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Estrogen and progestin drugs

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Estrogen drugs can be divided into three types:
1. Natural Estrogen: the natural estrogen secreted by the body includes estradiol, estrone and estriol. At present, the estrogen commonly used in clinical contains its derivatives, estradiol and its synthetic derivatives, such as the ong-acting estrogen estradiol benzoate, estradiol valerate, estradiol cypionate used for injection and the orally active ethinyl estradiol, quinestrol. And they are all the commonly used clinical estrogen drugs, which can also be combined with progestogen to form various compounds and be used for contraceptives. The estriol has weaker estrogenic activity than estradiol, and is characterized by the selection to vagina and cervical canal. The estriol in clinic is mainly used to cure menopausal syndrome and senile vaginitis. Their metabolic processes in the body is similar to the natural estrogen. Premarin is a kind of natural conjugated estrogens, and can be used as a supplement therapeutic agent for estrogen.
2. Semi-synthetic estrogen: ethinyl estradiol is a oral potent estrogen, and the effect of ethinyl estradiol is about 20 times than that of diethylstilbestrol. Its long derivatives is nilestriol.
3. The synthetic estrogen (non-steroidal estrogens): the nonsteroidal synthetic estrogen diethylstilbestrol and other drugs are also commonly used in the clinical practice, in which the chloroallyl female ether is the best variety.

The progesterone drugs generally include the progesterone and the drugs that have similar physiological activity with the natural progesterone (progestogens). Its physiological effects are closely related with the progesterone. It changes the uterine tissue in order to facilitate the transport implantation and development of the fertilized egg. At the same time,   it can suppress the ovulation and effect the function of the uterus and the development of the mammary gland. The natural progesterone comes from the cyclical secretion of the corpus luteum and can be synthesized with Yaro sapogenin and sterol in industry.
The engineered progestin compounds, according to their chemical structure, can be divided into two categories:
1. progesterone derivatives 17α- hydroxyprogesterone class, such as medroxyprogesterone acetate (medroxyprogesterone acetate, medr-oxyprogesterone acetate), megestrol acetate, chlormadinone (chlormadinone acetate) and injectable long-acting progesterone caproate (17α- hydroxyprogesterone caproate, hydroxyprogester-one caproate) and the like.
2. 19-nortestosterone class, such as norethindrone, norethindrone (norethynodrel), and other high-quinolone represented. Their structure is based on the 19-acetylene testosterone that has different structure with the progesterone and the position of the methyl-10,13-substituted have also been changed.

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Structure:
Chemical Name:
Promestriene
CAS:
39219-28-8
MF:
C22H32O2
Structure:
Chemical Name:
Estrone
CAS:
53-16-7
MF:
C18H22O2
Structure:
Chemical Name:
Ethinyl Estradiol
CAS:
57-63-6
MF:
C20H24O2
Structure:
Chemical Name:
Estriol
CAS:
50-27-1
MF:
C18H24O3
Structure:
Chemical Name:
β-Estradiol
CAS:
50-28-2
MF:
C18H24O2
Structure:
Chemical Name:
Progesterone
CAS:
57-83-0
MF:
C21H30O2
Structure:
Chemical Name:
Medroxyprogesterone Acetate
CAS:
71-58-9
MF:
C24H34O4
Structure:
Chemical Name:
Estradiol benzoate
CAS:
50-50-0
MF:
C25H28O3
Structure:
Chemical Name:
ALTRENOGEST
CAS:
55720-26-8
MF:
C6H13ClN2O3
Structure:
Chemical Name:
Medrogestone
CAS:
977-79-7
MF:
C23H32O2
Structure:
Chemical Name:
Cyproterone acetate
CAS:
427-51-0
MF:
C24H29ClO4
Structure:
Chemical Name:
17a-Ethynyl-1,3,5(10)-estratriene-3,17b-diol 3-methyl ether
CAS:
72-33-3
MF:
C21H26O2
Structure:
Chemical Name:
Allylestrenol
CAS:
432-60-0
MF:
C21H32O
Structure:
Chemical Name:
Estradiol valerate
CAS:
979-32-8
MF:
C23H32O3
Structure:
Chemical Name:
Diethylstilbestrol
CAS:
6898-97-1
MF:
C18H20O2
Structure:
Chemical Name:
Ethisterone
CAS:
434-03-7
MF:
C21H28O2
Structure:
Chemical Name:
DIENESTROL
CAS:
84-17-3
MF:
C18H18O2
Structure:
Chemical Name:
HEXESTROL
CAS:
84-16-2
MF:
C18H22O2
Structure:
Chemical Name:
2-METHYL-4-TRIMETHYLSILYL-3-BUTYN-2-OL
CAS:
5272-33-3
MF:
C8H16OSi
Structure:
Chemical Name:
Premarin
CAS:
12126-59-9
MF:
C18H19NaO5S
Structure:
Chemical Name:
Nomegestrol 17-acetate
CAS:
58652-20-3
MF:
C23H30O4
Structure:
Chemical Name:
MOXESTROL
MF:
C21H26O3
Structure:
Chemical Name:
quinestradol
CAS:
1169-79-5
MF:
C23H32O3
Structure:
Chemical Name:
Alphasone acetonide
CAS:
4968-09-6
MF:
C24H34O4
Structure:
Chemical Name:
Nilestriol
CAS:
39791-20-3
MF:
C25H32O3
Structure:
Chemical Name:
Nomegestrol
CAS:
58691-88-6
MF:
C21H28O3
Chemical Name:
HexestroleBromoacetate
Structure:
Chemical Name:
POLY(ESTRADIOL PHOSPHATE)
CAS:
34828-67-6
MF:
C18H24O8P2X2
Structure:
Chemical Name:
Gestonorone
CAS:
2137-18-0
MF:
C20H28O3
Structure:
Chemical Name:
Flugestone
CAS:
337-03-1
MF:
C21H29FO4
Structure:
Chemical Name:
17ALPHA-ESTRADIOL HEMIHYDRATE VETRANAL
CAS:
6045-52-9
MF:
C18H26O3
Structure:
Chemical Name:
Almestrone
CAS:
10448-96-1
MF:
C19H24O2
Chemical Name:
Dydrogesterone
Structure:
Chemical Name:
PROMEGESTONE
CAS:
34184-77-5
MF:
C22H30O2
Structure:
Chemical Name:
DIETHYLSTILBESTROL DIPROPIONATE
CAS:
130-80-3
MF:
C24H28O4
Chemical Name:
Esterified Estrogens
Structure:
Chemical Name:
Estropipate
CAS:
7280-37-7
MF:
C22H32N2O5S
Structure:
Chemical Name:
DIMETHISTERONE
CAS:
79-64-1
MF:
C23H32O2
Structure:
Chemical Name:
methallenestril
CAS:
517-18-0
MF:
C18H22O3
Structure:
Chemical Name:
Cyproterone
CAS:
2098-66-0
MF:
C22H27ClO3
Structure:
Chemical Name:
17-Hydroxy-19-nor-17alpha-pregna-4,9,11-trien-20-yn-3-one
CAS:
848-21-5
MF:
C20H22O2
Structure:
Chemical Name:
CHLOROTRIANISENE
CAS:
569-57-3
MF:
C23H21ClO3
Structure:
Chemical Name:
GESTONORONE CAPROATE
CAS:
1253-28-7
MF:
C26H38O4
Structure:
Chemical Name:
Diethylstilbestrol
CAS:
56-53-1
MF:
C18H20O2