Tris(dibenzylideneacetone)dipalladium

ChemicalBook > CAS DataBase List > Tris(dibenzylideneacetone)dipalladium

Tris(dibenzylideneacetone)dipalladium

Description Uses Reactions References

Product Name: Tris(dibenzylideneacetone)dipalladium
CAS No.: 51364-51-3
Chemical Name: Tris(dibenzylideneacetone)dipalladium
Synonyms: (DBA)3PD2;Tris(dibenzylideneacetone)palladium;tris(1,5-diphenylpenta-1,4-dien-3-one) dipalladium;Pd2(dbba)3;Pd2(dibenzylideneacetone)3;Tris(dibenzylideneacetonyl)bis-palladium;Tris(dibenzylidenaceTone) dipalladium (O);Tris(dibenzylideneac;Tris(dibenzyL;ideneacetone)dipaL
CBNumber: CB9855353
Molecular Formula: C51H42O3Pd2
Formula Weight: 915.71738
MOL File: 51364-51-3.mol

Less

Tris(dibenzylideneacetone)dipalladium Property

Melting point:: 152-155°C
storage temp.: 2-8°C
solubility: Soluble in chlorinated solvents, benzene and THF.
form: Fine Crystalline Powder
color: Purple to black
Water Solubility: insoluble
Sensitive: Air & Moisture Sensitive
InChI: InChI=1S/3C17H14O.2Pd/c3*18-17(13-11-15-7-3-1-4-8-15)14-12-16-9-5-2-6-10-16;;/h3*1-14H;;/b3*13-11+,14-12+;;
InChIKey: IBXMKLPFLZYRQZ-VCHVFRDLSA-N
CAS DataBase Reference: 51364-51-3(CAS DataBase Reference)

Less

Safety

Hazard Codes: Xn
Risk Statements: 20/22-36-40
Safety Statements: 24/25-36/37
WGK Germany: 3
TSCA: No
HS Code: 28439000

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H317May cause an allergic skin reaction

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P272Contaminated work clothing should not be allowed out of the workplace.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 328774
Product name: Tris(dibenzylideneacetone)dipalladium(0)
Purity: 97%
Packaging: 1g
Price: $89.2
Updated: 2024/03/01

Sigma-Aldrich

Product number: 328774
Product name: Tris(dibenzylideneacetone)dipalladium(0)
Purity: 97%
Packaging: 5g
Price: $383
Updated: 2024/03/01

Sigma-Aldrich

Product number: 919772
Product name: Tris(dibenzylideneacetone)dipalladium(0) ChemBeads
Packaging: 250MG
Price: $119
Updated: 2023/06/20

Sigma-Aldrich

Product number: 919772
Product name: Tris(dibenzylideneacetone)dipalladium(0) ChemBeads
Packaging: 1G
Price: $299
Updated: 2023/06/20

TCI Chemical

Product number: T2184
Product name: Tris(dibenzylideneacetone)dipalladium(0)
Purity: >75.0%(T)
Packaging: 1g
Price: $175
Updated: 2024/03/01

Less

Tris(dibenzylideneacetone)dipalladium Chemical Properties,Usage,Production

Description

Tris(dibenzylideneacetone) dipalladium (Tris DBA) is used as catalyst for a wide variety of Pd catalyzed reactions including Suzuki coupling, Heck coupling, Negishi coupling, Carroll reaarangement, Trost asymmetric allylic alkylation, Buchwald-Hartwig amination of acryl halides, fluorination of allylic chlorides, arylation of ketones, carbonylation of 1,1-dichloro-1-alkenes, ?-arylation of carboxylic esters, and conversion of aryl and vinyl triflates to aryl and vinyl halides. It is also involved in the synthesis of azepane. Tris DBA is also a novel inhibitor of N-myristoyltransferase-1 with significant antitumor activity.

Uses

Tris(dibenzylideneacetone)dipalladium is used in the preparation of semiconducting polymers processed from nonchlorinated solvents into high performance thin film transistors. Also used in the synthesis of polymer bulk-heterojunction solar sells as a semiconductor.

