ChemicalBook > CAS DataBase List > 5-Nitro-1,10-phenanthroline

5-Nitro-1,10-phenanthroline

Product Name
5-Nitro-1,10-phenanthroline
CAS No.
4199-88-6
Chemical Name
5-Nitro-1,10-phenanthroline
Synonyms
5-NP;5-Nitro-1;NITROFERROIN;TIMTEC-BB SBB008850;5-nitro-10-phenanthroline;5-Nitro-1,10-phenathroline;5-NITRO-1,10-PHENANTHROLINE;1,10-Phenanthroline, 5-nitro-;5-Nitro-1,10-phenanthroline>5-Nitro-1, 10-diazaphenanthrene
CBNumber
CB9747931
Molecular Formula
C12H7N3O2
Formula Weight
225.2
MOL File
4199-88-6.mol
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5-Nitro-1,10-phenanthroline Property

Melting point:
202-204 °C(lit.)
Boiling point:
366.71°C (rough estimate)
Density 
1.2844 (rough estimate)
refractive index 
1.5700 (estimate)
storage temp. 
Sealed in dry,Room Temperature
solubility 
soluble in Alcohol,Benzene
pka
pK1:3.232(+1) (25°C)
form 
crystalline
color 
yellow to orange
biological source
synthetic
Water Solubility 
insoluble
BRN 
196245
CAS DataBase Reference
4199-88-6(CAS DataBase Reference)
EPA Substance Registry System
1,10-Phenanthroline, 5-nitro- (4199-88-6)
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Safety

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-40
Safety Statements 
26-36-24/25-22
WGK Germany 
3
TSCA 
Yes
HS Code 
29339900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
N8501
Product name
5-Nitro-1,10-phenanthroline
Purity
≥97%, crystalline
Packaging
1g
Price
$96
Updated
2024/03/01
Sigma-Aldrich
Product number
N8501
Product name
5-Nitro-1,10-phenanthroline
Purity
≥97%, crystalline
Packaging
5g
Price
$859
Updated
2024/03/01
TCI Chemical
Product number
N0214
Product name
5-Nitro-1,10-phenanthroline
Purity
>98.0%(HPLC)(T)
Packaging
1g
Price
$85
Updated
2024/03/01
Alfa Aesar
Product number
A11428
Product name
5-Nitro-1,10-phenanthroline, 98%
Packaging
1g
Price
$87.65
Updated
2024/03/01
Alfa Aesar
Product number
A11428
Product name
5-Nitro-1,10-phenanthroline, 98%
Packaging
5g
Price
$310.65
Updated
2024/03/01
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5-Nitro-1,10-phenanthroline Chemical Properties,Usage,Production

Chemical Properties

Light yellow to yellow-brown crystalline powder

Uses

5-Nitro-1,10-phenanthroline complexes of iron find wide applications in redox titrations. It is used as a precursor for the synthesis of 5-amino-1,10-phenanthroline, 5-isothiocyanato-1,10-phenanthroline.

Biochem/physiol Actions

Platinum chelates of a variety of 5-substituted phenanthrolines, including this compound, were tested for cytotoxicity against L1210 murine leukemia cells. Though all tested compounds had very similar DNA-binding affinities, they exhibited a wide range of cytotoxicity.

Purification Methods

Crystallise the phenanthroline from *benzene/pet ether, until anhydrous. It also crystallises from H2O with m 202o, and EtOAc with m 203o. Its pK2 5 varies from 3.20 to 2.69 with varying MeOH/H2O ratios from 0 to 0.95 moles/L, and from 3.20 to 1.95 in varying EtOH/H2O ratios from 0 to 0.94 moles/L [Ram et al. J Prakt Chem 319 719 1977]. It forms complexes with Cu2+, Zn2+, In2+, Fe2+ , Co2+, Ni2+ . [Beilstein 23 III/IV 1682, 23/8 V 425.]

5-Nitro-1,10-phenanthroline Preparation Products And Raw materials

Raw materials

Preparation Products

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5-Nitro-1,10-phenanthroline Suppliers

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View Lastest Price from 5-Nitro-1,10-phenanthroline manufacturers

Shanghai UCHEM Inc.
Product
5-Nitro-1,10-phenanthroline 4199-88-6
Price
US $32.00-423.00/g
Min. Order
1g
Purity
0.98
Supply Ability
10kg
Release date
2023-10-17
Shaanxi Dideu Medichem Co. Ltd
Product
5-Nitro-1,10-phenanthroline 4199-88-6
Price
US $1.00-45.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200000KG
Release date
2024-08-01
Career Henan Chemical Co
Product
5-Nitro-1,10-phenanthroline 4199-88-6
Price
US $1.00/kg
Min. Order
1kg
Purity
95%-99%
Supply Ability
100kg
Release date
2018-12-24

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