email: 3423497944@qq.com
Country: China
ProdList: 8144
Advantage: 55

Shanghai Song Yuan Chemical Technology Co., Ltd.

Tel: 010-1234567 18521000990
Fax: 86-021-33275113
Email: sonyuanchemical@163.com
Country: China
ProdList: 6479
Advantage: 50

Beijing Xinsavi Chemical Technology Co., Ltd.

Tel: 010-56218822 13717722232
Fax: 010-56218800
Email: xinsavichem@163.com
Country: China
ProdList: 3201
Advantage: 56

Beijing Holiyang Chemical Co. Ltd.

Tel: 13718199399
Fax: QQ : 206661479
Email: holiyangchem@163.com
Country: China
ProdList: 3280
Advantage: 56

Shanghai YouPeng Chemical Co. Ltd.

Tel: 021-69005955 13701776567
Fax: 021-69005775
Email: youpengchem@163.com
Country: China
ProdList: 4161
Advantage: 56

Sichuan Hainuowei Technology Co. Ltd.

Tel: 13708085536 13708085536
Fax: QQ : 121102042
Email: hanovichem@163.com
Country: China
ProdList: 3282
Advantage: 56

Shanghai TongYuan Chemical Co., Ltd.

Tel: 021-021-69182866 13701855675
Fax: 021-69182022
Email: tongyuanchem@126.com
Country: China
ProdList: 4193
Advantage: 58

Shanghai Kaisai Chemical Co., Ltd

Tel: 021-33516722 13701817765
Fax: 021-33516776
Email: kaisaichem@163.com
Country: China
ProdList: 4610
Advantage: 58

Less

View Lastest Price from 5-Chloro-2-methylbenzoic acid manufacturers

Shaanxi Dideu New Materials Co. Ltd

Product: 5-Chloro-2-methylbenzoic acid 7499-06-1
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98.0%
Supply Ability: 10000KGS
Release date: 2025-05-12

Hebei Chuanghai Biotechnology Co., Ltd

Product: 5-Chloro-2-methylbenzoic acid 7499-06-1
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2024-10-28

Changzhou waston chemical technology Co.,Ltd

Product: 5-Chloro-2-methylbenzoic acid 7499-06-1
Price: US $0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: follow your request
Release date: 2023-06-01

7499-06-1, 5-Chloro-2-methylbenzoic acidRelated Search:

3-(Trifluoromethyl)benzoic acid Folic acid m-Toluic acid Methyl 4-methylbenzoate Methyl 4-(bromomethyl)benzoate Ethyl 2-(Chlorosulfonyl)acetate 5-CHLORO-2-HYDROXYPHENYLBORONIC ACID p-Toluic acid 3-Chloroperoxybenzoic acid o-Toluic acid 4-CHLORO-2-METHYLBENZOIC ACID Difluorochloromethane Methyl 3-chloro-4-methylbenzoate 2-CHLORO-5-METHYLBENZOIC ACID 4-CHLORO-3-METHYLBENZOIC ACID / 4-CHLORO-M-TOLUIC ACID,4-CHLORO-3-METHYLBENZOIC ACID 3,5-Dichloro-4-methylbenzoic acid 4-Chloro-3-methylbenzoic acid methyl ester~4-Chloro-m-toluic acid methyl ester,4-CHLORO-3-METHYLBENZOIC ACID METHYL ESTER 2-AMINO-5-CHLORO-3-METHYLBENZOIC ACID

3-CHLORO-6-METHYLBENZOIC ACID

5-CHLORO-2-METHYLBENZOIC ACID

5-CHLORO-O-TOLUIC ACID

RARECHEM AL BO 0471

5-Chloro-2-methylbenzoic

4-(CHLOROMETHYL)BENZOIC ACID 99+%

5-Chloro-o-toluic acid, 2-Carboxy-4-chlorotoluene

o-Toluic acid, 5-chloro-

5-Chloro-2-methylbenzoic Acid &gt

Benzoic acid, 5-chloro-2-methyl-

7499-06-1

7499-6-1

7499/6/1

ARYL ACID

Benzoic acid

Organic acids

Building Blocks

Carbonyl Compounds

Carboxylic Acids

Chemical Synthesis

Organic Building Blocks

Carbonyl Compounds

Carboxylic Acids

Aromatic Nitriles

Acids and Derivatives