ChemicalBook > CAS DataBase List > Manganese triacetate dihydrate

Manganese triacetate dihydrate

Product Name
Manganese triacetate dihydrate
CAS No.
19513-05-4
Chemical Name
Manganese triacetate dihydrate
Synonyms
MANGANESE(III) ACETATE DIHYDRATE;MANGANESE (III) ACETATE;anese(Ⅲ) acetate dihydrate;Manganic acetate dihydrate;manganese acetate dihydrate;TriacetoxyManganese dihydrate;MANGANESE TRIACETATE DIHYDRATE;Manganese(Ⅲ) acetate dihydrate;MANGANESE(III) ACETATE HYDRATE;Manganese(III)acetatedehydrated
CBNumber
CB9725704
Molecular Formula
C2H6MnO3
Formula Weight
133.01
MOL File
19513-05-4.mol
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Manganese triacetate dihydrate Property

Density 
1.59
storage temp. 
Inert atmosphere,Room Temperature
solubility 
DMF (Slightly, Heated, Sonicated), DMSO (Slightly, Heated), Methanol (Slightly),
form 
Solid
color 
Pink
Water Solubility 
decomposes
Sensitive 
Hygroscopic
BRN 
3732626
Exposure limits
OSHA: Ceiling 5 mg/m3
NIOSH: IDLH 500 mg/m3; TWA 1 mg/m3; STEL 3 mg/m3
CAS DataBase Reference
19513-05-4(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-63-62
Safety Statements 
26-36-37/39
RIDADR 
1479
WGK Germany 
3
TSCA 
Yes
HazardClass 
5.1
PackingGroup 
III
HS Code 
29152990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
215880
Product name
Manganese(III) acetate dihydrate
Purity
97%
Packaging
5g
Price
$64.7
Updated
2024/03/01
Sigma-Aldrich
Product number
215880
Product name
Manganese(III) acetate dihydrate
Purity
97%
Packaging
25g
Price
$323
Updated
2024/03/01
Alfa Aesar
Product number
030519
Product name
Manganese(III) acetate hydrate, 96%
Packaging
10g
Price
$72.65
Updated
2024/03/01
Alfa Aesar
Product number
030519
Product name
Manganese(III) acetate hydrate, 96%
Packaging
50g
Price
$285.65
Updated
2024/03/01
Strem Chemicals
Product number
25-0750
Product name
Manganese(III) acetate dihydrate, 98%
Packaging
5g
Price
$44
Updated
2024/03/01
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Manganese triacetate dihydrate Chemical Properties,Usage,Production

Description

Manganese (III) acetate is an inorganic compound that is used as an oxidizing agent in organic synthesis and materials science. Like the analogous acetates of iron and chromium, it is an oxygen-centered coordination complex containing three manganese atoms bridged by acetate units. The anhydrous form of this compound crystallizes as a linear coordination polymer, with an additional acetic acid molecule bridging between manganese atoms on consecutive three-manganese clusters.The chemical is therefore not a simple metal acetate ionic compound nor does the actual structure of it reflect the simple "Mn(OAc)3" chemical formula that is commonly given. It is usually used as the dihydrate, though the anhydrous form is also used in some situations. The dihydrate is prepared by reacting potassium permanganate and manganese (II) acetate in acetic acid; addition of acetic anhydride to the reaction produces the anhydrous form.
Mangese triacetate has been used as a single electron oxidant. It can oxidize alkenes via addition of acetic acid to form lactones.

Chemical Properties

orange-brown to brown powder

Uses

Triacetoxymanganese Dihydrate functions as a catalyst for direct acetylation of alcohols with acetic acid.

Uses

Mild and selective oxidizing agent. Catalyzes allylic oxidation of a variety of alkenes in the presence of tert-butylhydroperoxide. Reagent used for radical cyclizations and α-keto-acetoxylation.

Manganese triacetate dihydrate Preparation Products And Raw materials

Raw materials

Preparation Products

polyester-based liquid crystalling ionmer containing sulfonate group Sorbic acid 2-[3-(2-FURYL)PHENYL]-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE 3-THIOPHEN-2-YL-BENZALDEHYDE Butyric Acid LITHIUM MANGANESE OXIDE 1-Naphthaleneacetic acid Mn(Ⅲ)salen epoxidation catalyst 5-Bromo-7-azaindole gamma-Nonanolactone Terephthalic acid
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View Lastest Price from Manganese triacetate dihydrate manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
Manganese triacetate dihydrate 19513-05-4
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-11
Zhuozhou Wenxi import and Export Co., Ltd
Product
Manganese triacetate dihydrate 19513-05-4
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-09
Career Henan Chemical Co
Product
Manganese triacetate dihydrate 19513-05-4
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200kg
Release date
2019-07-03

19513-05-4, Manganese triacetate dihydrateRelated Search:

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