Reactions

1. Catalyst precursor for conversion of aryl chlorides, triflates, and nonaflates to nitroaromatics.
2. Catalyst for the synthesis of epoxides.
3. Catalytic asymmetric allylic and homoallylic diamination of terminal olefins.
4. Site-selective benzylic sp3 palladium-catalyzed direct arylation.
5. Palladium-catalyzed one-pot synthesis of tricyclic indolines.
6. Active catalyst for the Suzuki-Miyaura coupling of 2-pyridyl nucleophiles.
7. Catalyst in combination with BINAP for the asymmetric Heck Arylation of olefins.
8. Precursor for palladium-catalyzed carbon-nitrigen bond formation.
9. Catalyst for α-arylation of ketones,
10. Cross-coupling of aryl halides with aryl boronic acids.

References

https://en.wikipedia.org/wiki/Tris(dibenzylideneacetone)dipalladium(0)
http://www.sigmaaldrich.com
https://www.alfa.com
https://pubchem.ncbi.nlm.nih.gov
S. S. Bhandarkar, J. Bromberg, C. Carrillo, P. Selvakumar, R. K. Sharma, B. N. Perry, B. Govindarajan, L. Fried, A. Sohn, K. Reddy and J. L. Arbiser, Tris (Dibenzylideneacetone) Dipalladium, a N-Myristoyltransferase-1 Inhibitor, Is Effective against Melanoma Growth In vitro and In vivo, Clinical Cancer Research, 2008, vol. 18, 5743-5748

Chemical Properties

dark purple solid

Uses

suzuki reaction

Uses

A cycloaddition catalyst.

Uses

Tris(dibenzylideneacetone)dipalladium is used in the preparation of semiconducting polymers processed from nonchlorinated solvents into high performance thin film transistors. It is also used as a semiconductor in the synthesis of polymer bulk-heterojunction solar cells.

Preparation

First reported in 1970,Tris(dibenzylideneacetone)dipalladium(0) is prepared from dibenzylideneacetone and sodium tetrachloropalladate. Because it is commonly recrystallized from chloroform, the complex is often supplied as the adduct [Pd2(dba)3·CHCl3].The purity of samples can be variable.

General Description

Tris(dibenzylideneacetone)dipalladium(0) (Pd₂(dba)₃) participates in the synthesis of azepane. Crystal structure of Pd₂(dba)₃ has been determined by three-dimensional X-ray data. Crystals of Pd₂(dba)₃ are reported to crystalize in triclinic system. It is widely used Pd(0) source in Pd-mediated transformations.

Structure and conformation

In [Pd2(dba)3], the pair of Pd atoms are separated by 320 pm but are tied together by dba units.The Pd(0) centres are bound to the alkene parts of the dba ligands.

Tris(dibenzylideneacetone)dipalladium Preparation Products And Raw materials

Raw materials

Sodium acetate Benzaldehyde Palladium chloride

Preparation Products

4-PYRIDIN-2-YLISOXAZOL-5-AMINE 3-MORPHOLINOPHENYLBORONIC ACID PINACOL ESTER 3-Morpholinobenzaldehyde

Less

Tris(dibenzylideneacetone)dipalladium Suppliers

Australia 1 Belgium 3 Canada 1 China 415 Europe 1 France 1 Germany 6 India 26 Japan 6 South Korea 2 Switzerland 4 Ukraine 1 United Kingdom 9 United States 47 Global 523

Shaanxi Rock New Materials Co., Ltd.

Tel: 0917-8888777, 3380777,18691786767; 15619786767
Email: xuya@bjrock.com
Country: China
ProdList: 310
Advantage: 62

WuHan Taiyukaishang Chemical Co., Ltd.

Tel: 027-027-87680032 18963957250
Fax: 027-87680032 -8016
Email: taiyuchem@163.com
Country: China
ProdList: 108
Advantage: 55

Beijing Guofang Dingsheng Technology Co., Ltd.

Tel: 18610472091 18610472091
Fax: 010-59092859
Email: gfdskj@163.com
Country: China
ProdList: 494
Advantage: 58

Wu Han Lbpchem Chemical Co., Ltd.

Tel: 02763499399 13797220777
Email: lpbchem@163.com
Country: China
ProdList: 99
Advantage: 58

Wuhan Huahan Dingcheng New Material Technology Co., Ltd

Tel: +86-027-81388558 18963961905
Email: huahandingcheng@sina.com
Country: China
ProdList: 81
Advantage: 58

Wuhan Jiade Ruifeng New Materials Co., Ltd

Tel: 18271874579; 18271874579
Email: 2176439072@qq.com
Country: China
ProdList: 268
Advantage: 58

Shanghai Chiral Chemistry Co.,Ltd

Tel: 021-34621844 17301717660
Email: 404352994@qq.com
Country: China
ProdList: 17
Advantage: 58

Wuhan Houshuang Technology Co., Ltd

Tel: 13080686708
Email: houshuangchem@163.com
Country: China
ProdList: 77
Advantage: 58

Shandong Carbene New Material Technology Co., Ltd

Tel: 183-6607-2789 13305403391
Email: sdcarbene@163.com
Country: China
ProdList: 327
Advantage: 58

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 94657
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24529
Advantage: 81

Beijing dtftchem Technology Co., Ltd.

