ChemicalBook > CAS DataBase List > D(+)-Phenylalaninol

D(+)-Phenylalaninol

Product Name
D(+)-Phenylalaninol
CAS No.
5267-64-1
Chemical Name
D(+)-Phenylalaninol
Synonyms
D-PHENYLALANINOL;H-D-PHE-OL;D-Phenylalanino;(R)-2-AMINO-3-PHENYL-1-PROPANOL;(2R)-2-amino-3-phenylpropan-1-ol;(R)-2-AMINO-3-PHENYL-PROPAN-1-OL;H-D-Phen-ol;R-228060-001;D-PHENYLANINOL;D-PHEYLALANINOL
CBNumber
CB9741308
Molecular Formula
C9H13NO
Formula Weight
151.21
MOL File
5267-64-1.mol
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D(+)-Phenylalaninol Property

Melting point:
93-95 °C(lit.)
Boiling point:
122 °C / 4mmHg
alpha 
23 º (c=1.2, 1 N HCl 22 ºC)
Density 
1.0406 (rough estimate)
refractive index 
23.5 ° (C=1.2, 1mol/L HCl)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
Soluble in Dichloromethane, Ethyl Acetate, Methanol.
form 
Crystalline Powder and Chunks
pka
12.85±0.10(Predicted)
color 
White to yellow
optical activity
[α]/D +22.8°, c = 1.2 in 1 M HCl
Sensitive 
Air Sensitive
BRN 
4665408
InChI
InChI=1/C9H13NO/c10-9(7-11)6-8-4-2-1-3-5-8/h1-5,9,11H,6-7,10H2/t9-/s3
InChIKey
STVVMTBJNDTZBF-DJEYLCQNNA-N
SMILES
C(C1C=CC=CC=1)[C@@H](N)CO |&1:7,r|
CAS DataBase Reference
5267-64-1(CAS DataBase Reference)
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Safety

Hazard Codes 
C,Xi
Risk Statements 
34
Safety Statements 
26-36/37/39-45-27
RIDADR 
UN 3259 8/PG 3
WGK Germany 
3
F 
10-23
HazardClass 
IRRITANT
HazardClass 
8
PackingGroup 
III
HS Code 
29221990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
284491
Product name
(R)-(+)-2-Amino-3-phenyl-1-propanol
Purity
98%
Packaging
5g
Price
$142
Updated
2023/01/07
TCI Chemical
Product number
P1289
Product name
D-Phenylalaninol
Purity
>98.0%(GC)(T)
Packaging
5g
Price
$72
Updated
2024/03/01
TCI Chemical
Product number
P1289
Product name
D-Phenylalaninol
Purity
>98.0%(GC)(T)
Packaging
25g
Price
$218
Updated
2024/03/01
Alfa Aesar
Product number
L09697
Product name
D-Phenylalaninol, 98%
Packaging
1g
Price
$40.65
Updated
2024/03/01
Usbiological
Product number
019430
Product name
D-Phenylalaninol
Packaging
5g
Price
$403
Updated
2021/12/16
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D(+)-Phenylalaninol Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powde

Uses

D-Phenylalaninol is used as a chiral auxiliary for asymmetric Michael reactions. It is an enantiomer of L-Phenylalaninol, an inhibitor of intestinal Phenylalanine absorption. It acts as an inhibiting agent to the enzymes which are responsible for the breakdown of endorphins.

Purification Methods

It can be recrystallised from Et2O, *C6H6/pet ether (b 40-60o) or toluene and distilled in a vacuum. It has been purified by dissolving in Et2O, drying over K2CO3, filtering, evaporating to a small volume, cooling in ice and collecting the plates. Store them in the presence of KOH (i.e. CO2—free atm). [Karrer & Ehrhardt Helv Chim Acta 34 3203 1951, Oeda Bull Chem Soc Jpn 13 465 1938.] The picrate has m 141-141.5o (from EtOH/pet ether). The hydrogen oxalate has m 177o, 161-162o [Hunt & McHale J Chem Soc 2073 1957]. The racemate has m 87-88o from *C6H6/pet ether (75-77o from Et2O), and the hydrochloride has m 139-141o [Fodor et al. J Chem Soc 1858 1951]. [Beilstein 13 IV 1920.]

D(+)-Phenylalaninol Preparation Products And Raw materials

Raw materials

Preparation Products

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D(+)-Phenylalaninol Suppliers

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View Lastest Price from D(+)-Phenylalaninol manufacturers

Sichuan HongRi Pharma-Tech Co.,Ltd
Product
d-phe-ol 5267-64-1
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1T+
Release date
2024-01-20
WUHAN CIRCLE POWDER TECHNOLOGY CO.,LTD
Product
D(+)-Phenylalaninol 5267-64-1
Price
US $0.00/KG
Min. Order
100g
Purity
98%+
Supply Ability
100kg
Release date
2021-03-01
WUHAN FORTUNA CHEMICAL CO., LTD
Product
D(+)-Phenylalaninol 5267-64-1
Price
US $0.00/Kg/Drum
Min. Order
1KG
Purity
98%min
Supply Ability
1000kg
Release date
2021-08-28

5267-64-1, D(+)-PhenylalaninolRelated Search:

TRISTEARIN Tris(hydroxymethyl)aminomethane Dexketoprofen trometamol (S)-(-)-2-Methyl-1-butanol Phenprobamate ALTRENOGEST 1-Phenyl-2-nitropropene Acetaminophen PHENYL VALERATE 6-Aminocaproic acid 1-Propanol Fosfomycin tromethamine Ketorolac tromethamine Glycine Diethylstilbestrol Isopropyl alcohol EC 2.6.1.2 D-Phenylglycinol

  • D-(+)-Phenylalinol
  • S/R-Phenylalaninol
  • (2R)-2-amino-3-phenylpropan-1-ol
  • BENZENEPROPANOL, .BETA.-AMINO-, (.BETA.R)-
  • D-Penylalaninol
  • D-PHEYLALANINOL
  • D-PHENYLANINOL
  • (D)-(+)-2-PHENYLALANINOL / D-(+)-2-AMINO-3-PHENYL-1-PROPANOL
  • D-Phenylalaninol(R+Phenylalaninol)
  • Benzenepropanol, beta-amino-, (R)-
  • D-Phenylalaninol ,98%
  • (R)-3-Phenyl-2-amino-1-propanol
  • (R)-3-Phenyl-2-aminopropane-1-ol
  • (αR)-α-(Hydroxymethyl)benzeneethanamine
  • H-D-Phen-ol
  • D(+)-2-Amino-3-phenyl-1-propanol,98%
  • D-PHENYLALANINOL ((R)-(+)-2-AMINO-3-PHENYL-1-PROPANOL)
  • ((1R)-1-HydroxyMethyl-2-phenylethyl)aMine
  • (2R)-2-AMino-3-phenyl-1-propanol
  • (R)-(+)-2-AMino-3-phenyl-1-glycinol
  • (R)-2-AMino-1-hydroxy-3-phenylpropane
  • (R)-2-BenzylethanolaMine
  • (βR)-β-AMino-benzenepropanol
  • D-Phenylalaninol, (2R)-2-Amino-1-hydroxy-3-phenylpropane
  • BENZENEPROPANOL, B-AMINO-, (BR)-
  • D-(R)-PHENYLALANINOL
  • (+)-D-PHENYLALANINOL
  • D(+)-PHENYLALANINOL
  • D-PHENYLALANINOL
  • D-ALPHA-PHENYLALANINOL
  • D(+)-2-AMINO-3-PHENYL-1-PROPANOL
  • D-2-PHENYLALANINOL
  • H-D-PHE-OL
  • H-D-PHENYLALANINOL
  • (R)-(+)-2-AMINO-3-PHENYL-1-PROPANOL
  • (R)-2-AMINO-3-PHENYL-1-PROPANOL
  • (R)-2-AMINO-3-PHENYL-PROPAN-1-OL
  • (R)-(+)-PHENYLALANINOL
  • (R)-PHENYLALANINOL
  • PHENYLALANINOL-D
  • (R)-2-amino-3-phenylpropanol
  • (R)-2-Amino-3-phenyl-1-propanol D(+)-Phenylalaninol D(+)-2-Amino-3-phenyl-1-propanol
  • D-2-Amino-3-phenyl-1-propanol,99%e.e.
  • R-228060-001
  • (R)-(+)-2-Amino-3-phenyl-1-propanol 98%
  • D-Phenylalaninol&gt
  • Benzenepropanol, β-amino-, (βR)-
  • D-Phenylalanino
  • D(+)-Phenylalaninol USP/EP/BP
  • D-(+)-2-Amino-3-phenyl-1-proanol
  • (+)-D-Phenylalaninol
  • 5267-64-1
  • 15267-64-1
  • Amino Alcohols (Chiral)
  • Chiral Building Blocks
  • Asymmetric Synthesis
  • Amino Acid Derivatives
  • Amino Alcohols