Tel: 010-60275820 13031183356
Fax: 010-60270825
Email: elainezt@sina.com
Country: China
ProdList: 1390
Advantage: 62

Beijing HwrkChemical Technology Co., Ltd

Tel: 010-89508211 18501085097
Fax: 010-89508210
Email: sales.bj@hwrkchemical.com
Country: China
ProdList: 8418
Advantage: 55

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44688
Advantage: 61

Capot Chemical Co., Ltd

Tel: +86 (0) 571 85 58 67 18
Fax: 0086-571-85864795
Email: sales@capotchem.com
Country: China
ProdList: 18207
Advantage: 66

Beijing Ouhe Technology Co., Ltd

Tel: 010-82967028 13552068683
Fax: +86-10-82967029
Email: 2355560935@qq.com
Country: China
ProdList: 12390
Advantage: 60

JinYan Chemicals(ShangHai) Co.,Ltd.

Tel: 13817811078
Fax: 86-021-50426522,50426273
Email: sales@jingyan-chemical.com
Country: China
ProdList: 9976
Advantage: 60

Jia Xing Isenchem Co.,Ltd

Tel: 0573-85285100 18627885956
Fax: 0573-85285100
Email: isenchem@163.com
Country: China
ProdList: 9513
Advantage: 66

Beijing VSciChem Technology Co., Ltd.

Tel: 13811761079
Email: vscichem@163.com
Country: China
ProdList: 251
Advantage: 64

Accela ChemBio Co.,Ltd.

Tel: 021-50795510 4000665055
Fax: 021-50795055
Email: sales@accelachem.com
Country: China
ProdList: 11655
Advantage: 64

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696
Email: info@hanhongsci.com
Country: China
ProdList: 42958
Advantage: 64

Chemsky（shanghai）International Co.,Ltd.

Tel: 021-50135380
Email: shchemsky@sina.com
Country: China
ProdList: 32321
Advantage: 50

Beijing Isomersyn Technology CO;LTD

Tel: 010-82954736 13391601435
Email: sales@isomersyn.com
Country: China
ProdList: 3295
Advantage: 57

Shandong Xiya Chemical Co., Ltd

Tel: 4009903999 13355009207
Fax: 0539-6365991
Email: 3007715519@qq.com
Country: China
ProdList: 18738
Advantage: 57

Sichuan Kulinan Technology Co., Ltd

Tel: 400-1166-196 18981987031
Fax: 028-84555506 800101999
Email: cdhxsj@163.com
Country: China
ProdList: 11707
Advantage: 57

China Langchem Inc.

Tel: 0086-21-58956006
Fax: 0086-21-58956100
Country: China
ProdList: 7811
Advantage: 57

Tianjin heowns Biochemical Technology Co., Ltd.

Tel: 400 638 7771
Email: sales@heowns.com
Country: China
ProdList: 14435
Advantage: 57

Shanghai Chem-Milestone Co., Ltd

Tel: 021-50273253 13641951838
Fax: +86-21-61294436
Email: chemmilestone@163.com
Country: China
ProdList: 151
Advantage: 62

SpringPharma Tech Co.,Ltd

Tel: +86-25-68710855, +86-25-68710897
Fax: 025-68710856
Email: sales@springpharma.net
Country: China
ProdList: 1261
Advantage: 62

Shanghai Sunway Pharmaceutical Technology Co., Ltd

Tel: 021-51613915-820 13611835272
Fax: 021 51613951
Email: mmwang@sunwaypharm.cn
Country: China
ProdList: 9734
Advantage: 57

Nanjing Vital Chemical Co., Ltd.

Tel: Please Send Email 18652950785
Fax: 025-87193546
Email: chemweiao@163.com
Country: China
ProdList: 4378
Advantage: 65

Aemon Chemical

Tel: 0086-755-86198205
Email: acinfo@aemonchem.com
Country: China
ProdList: 1931
Advantage: 57

Nanjin Cynthia chemicals Technology Co.,Ltd

Tel: 0550-5618439 15951861180
Fax: 0550-5610690
Email: cynthiachem@163.com
Country: China
ProdList: 335
Advantage: 62

Hangzhou Yuhao Chemical Technology Co., Ltd

Tel: 0571-82693216
Fax: +86-571-82880190
Email: info@yuhaochemical.com
Country: China
ProdList: 9387
Advantage: 52

Springchem New Material Technology Co.,Limited

Tel: +86-021-62885108 +8613917661608
Email: info@spring-chem.com
Country: China
ProdList: 2068
Advantage: 57

Explovisual Technology Incorporation

Tel: +86 (519) 8829-2061
Fax: +86 (519) 8829-2061
Email: explovisual@hotmail.com
Country: China
ProdList: 296
Advantage: 60

ZhengZhou HuaWen Chemical Co.Ltd

Tel: 0370-2785118 17550508557
Fax: QQ：3470079902
Email: 675141927@qq.com
Country: China
ProdList: 3203
Advantage: 55

Shanghai Sphchem Co., Ltd.

Tel: 21-21-56491756 13512199871
Fax: 021-5649-1756
Email: sales@panhongchem.com
Country: China
ProdList: 4000
Advantage: 55

Chengdu Ai Keda Chemical Technology Co., Ltd.

Tel: 4008-755-333 18080918076
Fax: 028-86757656
Email: 800078821@qq.com
Country: China
ProdList: 9718
Advantage: 55

T&W GROUP

Tel: 021-61551611 13296011611
Fax: ＋86 21-50676805
Email: contact@trustwe.com
Country: China
ProdList: 9895
Advantage: 58

S.Z. PhyStandard Bio-Tech. Co., Ltd.

Tel: 0755-4000505016 13380397412
Fax: 0755 28094224
Email: 3001272453@qq.com
Country: China
ProdList: 5047
Advantage: 50

Shanghai civi chemical technology co.,Ltd

Tel: 86-21-34053660
Fax: 86-21-34053661
Email: sale@labgogo.com
Country: China
ProdList: 9865
Advantage: 52

Suzhou Sibian Chemical Technology Co.,Ltd.

Tel: 0512-65617459 18915409046
Fax: 0512-65617459
Email: sales@sibian-chem.com
Country: China
ProdList: 1922
Advantage: 55

Beijing Yisiyan Technology Research Center

Tel: 010-56645598 13366904824
Fax: 01062230033
Email: bjkaida@163.com
Country: China
ProdList: 1637
Advantage: 59

Thermo Fisher Scientific

Tel: 800-810-5118
Fax: +86-10-84193589
Email: cnchemical@thermofisher.com
Country: China
ProdList: 17770
Advantage: 75

Beijing HuaMeiHuLiBiological Chemical

Tel: 010-56205725
Fax: 010-65763397
Email: waley188@sohu.com
Country: China
ProdList: 12335
Advantage: 58

Beijing innoChem Science & Technology Co.,Ltd.

Tel: 400-810-7969 010-59572699
Fax: 010-59572688
Email: ningzi.li@inno-chem.com.cn
Country: China
ProdList: 6134
Advantage: 55

Accendatech Co., LTD.

Tel: 13132578992
Fax: 022-83718543-802
Email: sales@accendatech.com
Country: China
ProdList: 332
Advantage: 58

Less

View Lastest Price from Tris(dibenzylideneacetone)dipalladium manufacturers

Hebei Dangtong Import and export Co LTD

Product: Tris(dibenzylideneacetone)dipalladium 51364-51-3
Price: US $12.00-7.00/g
Min. Order: 1g
Purity: 99%
Supply Ability: 500
Release date: 2023-09-14

Shanghai Daken Advanced Materials Co.,Ltd

Product: Tris(dibenzylideneacetone)dipalladium 51364-51-3
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98.00%
Supply Ability: 100KG /month
Release date: 2021-11-05

R&D Scientific Inc.

Product: Tris(dibenzylideneacetonyl)bis-palladium 51364-51-3
Price: US $1786.00/g
Min. Order: 1g
Purity: 98
Supply Ability: 500 Kg
Release date: 2024-11-12

51364-51-3, Tris(dibenzylideneacetone)dipalladiumRelated Search:

BENZALPHTHALIDE Tris(hydroxymethyl)aminomethane Benzyl chloride 1,3-Dihydroxyacetone Tricine BUFFER SOLUTION PH = 6,00 (20 °C) (POTASSIUM DIHYDROGEN PHOSPHATE/SODIUM HYDROXIDE) Benzyltrimethylammonium chloride Benzalacetone BIS-Tris Diacetone Alcohol Dibenzylideneacetone Tris(dibenzylideneacetone)dipalladium Tris(dibenzylideneacetone)dipalladium-chloroform adduct Benzyltriethylammonium chloride Dichloro(1,5-cyclooctadien)ruthenium(II) polymer Dichloro(1,5-cyclooctadiene)platinum(II) Chloro(1,5-cyclooctadiene)rhodium(I) dimer Tris(triphenylphosphine)rhodiu

Bis(dibenzylideneacetone)palladium(0)~Pd_2(dba)_3

Tris(dibenzylidenaceTone) dipalladium (O)

Tris(dibezylideneacetone)dipalladium

Palladium, tris.mu.-(1,2-.eta.:4,5-.eta.)-(1E,4E)-1,5-diphenyl-1,4-pentadien-3-onedi-

Tris(dibenzylidenaceton)dipalladium

TRIS(BIBENZYLIDENEACETONE) DIPALLADIUM

Tris(dibenzylideneacetone)dipalladium(0), Pd 21.5% min

Tris(dibenzylideneacetone)dipalladium(0), Pd content 22-24%

TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM，20.3%

ChemDose(R), Tris[dibenzylideneacetone]dipalladium(0) impregnated tablets

Tris[dibenzylideneacetone]dipalladium(0), ChemDose(R) tablets

Tris(dibenzylideneacetone)dipalladium(0) Can be used to form catalysts in situ by separate addition of ligand dec. 152-155

Tris(dibenzylideneacetone)dipalladium(0),97%

Tris(dibenzylideneacetone)dipalladium(0), Pd min

tris(dibenzylidineacetone)dipalladium(0)

Tris(dibenzylideneacetone)dipalladium(0) ,98%

Tris(dibenzylideneac

Bis[tris(dibenzylideneacetone)palladium(0)]

Tris(dibenzylideneacetone)dipalladiuM(0), 97% 500MG

Tris(dibenzylideneacetone)dipalladiuM(0), 97% 5GR

(DBA)3PD2

Tris(Dibenzylidenacetone)palladiuM (O)

Tris(dlbenzylideneacetone)dipalladiuM(O)

Tris(dibenzylideneacetone)dipalladiuM (0), Pd2(dba)3

Pd2(dibenzylideneacetone)3*CHCl3

Tris(dibenzylideneacetone)dipa

Tris(dibenzylideneacetone)dipalladiuM(0), 20% Pd, Product of UMicore

Tris[dibenzylideneacetone]dipalladium(0)impregnated tablets

Tris[dibenzylideneacetone]dipalladium(0), ChemDose? tablets

Tris(dibenzylideneacetonyl)bis-palladium

Tris (dibenzylideneacetone indene) dipalladiuM

Three (2 benzylidene acetone) 2 palladiuM

Pd2(dba)3(=Tris(debenzylideneacetone)Dipalladium(0)

ideneacetone)dipaL

Tris(dibenzyL

Tris(dibenzylideneacetone)palladium

Pd21.5%Tris(dibenzylideneacetonyl)bis palladium

Pd2(dibenzylideneacetone)3

Tris[dibenzylideneacetone]dipalladium(0), ChemDose(TM) tablets

Tris (dibenzilidenacetona) dipaládio (0) (Pd2(dba)3)

Tris(dba)dipalladium(0)

Pd2(dbba)3

Tris(dibenzylideneacetone)dipalladium(0),>98%,,Pd 21.5% min

Tris(dibenzylideneacetone)dipalladium(0) (Pd2(dba)3) extrapure, 22-25% Pd

tris(1,5-diphenylpenta-1,4-dien-3-one) dipalladium

Tris(dibenzylideneacetone)dipalladium / Pd2(dba)3

Tri (dibenzylacetone) dipalladium

TRI DIBENZYLIDENEACETONE DIPALLADIUM

Tris(dibenzylideneacetone)palladium(0)

51364-51-3

51364-05-3

C6H5CHCHCOCHCHC6H53Pd2

C51H42O3Pd2

Pd2dba3xdba

3C17H14O2Pd

chemical reaction,pharm,electronic,materials

organometallic complexes

Catalysts-Ligands